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Article
Influence of the Microenvironment Dynamics of Tryptophan on Its Fluorescence Parameters at Different Temperatures
The temperature dependences of the fast and slow fluorescence decay components of aqueous tryptophan solution after freezing under actinic light and in the dark were investigated in the temperature range from ...
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Article
Temperature Dependence of the Nonlinear Dynamics of the Deactivation of Excited States of Tryptophan in Various Media
The authors’ research on the dynamics of the excited states of tryptophan in various solvents as a function of temperature (–170 to +20°С) is presented. The antibatic behavior of the temperature dependences of...
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Article
Increasing Reactive Load of a Generator–Transformer Unit under the Influence of Quasi-Direct Currents
The parameters of the magnetization current of a block transformer are determined when the magnetic system is saturated under the influence of a quasi-direct current, taking into account the equipment of a syn...
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Article
Temperature Dependence of Tryptophan Fluorescence Lifetime as an Indicator of Its Microenvironment Dynamics
The spectral-kinetic characteristics of the fluorescence of the tryptophan molecule in an aqueous solution and in the composition of a protein (albumin) were studied in the temperature range from –170 to 25°C....
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Article
A Study of the Temperature Dependence of Tryptophan Fluorescence Lifetime in the Range of –170 to +20°С in Various Solvents
The temperature dependences (–170...+20°C) of the fluorescence lifetime of tryptophan molecules in an aqueous solution, in solutions of glycerol (50 and 75% by volume), dimethyl sulfoxide (50 and 75% by volume...
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Article
Pulse–Periodic Diffuse Discharge with Self-Ionization in a Gas Flow
A pulse–periodic diffuse discharge self-initiated in an atmospheric-pressure air flow passing through an annular gap with a strongly nonuniform electric field has been studied. The discharge serves as a source...
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Article
On Transformation of Energy of Geomagnetic Disturbances
Abstract—A mechanism responsible for the transformation of energy of geomagnetic disturbances into the energy of chemically active products is proposed. According to this mechanism, this transformation is impleme...
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Article
Photophysical Properties of Upconverting Nanoparticle–Phthalocyanine Complexes
Interaction between upconverting nanoparticles and aluminum octacarboxyphthalocyanine was studied. The efficiency of non-radiative energy transfer from the nanoparticles to phthalocyanine increased with the nu...
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Article
Statistical Studies of the Electric Breakdown in Nitrogen in the Duration Range of 3 ms–60 min
The statistical characteristics of an electric breakdown in the nitrogen in the spike (cathode)–plane gap in the duration range of (3 × 10–3)–3600 s at voltages close to a static breakdown have been studied. It h...
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Article
Influence of trehalose on high-temperature stability of the photosynthetic reaction centers
The effect of heating at 65°C for 20 min on the absorption spectra and kinetics of the dark recombination of charges separated between photoactive bacteriochlorophyll and quinone acceptors was studied in dry f...
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Article
Temperature dependence of tryptophan fluorescence lifetime in aqueous glycerol and trehalose solutions
The temperature dependences of tryptophan fluorescence decay kinetics in aqueous glycerol and 1 M trehalose solutions were examined. The fluorescence decay kinetics were recorded in the spectral region of 292....
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Article
The Effects of ultraviolet irradiation on hybrid films of photosynthetic reaction centers and quantum dots in various organic matrices
The effects of ultraviolet radiation (up to 0.6 J/cm2) on the absorption spectra and electron transfer in dehydrated films of photosynthetic reaction centers from purple bacteria Rb. sphaeroides and hybrid struct...
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Article
The influence of dipyridamole and its derivatives on the membrane energization state of Rhodobacter sphaeroides bacterial chromatophores
The mechanisms of the specific influence of dipyridamole therapy remain as a subject of research. In the present work the effects of dipyridamole and some its derivatives on the energization state of photosynt...
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Article
Synthesis of new 1-(3,4-dimethylphenyl)-1,5-dihydropyrazolo[3,4-d]pyrimidin-4-one derivatives
New substituted pyrazolo[3,4-d]pyrimidin-4-ones have been synthesized as a result of a series of transformations including hydrolysis of ethyl 5-amino-1H-pyrazole-4-carboxylates, cyclization of the carboxylic aci...
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Article
Generation of radical form of dipyridamole at illumination of photosynthetic reaction centers of Rb. sphaeroides
The study of the effect of vasodilator, antiplatelet agent, and inhibitor P-glycoprotein dipyridamole (DIP) on the functioning of the transmembrane protein of the reaction center (RC) of Rb. sphaeroides showed th...
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Article
Covalently linked hybrid structures of semiconductor nanocrystals and allophycocyanin
Covalently linked hybrid structures of semiconductor nanocrystals (CdSe/ZnS quantum dots) as an inorganic component with a fluorescence maximum at 620 nm and photosynthetic protein allophycocyanin (APC) as an ...
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Article
The efficiency of non-photochemical fluorescence quenching by cation radicals in photosystem II reaction centers
In a direct experiment, the rate constants of photochemical k p and non-photochemical k p + quenching of the c...
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Article
A comparison of the temperature dependence of charge recombination in the ion-radical pair P870+QA - and tryptophan fluorescence in the photosynthetic reaction centers of Rhodobacter sphaeroides
The temperature dependences of the charge-recombination rate in the ion-radical pair P870+QA - in photosynthetic reaction centers of Rhodobacter sphaeroides were investigated. Reco...
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Article
Non-photochemical fluorescence quenching in photosystem II antenna complexes by the reaction center cation radical
In direct experiments, rate constants of photochemical (k P) and non-photochemical (k P + ) flu...
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Article
An indirectly heated metal oxide hot cathode with a 100-cm2 area
Results of designing of a sectioned metal oxide hot cathode with indirect heating and a total emission coating area of 100 cm2 are described. The design of the hot cathode enables control of the working surface t...