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  1. No Access

    Article

    Catalytic hydroboration of carbon dioxide and cyclohexyl isocyanate with diimine zinc hydrides

    Reactions of generated in situ zinc hydride complexes [(dpp-bian)Zn(μ-H)]2(1) (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) and [(ArBIG-bian)ZnH] (ArBIG-bian is 1,2-bis[(2,6-dibenzhydryl-4-methy...

    V. G. Sokolov, A. A. Skatova, M. V. Moskalev, E. V. Baranov… in Russian Chemical Bulletin (2024)

  2. No Access

    Article

    SYNTHESIS AND CRYSTAL STRUCTURES OF EUROPIUM COMPLEXES WITH A STERICALLY HINDERED ArBIG-BIAN LIGAND

    The reduction of ArBIG-bian (ArBIG-bian = 1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)-imino]acenaphthene) with an excess of metallic europium in dme and subsequent crystallization from a tmeda/thf mixture leads to ...

    V. G. Sokolov, D. A. Lukina, A. A. Skatova… in Journal of Structural Chemistry (2023)

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    Coordination Polymers of Lithium Based on 1,2-Bis[(2,6-diisopropyl-4-diethylmalonophenyl)imino]acenaphthene

    1,2-Bis[(2,6-diisopropyl-4-diethylmalonophenyl)imino]acenaphthene (Dem-Bian) with zinc chloride forms complex [(Dem-Bian)ZnCl2] (I). The reaction of complex I with n-BuLi proceeds with the deprotonation of the ma...

    N. L. Bazyakina, V. G. Sokolov, M. V. Moskalev… in Russian Journal of Coordination Chemistry (2023)

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    Article

    Samarium and ytterbium complexes based on sterically hindered 1,2-bis(imino)acenaphthene*

    Reactions of the samarium complex [(ArBIG-bian)2−Sm2+] (1) (ArBIG-bian is the 1,2-bis-[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene dianion) with iodine (0.5 mol. equiv.) or triphenyltin chloride lead to t...

    V. G. Sokolov, D. A. Lukina, A. A. Skatova, M. V. Moskalev… in Russian Chemical Bulletin (2021)

  5. No Access

    Article

    Chromium and tungsten complexes with a paramagnetic gallaimidazole ligand

    The reaction of digallane [(dpp-bian)Ga—Ga(dpp-bian)] (1) (dpp-bian is 1,2-bis[(2,6-di-isopropylphenyl)imino]acenaphthene dianion) with chromium or tungsten hexacarbonyl affords the complexes [(dpp-bian)Ga—Cr(CO)

    V. G. Sokolov, A. A. Skatova, A. V. Piskunov, E. V. Baranov… in Russian Chemical Bulletin (2020)

  6. No Access

    Article

    New Gallium Hydrides with Dianionic Acenaphthene-1,2-Diimine Ligands

    Heating of a solution of [(Dpp-bian)GaH2] (I) (Dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) in pyridine leads to elimination of a hydrogen atom and reduction of the diimine ligand to dianion, res...

    T. S. Koptseva, V. G. Sokolov, E. V. Baranov… in Russian Journal of Coordination Chemistry (2020)

  7. No Access

    Article

    New Bromine-Containing Bis(arylimino)acenaphthenes and Related Metal Complexes

    The condensation reactions of 5-bromoacenaphthenequinone with 2,6-diisopropylaniline and 4‑bromo-2,6-di-iso-propylaniline afford new mono- and tribromosubstituted bis(arylimino)acenaphthenes: 1,2-bis[(2,6-diisopr...

    V. M. Makarov, T. S. Koptseva, V. G. Sokolov… in Russian Journal of Coordination Chemistry (2020)

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    Article

    New functionalized acenaphthene-1,2-diimines and derived zinc and copper complexes

    The new compound 1,2-bis[(2,6-diisopropyl-4-iodophenyl)imino]acenaphthene (I2-dppbian, 1) was synthesized by the condensation of acenaphthenequinone with 2,6-diisopropyl-4-iodoaniline. The reaction of 1 with zinc...

    V. G. Sokolov, M. V. Moskalev, T. S. Koptseva, A. A. Skatova… in Russian Chemical Bulletin (2020)

  9. No Access

    Article

    Reactions of Acenaphthenediimine Aluminum Hydride with 1,3-Dicyclohexylcarbodiimide and 2,6-Di-tert-Butyl-4-Methylphenol

    The reaction of [(Dpp-Bian)AlH(THF)] (I) (Dpp-Bian = 1,2-bis[(2,6-diisopropylphenyl)imi-no]acenaphthene) with 1,3-dicyclohexylcarbodiimide (DCC) is accompanied by reduction of the carbodiimide C=N bond giving the...

    V. G. Sokolov, T. S. Koptseva, M. V. Moskalev… in Russian Journal of Coordination Chemistry (2019)

  10. No Access

    Article

    Reactivity of an aluminum hydride complex with a redox-active diimine ligand

    The reaction of the hydride [(dpp-bian)Al(H)Cl] (1) containing the 1,2-bis[(2,6-diisopropylphenyl) imino]acenaphthene (dpp-bian) radical anion with MeLi affords the compound [(dpp-bian)Al(H)Me] (2). The reaction ...

    V. G. Sokolov, T. S. Koptseva, V. A. Dodonov, R. V. Rumyantsev… in Russian Chemical Bulletin (2018)

  11. No Access

    Article

    Photorealistic Rendering of Images Formed by Augmented Reality Optical Systems

    Stochastic ray tracing is used for rendering photorealistic images formed by augmented reality optical systems that combine the image generated by an optoelectronic device with the image of the environment. Me...

    D. D. Zhdanov, V. A. Galaktionov, A. G. Voloboy… in Programming and Computer Software (2018)

  12. No Access

    Article

    Aluminum hydrides with radical-anionic and dianionic acenaphthene-1,2-diimine ligands

    The reaction of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) with LiAlH4 affords two products regardless of the solvent used (tetrahydrofuran or diethyl ether). These products were isolated as gre...

    V. G. Sokolov, T. S. Koptseva, M. V. Moskalev, A. V. Piskunov… in Russian Chemical Bulletin (2017)

  13. No Access

    Article

    Embedding the script language into optical simulation software

    Integration of the Python script language into computer-aided design and simulation applications is considered. By the example of the physically correct optical simulation application, an approach based on the...

    N. B. Deryabin, D. D. Zhdanov, V. G. Sokolov in Programming and Computer Software (2017)

  14. No Access

    Article

    Reconstruction of scattering properties of rough air-dielectric boundary

    The article is devoted to elaboration of the method of reconstruction of rough surface scattering properties. The object with rough surface is made of transparent dielectric material. Typically these propertie...

    V. G. Sokolov, D. D. Zhdanov, I. S. Potemin, A. A. Garbul, A. G. Voloboy… in Optical Review (2016)

  15. No Access

    Article

    Transition metal 1,3,2-diazagallol derivatives

    Reduction of digallane (dpp-bian)Ga—Ga(dpp-bian) (1) (dpp-bian is the 1,2-bis[(2,6-di-isopropylphenyl)imino]acenaphthene dianion) with metallic sodium in THF leads to the formation of gallylsodium (dpp-bian)Ga—Na...

    I. L. Fedushkin, V. G. Sokolov, V. M. Makarov, A. V. Cherkasov… in Russian Chemical Bulletin (2016)

  16. No Access

    Article

    Photorealistic volume scattering model in the bidirectional stochastic ray tracing problem

    This paper is devoted to the development of physically correct rendering model of scenes containing volume scattering objects. The solution of the rendering equation is based on the Monte-Carlo bidirectional r...

    D. D. Zhdanov, A. A. Garbul, I. S. Potemin… in Programming and Computer Software (2015)

  17. No Access

    Article

    Compounds of chromium, titanium, and zirconium with different reduced forms of acenaphthene-1,2-diimine

    The reaction of Cr(CO)6 with 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (1, dppbian) affords a chromium complex with the neutral diimine ligand (dpp-bian)Cr(CO)4 (2). The exchange reactions of the compound...

    I. L. Fedushkin, V. M. Makarov, V. G. Sokolov, G. K. Fukin… in Russian Chemical Bulletin (2014)

  18. No Access

    Article

    Holomorphy of coordinates with respect to eccentricities in the planetary three-body problem

    The boundaries of the domains of holomorphy of the coordinates of unperturbed elliptic motion with respect to the eccentricities of planetary orbits are determined for the cases when any of the five anomalies ...

    V. G. Sokolov in Solar System Research (2009)

  19. No Access

    Article

    Photocatalytic lithography with image inversion

    The feasibility of the inversion of metal images obtained by the chemical deposition of nickel onto Pd2+-loaded films of nanostructural TiO2 exposed to high irradiation doses has been demonstrated. This permits t...

    E. V. Skorb, V. G. Sokolov, T. V. Gaevskaya… in Theoretical and Experimental Chemistry (2009)

  20. No Access

    Article

    Photocatalytic lithography based on thin films of amorphous hydrated titanium dioxide

    The mechanism of photoactivation of amorphous hydrated titanium dioxide thin films containing palladium ions toward the reaction of electroless deposition of nickel was studied. It was shown that the photocata...

    E. V. Skorb, V. G. Sokolov, T. V. Byk, T. V. Gaevskaya… in High Energy Chemistry (2008)

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