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Article
Preparation of Model Rh–CeO2 Catalysts by Pulsed Laser Ablation in Liquid
The powders of Rh and CeO2 are synthesized by pulsed laser ablation in liquid. The Rh–CeO2 model catalysts are prepared by the calcination of these powders in a wide temperature range from 450 °C to 1000 °C. The ...
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Article
Effect of the Type of Active Component–Support Interaction on the Low-Temperature Activity of Metal–Oxide Catalysts in CO Oxidation
The Pt–SnOx, Pd–SnOx, and Au–SnOx composite catalysts were synthesized by pulsed laser ablation. The catalyst testing in the CO + O2 reaction showed that the action of the reaction medium can induce both partial ...
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Article
ACTIVATION OF Au–CeO2 COMPOSITES PREPARED BY PULSED LASER ABLATION IN THE REACTION OF LOW-TEMPERATURE CO OXIDATION
The Au/CeO2 composite catalyst is prepared by pulsed laser ablation in liquid (PLAL). Dispersions of gold and cerium are prepared in alcohol and water, respectively, mixed, dried, and annealed at various temperat...
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Article
A Study of Pt/Al2O3 Nanocomposites Obtained by Pulsed Laser Ablation to Be Used as Catalysts of Oxidation Reactions
Pulsed laser ablation (PLA) in liquids is an effective high-energy method for the synthesis of functional nanomaterials. In the present work, a nanocomposite catalyst Pt/Al2O3(PLA) is prepared by mixing solutions...
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Article
Platinum state in highly active Pt/CeO2 catalysts from the X-ray photoelectron spectroscopy data
The states of components of highly efficient Pt/CeO2 catalysts for low-temperature oxidation of carbon monoxide are studied in detail by X-ray photoelectron spectroscopy (XPS). Using the precise calibration of th...
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Article
Electrode modified by copper nanoparticles for ascorbic acid and dopamine simultaneous determination
In the present work it is proposed to modify a glassy carbon electrode by copper nanoparticles obtained by the laser ablation method. This modified electrode makes it possible to obtain separate peaks of ascor...
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Article
Carbon electrodes modified by metal nanoparticles obtained by laser ablation method in organic substances determination
Impregnated graphite electrodes surface modification by metal nanoparticles (Au, Pt, Pd, Ni, Cu) from ethanol colloids obtained by laser ablation of metal targets in liquid without stabilizing agents was carri...
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Article
Silver nanoparticles obtained by laser ablation as the active component of Ag/SiO2 catalysts for CO oxidation
Composite systems comprising a macroporous SiO2 support and silver nanoparticles preliminarily prepared by laser ablation in various liquids were synthesized and studied. Investigation of the catalytic properties...
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Article
Spectroscopy of the excited-state complex of zinc(II) with 3,3′-bis(dipyrrolylmethene)
Spectra of nonstationary transient absorption of metal bis(dipyrrolylmethene) complexes in cyclohexane and ethanol, which exhibit different photophysical and photochemical properties in these solvents, have be...
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Article
A setup for investigating the absorption spectra of dyes in excited states by the pump-probe method utilizing a fluorescence probe
An experimental setup for studying transient absorption spectra of organic dyes, which are excited with a high-power laser pulse, by the pump-probe method is described. Fluorescence of a mixture of organic-dye...
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Article
The formation of porous nickel-containing polyacrylate nanocomposites
The formation of porous nickel-polyacrylate nanocomposites (the sorption of nickel ions by a polyacrylate matrix followed by their reduction with thiourea dioxide) was studied. The kinetics of sorption of nick...
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Article
Structure and properties of organic nanocomposites for quantum electronics
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Article
Theoretic and Experimental Study of Photoprocesses in Substituted 4-Dicyanomethylene-4H-pyrans
The photoprocesses in substituted 4-dicyanomethylene-4H-pyran (DCM) derivatives were studied theoretically and experimentally. The experimental spectral and luminescent parameters of the molecules under study ...
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Article
Active media for tunable blue–green lasers based on aminocoumarins in polymethylmethacrylate
The lasing characteristics of 17 aminocoumarins in solutions and polymer polymethylmethacrylate (PMMA) matrix pumped by exciplex XeCl-laser radiation (λpump=308 nm) are investigated. It is demonstrated that 4-CF3
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Article
Phototransformations of Organic Compounds upon Powerful Laser Excitation under Nonlinear Absorption Conditions
Phototransformations, stationary- and induced-absorption spectra, and emission spectra of solutions of a dicarboxyalkyl derivative of p-terphenyl, as well as the transmission of exciting radiation from a XeCl las...
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Article
Phototransformations of Phenols in Aqueous Solutions under Different Excitation Modes
The photolysis of aqueous solutions of two widespread environmental organic ecotoxicants—phenol and 4-chlorophenol—on excitation by UV radiation from a KrCl exciplex laser and a glow-discharge KrCl excilplex l...
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Article
Solid-state active media of tunable organic-compound lasers pumped with a laser. I. An XeCl laser
The lasing properties of organic compounds in a polymethylmethacrylate matrix radiating in the blue-green (paraterphenyle and coumarine derivatives) and red (phodamine and phenalemine derivatives) regions of t...
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Article
Photolysis of Phenol and para-Chlorophenol by UV Laser Excitation
The photolysis of phenol and para-chlorophenol by irradiation with the fourth harmonic of a neodymium laser was examined using electronic absorption spectroscopy, fluorescence, and quantum-chemical techniques. It...