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Platinum state in highly active Pt/CeO2 catalysts from the X-ray photoelectron spectroscopy data

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Abstract

The states of components of highly efficient Pt/CeO2 catalysts for low-temperature oxidation of carbon monoxide are studied in detail by X-ray photoelectron spectroscopy (XPS). Using the precise calibration of the spectra relative to the internal standard and the fitting of Ce3d and Pt4f spectra by elementary doublets, we found the features of the platinum interaction with the ceria lattice. It is shown that when the codeposition technique is used, depending on the quality of stock solutions, it is possible to obtain both homogeneous solid solutions of platinum in the ceria lattice and solutions containing polyatomic platinum associates of the (PtO) m type. It is found that when homogeneous PtCeO x solid solutions are stored in air at room temperature, the homogeneous solutions slowly pass into the state of solutions with platinum associates. Mechanical mixtures of metallic platinum and ceria nanoparticles, synthesized by laser ablation, were also investigated in the course of their annealing in the air. The results obtained from the Pt4f spectra completely confirm the specific features of the interaction of platinum with ceria.

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References

  1. M. Shelef, Chem. Rev., 95, 209 (1995).

    Article  CAS  Google Scholar 

  2. W. Yu, M. Porosoff, and J. Chen, Chem. Rev., 112, 5780 (2012).

    Article  CAS  Google Scholar 

  3. Y. Zheng, Y. Zheng, Y. **ao, G. Cai, and K. Wei, Catal. Commun., 39, 1 (2013).

    Article  CAS  Google Scholar 

  4. G. K. Boreskov, Adv. Catal., 15, 285 (1965).

    Google Scholar 

  5. C. Doornkamp and V. Ponec, J. Mol. Catal. A Chem., 162, 19 (2000).

    Article  CAS  Google Scholar 

  6. A. Bruix, Ya. Lykhach, I. Matolínová, A. Neitzel, T. Skála, N. Tsud, M. Vorokhta, V. Stetsovych, K. Ševcíková, J. Myslivecek, R. Fiala, M. Václavu, K. C. Prince, St. Bruyère, V. Potin, F. Illas, V. Matolín, J. Libuda, and K. M. Neyman, Angew. Chem. Int. Ed. Engl., 53, 10525 (2014).

    Article  CAS  Google Scholar 

  7. C. T. Campbell, Nat. Chem., 4, 597 (2012).

    Article  CAS  Google Scholar 

  8. A. Gayen, K. R. Priolkar, P. R. Sarode, V. Jayaram, M. S. Hegde, G. N. Subbanna, and S. Emura, Chem. Mater., 16, 2317 (2004).

    Article  CAS  Google Scholar 

  9. E. M. Slavinskaya, R. V. Gulyaev, A. V. Zadesenets, O. A. Stonkus, V. I. Zaikovskii, Yu. V. Shubin, S. V. Korenev, and A. I. Boronin, Appl. Catal. B, 166/167, 91 (2015).

    Article  Google Scholar 

  10. P. Bera, K. C. Patil, V. Jayaram, G. N. Subbanna, and M. S. Hegde, J. Catal., 196, 293 (2000).

    Article  CAS  Google Scholar 

  11. M. S. Hegde and P. Bera, Catal. Today, 253, 40 (2015).

    Article  CAS  Google Scholar 

  12. K. Fugane, T. Mori, D. R. Ou, A. Suzuki, H. Yoshikawa, T. Masuda, K. Uosaki, Yo. Yamashita, Sh. Ueda, K. Kobayashi, N. Okazaki, I. Matolinova, and V. Matolin, Electrochim. Acta, 56, 3874 (2011).

    Article  CAS  Google Scholar 

  13. S. Gatla, D. Aubert, G. Agostini, O. Mathon, S. Pascarelli, T. Lunkenbein, M. G. Willinger, and H. Kaper, ACS Catal., 6, 6151 (2016).

    Article  CAS  Google Scholar 

  14. Practical Surface Analysis by Auger and X-Ray Photoelectron Spectroscopy, D. Briggs and M. P. Seah (eds.), John Wiley and Sons Ltd, Chichester (1983).

  15. O. Yu. Podyacheva, A. I. Stadnichenko, S. A. Yashnik, O. A. Stonkus, E. M. Slavinskaya, A. I. Boronin, A. V. Puzynin, and Z. R. Ismagilov, Chin. J. Catal., 35, 960 (2014).

    Article  CAS  Google Scholar 

  16. D. A. Svintsitskiy, L. S. Kibis, A. I. Stadnichenko, V. I. Zaikovskii, S. V. Koshcheev, and A. I. Boronin, Kinet. Catal., 54, 497 (2013).

    Article  CAS  Google Scholar 

  17. D. A. Svintsitskiy, L. S. Kibis, A. I. Stadnichenko, S. V. Koscheev, V. I. Zaikovskii, and A. I. Boronin, Chem. Phys. Chem., 16, 3318 (2015).

    Article  CAS  Google Scholar 

  18. E. M. Slavinskaya, T. Yu. Kardash, O. A. Stonkus, R. V. Gulyaev, I. N. Lapin, V. A. Svetlichnyi, and A. I. Boronin, Catal. Sci. Technol., 6, 6650 (2016).

    Article  CAS  Google Scholar 

  19. M. Romeo, K. Bak, J. El Fallah, F. Le Normand, and L. Hilaire, Surf. Interface Anal., 20, 508 (1993).

    Article  CAS  Google Scholar 

  20. I. G. Danilova, E. M. Slavinskaya, V. I. Zaikovskii, A. S. Ivanova, A. I. Boronin, R. V. Gulyaev, and Yu. I. Amosov, Kinet. Catal., 51, 143 (2010).

    Article  CAS  Google Scholar 

  21. R. V. Gulyaev, A. I. Stadnichenko, E. M. Slavinskaya, A. S. Ivanova, S. V. Koscheev, and A. I. Boronin, Appl. Catal. A Gen., 439/440, 41 (2012).

    Article  Google Scholar 

  22. F. Le Normand, J. El Fallah, L. Hilaire, P. Légaré, A. Kotani, and J. C. Parlebas, Solid State Commun., 71, 885 (1989).

    Article  Google Scholar 

  23. M. Vorokhta, I. Khalakhan, I. Matolínová, J. Nováková, S. Haviar, J. Lancok, M. Novotný, H. Yoshikawa, and V. Matolín, Appl. Surf. Sci., 396, 278 (2017).

    Article  CAS  Google Scholar 

  24. C. T. Campbell and C. H. F. Peden, Science, 309, 713 (2005).

    Article  CAS  Google Scholar 

  25. K. Wang, Y. Chang, L. Lv, and Y. Long, Appl. Surf. Sci., 351, 164 (2015).

    Article  CAS  Google Scholar 

  26. J. F. Moulder, W. F. Strickle, P. E. Sobol, and K. D. Bomben, A Reference Book of Standart Spectra for Identification and Interpretation of XPS Data, Perkin-Elmer Corporation Physical Electronics, Division, USA (1992).

    Google Scholar 

  27. L. Österlund, S. Kielbassa, C. Werdinius, and B. Kasemo, J. Catal., 215, 94 (2003).

    Article  Google Scholar 

  28. P. Bera, A. Gayen, M. S. Hegde, N. P. Lalla, L. Spadaro, F. Frusteri, and F. Arena, J. Phys. Chem. B, 107, 6122 (2003).

    Article  CAS  Google Scholar 

  29. S. Colussi, M. Boaro, L. De Rogatis, A. Pappacena, C. De Leitenburg, J. Llorca, and A. Trovarelli, Catal. Today, 253, 163 (2015).

    Article  CAS  Google Scholar 

  30. A. V. Kalinkin, M. Y. Smirnov, A. I. Nizovskii, and V. I. Bukhtiyarov, J. Electron Spectrosc. Relat. Phenom., 177, 15 (2010).

    Article  CAS  Google Scholar 

  31. A. I. Boronin, Kondensirovannye Sredy Mezhfaznye Granitsy, 2, No. 1, 4 (2000).

    Google Scholar 

  32. Jr. W. F. Egelhoff, Surf. Sci. Rep., 6, 253 (1987).

    Article  Google Scholar 

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. I. Stadnichenko, V. V. Murav’ev & A. I. Boronin

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    A. I. Stadnichenko, V. V. Murav’ev & A. I. Boronin

  3. Tomsk State University, Tomsk, Russia

    V. A. Svetlichnyi

Authors
  1. A. I. Stadnichenko
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  2. V. V. Murav’ev
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  3. V. A. Svetlichnyi
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  4. A. I. Boronin
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Corresponding author

Correspondence to A. I. Stadnichenko.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 6, pp. 1199–1207, July–August, 2017.

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Stadnichenko, A.I., Murav’ev, V.V., Svetlichnyi, V.A. et al. Platinum state in highly active Pt/CeO2 catalysts from the X-ray photoelectron spectroscopy data. J Struct Chem 58, 1152–1159 (2017). https://doi.org/10.1134/S0022476617060129

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  • DOI: https://doi.org/10.1134/S0022476617060129

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