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Open AccessThe importance of a charge transfer descriptor for screening potential CO2 reduction electrocatalysts
It has been over twenty years since the linear scaling of reaction intermediate adsorption energies started to coin the fields of heterogeneous and electrocatalysis as a blessing and a curse at the same time. ...
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Article
Open AccessA unifying mechanism for cation effect modulating C1 and C2 productions from CO2 electroreduction
Electrocatalysis, whose reaction venue locates at the catalyst–electrolyte interface, is controlled by the electron transfer across the electric double layer, envisaging a mechanistic link between the electron...
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Article
Open AccessOn the importance of the electric double layer structure in aqueous electrocatalysis
To design electrochemical interfaces for efficient electric-chemical energy interconversion, it is critical to reveal the electric double layer (EDL) structure and relate it with electrochemical activity; none...
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Article
Open AccessSelective electrochemical reduction of nitric oxide to hydroxylamine by atomically dispersed iron catalyst
Electrocatalytic conversion of nitrogen oxides to value-added chemicals is a promising strategy for mitigating the human-caused unbalance of the global nitrogen-cycle, but controlling product selectivity remai...
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Article
Confined local oxygen gas promotes electrochemical water oxidation to hydrogen peroxide
Electrochemical two-electron water oxidation is a promising route for renewable and on-site H2O2 generation as an alternative to the anthraquinone process. However, it is currently restricted by low selectivity d...
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Article
Open AccessDouble layer charging driven carbon dioxide adsorption limits the rate of electrochemical carbon dioxide reduction on Gold
Electrochemical CO \(_{2}\) 2 ...
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Article
Open AccesspH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper
We present a microkinetic model for CO(2) reduction (CO(2)R) on Cu(211) towards C2 products, based on energetics estimated from an explicit solvent model. We show that the differences in both Tafel slopes and pH ...