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Article
Polymeric lithium(I) diaquabarbiturate: Crystal structure
The lithium(I) catena-diaquabarbiturate complex [Li(H2O)2(HBA–O,O′)] n (I), where Н2ВА is barbituric acid, has been structurally characterized by X-ray diffraction (CIF file CCD...
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Article
Crystal structure and properties of polymeric hexaaqua-hexakis-(2-thiobarbiturato)-disamarium(III)
The structure (CIF file CCDC No. 1401886) of the hexaaqua-hexakis(2-thiobarbiturato)-disamarium [Sm2(H2O)6(HTBA)6] n polymeric complex (I), where H2ТВА is 2-thiobarbituric acid,...
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Article
Crystal structure and some properties of europium(III) Catena-{tris(1,3-diethyl-2-thiobarbiturate)}
The [Eu(HDTBA)3] n complex (I), HDTBA is 1,3-diethyl-2-thiobarbituric acid (C8H12N2O2S) is synthesized and its structure is determined by X-ray crystallography. The crystals of
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Article
New method for regulating the activity of ABO3 perovskite catalysts
A new possibility of changing the activity and selectivity of perovskite catalysts in the oxidative conversion of methane was demonstrated using the Sr x Gd1–x ...
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Article
Nature of the active sites of ferrospheres in the oxidative condensation of methane
The catalytic properties of ferrospheres containing 76–97 wt % Fe2O3 in the oxidative condensation of methane were compared with their phase composition and the distribution of iron cations over the crystallograp...
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Article
New approach to the preparation of catalysts for the oxidative coupling of methane
A new approach to the preparation of systems that exhibit catalytic activity in the oxidative coupling of methane (OCM) is considered. With the use of ferrospheres separated from power-generation ashes from di...
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Article
Helium permeability of microspherical membranes based on mullitized cenospheres
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Article
Hydrocarbon conversion on ZSM-5 in the presence of N2O: relative reactivity
Conversions of methane, ethane, propane, benzene and hydrogen were studied on HZSM-5 at 418°C using binary mixtures R1:R2:N2O:He (where R1, R2 are substances under study). Relative reactivities were determined, a...
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Article
Several features of the dealumination of type Y zeolite using silicon tetrachloride and ethylenediaminetetraacetic acid
Dealumination of type Y zeolite using SiCl4 produces a statistically averaged distribution of Al and Si atoms in the framework. The action of H4EDTA causes defects in the backbone and partial amorphization of the...
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Article
Peculiarities in oxidative conversion of methane to C2 hydrocarbons over CaO−CaCl2 catalysts
Experimental data for the oxidative dimerization of methane over CaO−CaCl2 systems indicate that C2 hydrocarbons are formed with the participation of chlorine generated by the catalyst surface under the effect of...
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Article
Conversion of ethane over zeolite catalysts in the presence of oxygen and nitrogen(I) oxide
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A study has been made of the relationship between the catalytic properties of pentasils and mordenite in the ...
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Article
Oxidative conversion of butane and pentane on superacid catalysts
Catalytic properties of AlBr3, AlBr3−CuCl2 and AlBr3−NiSO4 in liquid-phase conversion of butane and pentane have been examined. A possibility for the oxidative condensation has been revealed due to both the stoic...
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Article
Oxidative elongation of lower paraffins
It is shown that the oxidative condensation of ethane on CoMo/γ-Al2O3 catalysts is in principle possible. The conceivable paths of this reaction are analyzed.