Conclusions
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1.
A study has been made of the relationship between the catalytic properties of pentasils and mordenite in the oxidative conversion of ethane and the concentration of acid-base and one-electron sites in the decomposition of nitrogen(I) oxide.
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2.
A linear correlation was found in the C2H6-N2O system between the activity of the zeolites and the number of charge-transfer sites. The high activity of the zeolites studied in this system is due to the possibility of the oxidation of ethane occurring with the participation of atomic forms of oxygen. The absence of sites for the activation of oxygen in the atomic form is responsible for the low activity of zeolites in the C2H6-O2 system.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1718–1722, August, 1988.
The authors are grateful to K. G. Ione for graciously providing the high-silica zeolite samples.
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Vereshchagin, S.N., Baikalova, L.I. & Anshits, A.G. Conversion of ethane over zeolite catalysts in the presence of oxygen and nitrogen(I) oxide. Russ Chem Bull 37, 1529–1532 (1988). https://doi.org/10.1007/BF00961088
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DOI: https://doi.org/10.1007/BF00961088