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  1. No Access

    Article

    Linker-defect assisted catalytic fixation of CO2 in a dual-linker metal–organic framework

    We investigated the effect of linker defects induced by recycling MOF-508, a metal–organic framework with dual linkers, for the catalytic cycloaddition of the CO2 reaction. MOF-508 catalysts are characterized usi...

    Yunjang Gu, Sunghyun Yoon, Robin Babu… in Reaction Kinetics, Mechanisms and Catalysis (2024)

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    Article

    Synthesis and Characterization of Bimetallic ZnCo-ZIF-71 with Defect for an Efficient Catalytic CO2 Conversion

    A bimetallic zinc and cobalt zeolitic imidazolate framework (ZnCo-ZIF-71) catalyst was synthesized using metal acetate and 4,5-dichloroimidizole in a methanol solution. Various physicochemical analytical techn...

    Yunjang Gu, Sunghyun Yoon, Robin Babu… in Korean Journal of Chemical Engineering (2024)

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    Room temperature CO2 fixation via cyclic carbonate synthesis over vanadium-MOF catalysts

    Vanadium containing 3D MOF, MIL-47 displayed excellent synergistic catalysis with alkyl ammonium halides (TBAX) in the room temperature fixation of CO2. Theoretical intrinsic-reaction-coordinate calculations were...

    Roshith Roshan Kuruppathparambil, Robin Babu… in Korean Journal of Chemical Engineering (2019)

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    Article

    Zirconium-based isoreticular metal-organic frameworks for CO2 fixation via cyclic carbonate synthesis

    Two highly stable isoreticular metal-organic frameworks comprising chains of zirconium coordinated with linkers of 1,4-H2BDC (1,4-benzenedicarboxylic acid) and 4,4′-H2BPDC (4,4′-biphenyldicarboxylic acid), denote...

    Hye-Min Jeong, Roshith Roshan, Robin Babu… in Korean Journal of Chemical Engineering (2018)

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    Article

    Advancements in the Conversion of Carbon Dioxide to Cyclic Carbonates Using Metal Organic Frameworks as Catalysts

    Global warming has begun to show its impact on the environment, and it is time to take steps to manage CO2 emissions, so as to regain the balance of carbon cycle. In addition to various capture and sequestration ...

    Amal Cherian Kathalikkattil, Robin Babu, Jose Tharun… in Catalysis Surveys from Asia (2015)