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Article
Azadithiolate-bridged [FeFe]-hydrogenase mimics with bridgehead N-derivation: structural and electrochemical investigations
To further develop the active site mimics of azadithiolate-bridged [FeFe]-hydrogenases, a series of new diiron azadithiolate complexes [{(μ-SCH2)2N(C6H4CH2CH2OC(O)R)}Fe2(CO)6] (R = CH2C6H4Me-p, 2; C6H5, 3; CH3, 4
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Article
ADT-Type [FeFe]-hydrogenase biomimics featuring monodentate phosphines: formation, structures, and electrocatalysis
To further develop the diiron subsite biomimics of [FeFe]-hydrogenases, two new diiron azadithiolate (adt) complexes Fe2(μ-adtNPh)(CO)5(Ph2PX) (X = NHBut, 1 and P(O)Ph2, 2) featuring monodentate phosphines were u...
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Article
Novel P/N/Si/S-containing Mononickel Complex as a Metal-based Intumescent Flame Retardant for Cotton Fabrics
A new P/N/Si/S-containing mononickel complex NiS, which can be regarded as a rare type of the metal-based intumescent flame retardant, has been prepared through the condensation reaction of precursor NiCl with 1,...
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Article
Synthesis and structural characterization of iron–sulfur complexes with hydrophilic nitrogen–phosphorus ligands
Reaction of the parent complex (μ-PDT)Fe2-(CO)6 (A) (PDT = 1,3-SCH2CH2CH2S2−) with the bidentate N/P ligand [(Ph2P)2N(C6H4Cl-p)] in the presence of Me3NO as decarbonylating agent produced an unexpected iron–sulfu...
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Article
Synthesis, Characterization, and Crystal Structure of Tertiary Phosphine-Substituted Diiron Propanedithiolate Complexes
As the active site models of [FeFe]-hydrogenase, two new tertiary phosphine-substituted diiron propanedithiolate complexes [(μ-PDT)Fe2(CO)5L] (PDT = SCH2CH2CH2S, L = P(PhMe-m)3, 1; PPh2(CH2CH2CH3), 2) have been p...
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Article
Iron carbonyl cluster complexes with monophosphine ligands: synthesis, characterization, and crystal structure
Three new monophosphine-substituted iron carbonyl cluster complexes [(μ-PDT)Fe2(CO)5L] [(PDT = SCH2CH2CH2S, L = P(CH2Ph)3, 1; P(C6H11)3, 2; PPh2(PhMe-p), 3)], which can be regarded as active site mimics for [FeFe...
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Article
Synthetic and Structural Studies on Some New Butterfly Fe/S Cluster Complexes Containing 2,6-(CH2)2C5H3N or (CH2)2 Groups
Four new butterfly Fe/S cluster complexes bearing 2,6-(CH2)2C5H3N or (CH2)2 groups, as the active site models of [FeFe]-hydrogenase, have been prepared by condensation reaction and structurally characterized. Tre...
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Article
Calculation of dynamic loads of the sucker rod pum** system in CBM wells
The mathematical model of dynamic loads was developed based on an analysis of the polished rod load of beam pumps, and the variation of the dynamic loads and the computation of the minimum and maximum limits d...
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Article
Chemical constituents from the roots of Polygonum bistorta
Investigation of the roots of Polygonum bistorta L. afforded seven compounds including five triterpenoids, a coumarin, and a steroid, the structures of which were identified by EIMS, 1H NMR, 13C NMR, DEPT, and HM...