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Article
Quantum-Chemical Study of Proton Transfer and Photoreactions of Quinolone Derivatives
The possible routes of deactivation of electronically excited states of 4-methyl-7-hydroxy-2-quinolone and its protolytic forms were analyzed. The relative contribution of radiative and nonradiative deactivati...
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Article
Comparison of Vanillin and Isovanillin Photolysis in Aqueous Solutions
General kinetic regularities of reactions of stationary and laser photolysis of 3-methoxy-4-hydroxybenzaldehyde (vanillin) and 3-hydroxy-4-methoxybenzaldehyde (isovanillin) are investigated by the method of na...
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Article
Formation of the Titanium Oxide Surface by the Laser Ablation Method
It is demonstrated that the antibiotic therapy is the main therapy of infectious complications after surgical operations whose efficiency multiply increases due to the application of the mechanical suture in t...
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Article
Experimental and Quantum-Chemical Study of Electronically Excited States of Protolytic Isovanillin Species
Methods of electronic spectroscopy and quantum chemistry are used to compare protolytic vanillin and isovanillin species. Three protolytic species: anion, cation, and neutral are distinguished in the ground st...
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Article
Proteolytic Equilibria of Vanillic Acid in the Ground and Excited States
Proteolytic equilibria of vanillic acid in aqueous solutions were studied using electronic spectroscopy. The pH ranges for anionic, dianionic, cationic, and neutral forms of vanillic acid in the ground and exc...
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Article
Study of the Optical Spectra of 4-Hydroxy-3-Methoxibenzoic Acid
Using electronic spectroscopy and quantum chemistry methods, the electronic spectra of vanillic acid in various solvents are interpreted. In the ground electronic state, four protolytic forms of vanillic acid ...