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    Article

    Ligand Effects on the Reactivity of [CoX]+ (X = CN, F, Cl, Br, O, OH) Towards CO2: Gas-Phase Generation of the Elusive Cyanoformate by [Co(CN)]+ and [Fe(CN)]+

    The thermal reactions of [CoX]+ (X = CN, F, Cl, Br, O, OH) with carbon dioxide have been investigated experimentally and theoretically by using electrospray ionization mass spectrometry (ESI-MS) and density funct...

    Marjan Firouzbakht, Nicole J. Rijs, Maria Schlangen, Martin Kaupp… in Topics in Catalysis (2018)