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Article
Author Correction: Pentamethylcyclopentadienyl rhodium(iii)–chiral disulfonate hybrid catalysis for enantioselective C–H bond functionalization
In the version of this Article originally published, four important papers for transition metal/chiral anion asymmetric catalysis and 1,1'-binaphthyl-2,2'-disulfonate (BINSate) were erroneously omitted. These ...
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Article
Pentamethylcyclopentadienyl rhodium(III)–chiral disulfonate hybrid catalysis for enantioselective C–H bond functionalization
Though Cp*Rh(iii) complexes are prominent and versatile catalysts for C–H bond functionalization reactions, catalytic stereocontrol is difficult due to the lack of vacant coordination sites. Here, we report a hyb...
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Chapter
Brønsted Acid/Lewis Base Hybrid Complexes
Recent progress on our Brønsted acid/Lewis base hybrid complexes in some asymmetric catalyses is reviewed. Based on the rational design of conjugated acid–base catalysts, tailor-made supramolecular catalysts c...
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Article
Epidermal growth factor receptor-transfected bone marrow stromal cells exhibit enhanced migratory response and therapeutic potential against murine brain tumors
We have created a novel cellular vehicle for gene therapy of malignant gliomas by transfection of murine bone marrow stroma cells (MSCs) with a cDNA encoding epidermal growth factor receptor (EGFR). These cell...
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Chapter
Active Pd(II) Complexes as Either Lewis Acid Catalysts or Transition Metal Catalysts
The new frontier of asymmetric catalyses by Pd(II) complexes is reviewed. Asymmetric catalyses of carbon–carbon bond formation by Pd(II) complexes are divided into transition metal catalysis and Lewis acid cat...
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Article
Open AccessVaccination with EphA2-derived T cell-epitopes promotes immunity against both EphA2-expressing and EphA2-negative tumors
A novel tyrosine kinase receptor EphA2 is expressed at high levels in advanced and metastatic cancers. We examined whether vaccinations with synthetic mouse EphA2 (mEphA2)-derived peptides that serve as T cell...
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Article
Two Different Mechanisms of Apoptosis Resistance Observed in Interferon-β Induced Apoptosis of Human Glioma Cells
Interferon (IFN)-β is known to exert cytostatic or cytocidal effects in human glioma cells and is widely used in the treatment for gliomas. However, precise mechanisms of cell death induced by IFN-β are not we...