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Article
Near-threshold photoionization from the excited mp5(m + 1)p J = 0−3 levels of Ar, Kr and Xe (m = 3−5)
Using the configuration interaction Pauli-Fock including core polarization (CIPFCP) approach we have calculated absolute total and partial cross sections for photoionization of excited mp ...
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Article
Odd autoionizing 2p1/2 5n(s′/d′) resonances of Ne excited from the 2p53p[K]J states
Absolute photoionization cross sections for Ne atoms in the excited \(2{p}^{5}3{p}[K]_{J}~(J=0\!\!-\!\!3)\) levels (Pas...
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Article
High resolution study of anion formation in low-energy electron attachment to SF6 molecules in a seeded supersonic beam
Using two variants of the Laser Photoelectron Attachment (LPA) method involving a differentially-pumped, seeded supersonic beam (0.05% and 12.5% of SF6 molecules in helium carrier gas, nozzle temperatures T0= ...
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Article
Efficient long-term laser excitation of a collimated beam of potassium atoms on the D2 line
With the aim to provide a reliable scheme for efficient laser excitation of the potassium D2 line over long periods of time, we have developed a robust stabilization of a single mode laser of frequency f ...
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Article
A novel electron scattering apparatus combining a laser photoelectron source and a triply differentially pumped supersonic beam target: characterization and results for the resonance
A novel electron scattering apparatus for high resolution studies of angle-differential elastic and inelastic electron scattering from atoms and molecules in the gas phase is described and its performance char...
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Article
Vibrational Feshbach resonances in electron attachment to carbon dioxide clusters
Using a high resolution ( meV) laser photoelectron attachment method, we have studied the formation of (CO 2) q − ions (q = 4−22) in collisio...
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Article
Effects of solvation on dissociative electron attachment to methyl iodide clusters
Using laser photoelectron attachment to methyl iodide clusters in a differentially-pumped seeded supersonic helium beam and mass spectrometric ion detection, we have measured the rate coefficients for formatio...
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Article
Formation of small water cluster anions by attachment of very slow electrons at high resolution
Using a high resolution laser photoelectron attachment method, we have studied the formation of (H 2 O) q - (q = 2, 6, 7, 11, 15) cluster i...
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Article
Diatomic potential well depths from analyses of high-resolution electron energy spectra for autoionizing collision complexes
High-resolution energy spectra of electrons released in Penning ionization collisions of metastable rare gas atoms Rg*(ns) (Rg = He, Ne, Ar, Kr, Xe) with several open-shell and closed-shell atoms are analyzed to...
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Article
Rydberg electron transfer to C60 and C70
Experimental results are reported for the attachment of Ar* * (nl) Rydberg electrons to C60 and C70 over the range n = 19–270. In agreement with other Rydberg work we find that the rate coefficient for C ...
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Article
The interaction of metastable helium atoms with alkaline earth atoms: He*(23 S,21 S)+Mg, Ca, Sr and Ba
We have carried out experimental and theoretical studies of Penning ionization processes occurring in thermal energy collisions of state-selected metastable He*(23 S) and He*(21 ...
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Article
Comparison of rate coefficients for rydberg electron and free electron attachment
New experimental results on attachment reactions involving free electrons at sub-meV resolution allow for the first time a conclusive comparison of measured rate coefficients for Rydberg electron attachment wi...
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Article
Angle-dependent electron energy spectra resulting from autoionizing Ne⋆ (3s 3 P 2) +H(12 S) collisions
Experimental angle-dependent electron energy spectra for the autoionization complex Ne*(3s 3 P 2)+H(12 S), leading to Penning and associative ionization, are reported. The data, measured at thermal collision ener...
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Article
Penning ionization electron spectrometry of hydrogen iodide
The energy spectra of electrons released in thermal energy ionizing collisions of metastable helium and neon atoms with hydrogen iodide have been measured with high resolution and low background. The electron ...
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Article
Energy exchanges following very low energy electron attachment to neat CS2 and CS2-containing clusters
We have studied electron transfer from state-selected Rydberg atoms to (CS2) N and CS2(Ar) N clusters and compared the results to Rydberg elec...
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Article
Penning ionization and photoionization electron spectrometry of hydrogen fluoride
An electron spectrometric study has been performed on HF using metastable helium and neon atoms as well as helium and neon resonance photons. High-resolution electron spectra were obtained for a pure He(23 S) bea...
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Article
On theJ-dependence of the odd (ns′,J=0,1) autoionization resonances of the rare gases Ne, Ar, Kr, and Xe
Using resonant two-photon ionization of metastable rare gas atoms Rg(mp 5(m + 1)s 3 P 2,0) in a collimated beam by two transverse cw dye lasers, we have performed a comprehensive high resolution study of the odd ...
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Article
Effective absolute rate constant for the formation of negatively-charged CO2 cluster ions by electron transfer from state-selected Rydberg atoms
We have studied electron transfer from state-selected Ar** (nd) Rydberg atoms to (CO2) m clusters for 12≦n≦48. The relative rate constant for the total negative ion formation re...
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Article
Penning ionization and photoionization electron spectrometry of hydrogen bromide
An electron spectrometric study has been performed on HBr using metastable helium and neon atoms as well as helium resonance photons. High resolution electron spectra were obtained for a mixed He(21 S, 23 S) beam...
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Article
Experimental and theoretical studies of the Bi-excited collision systems He*(23 S) + He*(23 S, 21 S) at thermal and subthermal kinetic energies
We have carried out a comprehensive experimental and theoretical investigation of the autoionizing collision systems He*(23 S, 21 S) + He*(23 S). We present high resolution electron energy spectra, obtained with ...