![Loading...](https://link.springer.com/static/c4a417b97a76cc2980e3c25e2271af3129e08bbe/images/pdf-preview/spacer.gif)
-
Article
Open AccessControl of proton transport and hydrogenation in double-gated graphene
The basal plane of graphene can function as a selective barrier that is permeable to protons1,2 but impermeable to all ions3,4 and gases5,6, stimulating its use in applications such as membranes1,2,7,8, catalysis
-
Article
Open AccessProton and molecular permeation through the basal plane of monolayer graphene oxide
Two-dimensional (2D) materials offer a prospect of membranes that combine negligible gas permeability with high proton conductivity and could outperform the existing proton exchange membranes used in various a...
-
Article
Open AccessGate-controlled suppression of light-driven proton transport through graphene electrodes
Recent experiments demonstrated that proton transport through graphene electrodes can be accelerated by over an order of magnitude with low intensity illumination. Here we show that this photo-effect can be su...
-
Article
Open AccessProton transport through nanoscale corrugations in two-dimensional crystals
Defect-free graphene is impermeable to all atoms1–5 and ions6,7 under ambient conditions. Experiments that can resolve gas flows of a few atoms per hour through micrometre-sized membranes found that monocrystalli...
-
Article
Open AccessWien effect in interfacial water dissociation through proton-permeable graphene electrodes
Strong electric fields can accelerate molecular dissociation reactions. The phenomenon known as the Wien effect was previously observed using high-voltage electrolysis cells that produced fields of about 107 V m−...
-
Article
Open AccessExponentially selective molecular sieving through angstrom pores
Two-dimensional crystals with angstrom-scale pores are widely considered as candidates for a next generation of molecular separation technologies aiming to provide extreme, exponentially large selectivity comb...
-
Article
Limits on gas impermeability of graphene
Despite being only one-atom thick, defect-free graphene is considered to be completely impermeable to all gases and liquids1–10. This conclusion is based on theory3–8 and supported by experiments1,9,10 that could...
-
Article
Atomically thin micas as proton-conducting membranes
Monolayers of graphene and hexagonal boron nitride (hBN) are highly permeable to thermal protons1,2. For thicker two-dimensional (2D) materials, proton conductivity diminishes exponentially, so that, for example,...
-
Article
Open AccessPerfect proton selectivity in ion transport through two-dimensional crystals
Defect-free monolayers of graphene and hexagonal boron nitride are surprisingly permeable to thermal protons, despite being completely impenetrable to all gases. It remains untested whether small ions can perm...
-
Article
Transport of hydrogen isotopes through interlayer spacing in van der Waals crystals
Atoms start behaving as waves rather than classical particles if confined in spaces commensurate with their de Broglie wavelength. At room temperature this length is only about one ångström even for the lighte...
-
Article
Open AccessScalable and efficient separation of hydrogen isotopes using graphene-based electrochemical pum**
Thousands of tons of isotopic mixtures are processed annually for heavy-water production and tritium decontamination. The existing technologies remain extremely energy intensive and require large capital inves...
-
Article
Molecular transport through capillaries made with atomic-scale precision
Nanometre-scale graphitic capillaries with atomically flat walls are engineered and studied, revealing unexpectedly fast transport of liquid water through channels that accommodate only a few layers of water.
-
Article
Proton transport through one-atom-thick crystals
Measurements show that monolayers of graphene and hexagonal boron nitride are unexpectedly highly permeable to thermal protons and that their conductivity rapidly increases with temperature, but that no proton...