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Article
A new polyoxovanadium supramolecular complex [(N(CH2CH2NH3)3)2(V6O18)]·3H2O: Synthesis, structure, and thermal properties
A new polyoxovanadium supramolecular complex, [(N(CH2CH2NH3)3)2(V6O18)]·3H2O (1), was synthesized as a crystalline product from aqueous solution at room temperature. From single crystal X-ray structural analysis,...
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Article
Synthesis, structure, luminescence properties, quantum chemistry and cytotoxic effects of two vanadium(IV) complexes with polypyrazolylborates, HB(pz)3VO(acac) and HB(3,5-Me2pz)3VO(acac)·CH3CN (pz = pyrazole)
The reaction of VO(acac)2 (acac = acetylacetonate) with NaHB(pz)3 (pz = pyrazole) or NaHB(3,5-Me2pz)3 in methanol gave vanadium(IV) complexes HB(pz)3VO(acac) (1) or HB(3,5-Me2pz)3VO(acac)·CH3CN (2), respectively....