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A new polyoxovanadium supramolecular complex [(N(CH2CH2NH3)3)2(V6O18)]·3H2O: Synthesis, structure, and thermal properties

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Abstract

A new polyoxovanadium supramolecular complex, [(N(CH2CH2NH3)3)2(V6O18)]·3H2O (1), was synthesized as a crystalline product from aqueous solution at room temperature. From single crystal X-ray structural analysis, the complex is monoclinic, space group P21/n, with a = 15.878(2) Å,b = 11.3309(15) Å, c = 19.469(3) Å, β = 102.244(2)°, V = 3423.0(8) Å3, Z = 4, final R = 0.0469. The crystal structure comprises 1D spiral vanadate chain as the oxide moiety, doubly protonated cations of tris(2-aminoethyl)amine (tren) and three lattice molecules of water. There are numerous H bonds in the structure connecting the polyoxovanadium anion moiety, protonated tren cation and lattice water molecules; the average O...O and N...O distances are 2.753 Å for O-H...O and 2.879 Å for N-H...O, respectively.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Huanghe Road 850#, Dalian, 116029, P.R. China

    J. Li, Y. H. **ng, C. G. Wang, Z. P. Li & S. Y. Niu

  2. Institute of Chemistry, Chinese Academy of Sciences, Bei**g, 100080, P.R. China

    M. F. Ge

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  1. J. Li
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  2. Y. H. **ng
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  3. M. F. Ge
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  4. C. G. Wang
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  5. Z. P. Li
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  6. S. Y. Niu
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Correspondence to Y. H. **ng.

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Original Russian Text Copyright © 2009 by J. Li, Y. H. **ng, M. F. Ge, C. G. Wang, Z. P. Li, and S. Y. Niu

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 50, No. 3, pp. 553–559, May–June, 2009.

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Li, J., **ng, Y.H., Ge, M.F. et al. A new polyoxovanadium supramolecular complex [(N(CH2CH2NH3)3)2(V6O18)]·3H2O: Synthesis, structure, and thermal properties. J Struct Chem 50, 532–538 (2009). https://doi.org/10.1007/s10947-009-0081-4

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  • DOI: https://doi.org/10.1007/s10947-009-0081-4

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