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Article
A hybrid ray-wave optics model to study the scattering behavior of silver metallic paint systems
The gonioapparent lightness of a metallic paint system depends strongly on the 3D microstructure of the platelet-containing basecoat layer, and on the platelet roughness. Current optical models which are used ...
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Article
The characterization and effects of microstructure on the appearance of platelet–polymer composite coatings
Although color and appearance have a psychological component, they are material properties that can be of considerable significance and economic importance to designers. Paint systems are materials that have a...
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Article
Migration of hindered amine light stabilizers in automotive clearcoats
The diffusion behavior of two hindered amine light stabilizers (HALS) [bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl)-sebacate and bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-sebacate] in an automotive clearco...
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Article
Long-term weathering behavior of UV-curable clearcoats: Depth profiling of photooxidation, UVA, and HALS distributions
The long-term weathering performance of two UV-curable clearcoat systems was studied using in-plane microtomy in combination with infrared spectroscopy, UV spectroscopy, and ESR spectroscopy. Oxygen transport ...
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Article
Testing accelerated weathering tests for appropriate weathering chemistry: Ozone filtered xenon arc
Ftir spectroscopy has been used to follow the weathering chemistry of a HALS and UVA free polyester/urethane and a HALS and UVA free acrylic/melamine clearcoat cured on silicon wafers and subject...
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Article
On the combined use of UVA, HALS, photooxidation, and fracture energy measurements to anticipate the long-term weathering performance of clearcoat/basecoat automotive paint systems
Transmission UV spectroscopy measurements of clearcoat ul traviol et light absorber (UVA) disposition, electronspin resonance (ESR) spectroscopy measurements of clearcoat and basecoat Active hindered amine lig...
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Article
Effect of weathering on the stress distribution and mechanical performance of automotive paint systems
The sources of stress in complete automative paint systems have been identified and measured as a function of weathering. In addition to the stresses developed during cure, the main sources of stresses develop...
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Article
The toughness of epoxy-poly(butylene terephthalate) blends
Blends containing 5% poly(butylene terephthalate) (PBT) in an anhydride-cured epoxy with three different PBT morphologies were studied. The three morphologies were a dispersion of spherulites, a structureless ...