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Article
Photocatalytic nitrogen fixation over flower-like molecular cobalt phthalocyanine@ZnIn2S4 heterojunctions under visible-light irradiation
Molecular catalysts (such as metal phthalocyanine (Pc) molecules) have been widely utilized in homogeneous catalytic systems. However, its practical application is still hindered by the weak stability and diff...
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Article
Open AccessRetrosynthesis of multi-component metal−organic frameworks
Crystal engineering of metal−organic frameworks (MOFs) has allowed the construction of complex structures at atomic precision, but has yet to reach the same level of sophistication as organic synthesis. The sy...
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Article
Open AccessConstruction of hierarchically porous metal–organic frameworks through linker labilization
A major goal of metal–organic framework (MOF) research is the expansion of pore size and volume. Although many approaches have been attempted to increase the pore size of MOF materials, it is still a challenge...
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Article
Open AccessAn unprecedented (3,4,24)-connected heteropolyoxozincate organic framework as heterogeneous crystalline Lewis acid catalyst for biodiesel production
A novel 3D hexadecanuclear heteropolyoxozincate organic framework, IFMC-200, has been successfully synthesized based on a late transition metal-oxygen cluster. IFMC-200 not only represents the first example of...