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Article
Thermodynamic parameters of liquid ternary Fe1−x(Ni5/6Cr1/6)x alloys
Computer-aidedKnudsen cell mass spectrometry is used for thermodynamic investigations on liquid ternary Fe1−x(Ni5/6Cr1/6)x alloys. The thermodynamic excess properties have been determined by means of the Digital ...
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Article
The margules concept: The basis of modern Algebraic representations of thermodynamic excess properties
A modern description of molar excess properties is reducible to the Margules concept of representing the partial pressure of the components of mixtures by power series. Unifying to a common parameter set for r...
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Article
Thermodynamic mixing functions and phase equilibria in the nickel-chromium system by high-temperature knudsen cell mass spectrometry
Thermodynamic excess functions of nickel-chromium alloys in the body-centered cubic (bcc) phase have been investigated by computer-aided Knudsen cell mass spectrometry in the tem-perature range of 1300 to 1650...
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Article
Computer- aided determination of the molar excess heat capacity, ACP(T,X), from calorimetric data
All traditional evaluation techniques for determining the temperature,T, concentration,X, dependences of the molar excess heat capacity, ΔCP (T,X), from calorimetric data involve the problem that the molar excess...
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Article
Ein Knudsenzellen-Monopolmassenspektrometer für den Einsatz in der Hochtemperaturthermodynamik
A high temperature Knudsen cell was combined with a monopol mass spectrometer model MX 7304 with the ion source 1560014-T01 (Electron, Ukraine) despite the fact that these apparates have been designed for appl...
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Article
Thermodynamic parameters of liquid gold-aluminum alloys
Thermodynamic activities and, enthalpies for Au−Al alloys have been measured by Knudsen-cell mass spectrometry, independently using closely similar techniques in laboratories in Vienna and Strathclyde. The res...