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Article
Kinetics of the Hydrogenation of α-Pinene to cis- and trans-Pinanes on Pd/C
The liquid-phase hydrogenation of α-pinene on a Pd/C catalyst at 0–100°С and hydrogen pressures of 1–11 atm was studied. It was found that the order of reaction with respect to pinene increased with hydrogen p...
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Article
Kinetics of the Hydrogenation of Pinane Hydroperoxide to Pinanol on Pd/C
The liquid-phase hydrogenation of pinane hydroperoxide (PHP) to pinanol on a Pd/C catalyst at 20–80°C and hydrogen pressures of 1–11 atm was studied. It was found that the rate of hydrogenation decreased with ...
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Article
Kinetics of 2-Pinanol Isomerization to Linalool on the Monolith Carbon-Containing Catalyst
Isomerization of 2-pinanol into linalool is studied on a monolith carbon-containing catalyst at 733–893 and a total pressure of 2–40 torr. The rate constants of cis(trans)-2-pinanol transformation into linalool a...
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Article
Kinetics of Pinane Oxidation to Pinane Hydroperoxide by Dioxygen
The liquid-phase oxidation of pinane to pinane hydroperoxide (PHP) by dioxygen is studied at 353–373 K and under dioxygen pressures ranging from 2 to 4 atm. The rate of pinane oxidation is described by the equ...