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Article
Effect of Aminosilane Compounds as External Donors on Isospecific Polymerizations of 1-Butene with MgCl2/TiCl4/DIBP Catalyst
Four aminosilane compounds were synthesized and employed as external electron donors for 1-butene polymerization with MgCl2 supported Ziegler-Natta catalyst. The four aminosilane compounds are di(piperidinyl)dime...
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Article
Isospecific polymerizations of 1-butene catalyzed by MgCl2/TiCl4/internal donor-AlR3/external donor system
1-Butene polymerizations were carried out by using a MgCl2/TiCl4/ID-AlR3/ED catalyst system in n-hexane, therein the internal donor (ID) is diisobutyl phthalate (DIBP), the external donor (ED) is diphenyl dimetho...
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Article
Copolymerizations of ethylene with 1-hexene over MgCl2/SiO2 Bi-supported titanium catalysts: Effect of SiO2 on active site distribution
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Article
Effect of internal lewis base on active site distribution for ethylene/1-octene copolymerization by TiCl4/lewis base/MgCl2 catalysts