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  1. Article

    Open Access

    Borate–pyran lean electrolyte-based Li-metal batteries with minimal Li corrosion

    Engineering liquid electrolytes for lithium (Li)-metal electrodes has been used to control the morphology of deposited Li in Li-metal batteries (LMBs). However, the Li corrosion problem remains unresolved, hin...

    Hyeok** Kwon, Hongsin Kim, Jaemin Hwang, Wonsik Oh, Youngil Roh in Nature Energy (2024)

  2. No Access

    Article

    Leaching organics from the interphase

    In lithium metal batteries, the organic-rich solid electrolyte interphase that forms on the lithium metal electrode in carbonate electrolytes is unable to passivate the electrode surface against lithium corros...

    Hee-Tak Kim in Nature Energy (2023)

  3. Article

    Open Access

    Weakly coordinated Li ion in single-ion-conductor-based composite enabling low electrolyte content Li-metal batteries

    The pulverization of lithium metal electrodes during cycling recently has been suppressed through various techniques, but the issue of irreversible consumption of the electrolyte remains a critical challenge, ...

    Hyeok** Kwon, Hyun-Ji Choi, Jung-kyu Jang, **hong Lee in Nature Communications (2023)

  4. Article

    Open Access

    An electron-deficient carbon current collector for anode-free Li-metal batteries

    The long-term cycling of anode-free Li-metal cells (i.e., cells where the negative electrode is in situ formed by electrodeposition on an electronically conductive matrix of lithium sourced from the positive e...

    Hyeok** Kwon, Ju-Hyuk Lee, Youngil Roh, Jaewon Baek in Nature Communications (2021)

  5. Article

    Open Access

    Catalytic production of impurity-free V3.5+ electrolyte for vanadium redox flow batteries

    The vanadium redox flow battery is considered one of the most promising candidates for use in large-scale energy storage systems. However, its commercialization has been hindered due to the high manufacturing ...

    Jiyun Heo, Jae-Yun Han, Soohyun Kim, Seongmin Yuk, Chanyong Choi in Nature Communications (2019)

  6. Article

    Open Access

    Achieving three-dimensional lithium sulfide growth in lithium-sulfur batteries using high-donor-number anions

    Uncontrolled growth of insulating lithium sulfide leads to passivation of sulfur cathodes, which limits high sulfur utilization in lithium-sulfur batteries. Sulfur utilization can be augmented in electrolytes ...

    Hyunwon Chu, Hyungjun Noh, Yun-Jung Kim, Seongmin Yuk, Ju-Hyuk Lee in Nature Communications (2019)

  7. Article

    Open Access

    Dispersion-Solvent Control of Ionomer Aggregation in a Polymer Electrolyte Membrane Fuel Cell

    In this study, we examined the influence of the dispersion solvent in three dipropylene-glycol/water (DPG/water) mixtures, with DPG contents of 0, 50, and 100 wt%, on ionomer morphology and distribution, using...

    Ji Hye Lee, Gisu Doo, Sung Hyun Kwon, Sungyu Choi, Hee-Tak Kim in Scientific Reports (2018)

  8. Article

    Open Access

    Ultrathin Nafion-filled porous membrane for zinc/bromine redox flow batteries

    In this work, we present a 16 μm-thick Nafion-filled porous membrane for Zn/Br redox flow batteries (ZBBs). By using molecular dynamics simulation and dynamic light scattering analysis, we rationally design Na...

    Riyul Kim, Hyun Gyu Kim, Gisu Doo, Chanyong Choi, Soohyun Kim in Scientific Reports (2017)

  9. Article

    Open Access

    Structural modulation of lithium metal-electrolyte interface with three-dimensional metallic interlayer for high-performance lithium metal batteries

    The use of lithium (Li) metal anodes has been reconsidered because of the necessity for a higher energy density in secondary batteries. However, Li metal anodes suffer from ‘dead’ Li formation and surface deac...

    Hongkyung Lee, Jongchan Song, Yun-Jung Kim, Jung-Ki Park, Hee-Tak Kim in Scientific Reports (2016)

  10. No Access

    Article

    Homogeneously Dispersed Silver Nanoparticles in EVA Laminating Film for Efficiency Enhancement of Silicon Photovoltaic Cells

    We present a simple yet high-throughput approach for placing homogeneously dispersed silver nanoparticles (AgNPs) onto the top surface of a photovoltaic cell which can improve power conversion efficiency of a ...

    Chang Kyu Son, Hong Suk Kang, ** Woo Kim, Hongkyung Lee in Macromolecular Research (2016)

  11. Article

    Open Access

    Tuning selectivity of electrochemical reactions by atomically dispersed platinum catalyst

    Maximum atom efficiency as well as distinct chemoselectivity is expected for electrocatalysis on atomically dispersed (or single site) metal centres, but its realization remains challenging so far, because car...

    Chang Hyuck Choi, Minho Kim, Han Chang Kwon, Sung June Cho in Nature Communications (2016)

  12. Article

    Open Access

    Ionomer-Liquid Electrolyte Hybrid Ionic Conductor for High Cycling Stability of Lithium Metal Electrodes

    The inhomogeneous Li electrodeposition of lithium metal electrode has been a major impediment to the realization of rechargeable lithium metal batteries. Although single ion conducting ionomers can induce more...

    Jongchan Song, Hongkyung Lee, Min-Ju Choo, Jung-Ki Park, Hee-Tak Kim in Scientific Reports (2015)

  13. No Access

    Article

    Multilayered separator based on porous polyethylene layer, Al2O3 layer, and electro-spun PVdF nanofiber layer for lithium batteries

    With an aim to enhance the thermal stability and electrolyte wetting of a polyethylene porous separator, an Al2O3 nano-powder layer and an electro-spun PVdF nanofiber layer were successively formed on both sides ...

    Min-Young An, Hee-Tak Kim, Duck-Rye Chang in Journal of Solid State Electrochemistry (2014)

  14. Article

    Mechanism of Photo-Induced Liquid Crystal Alignment on a Poly(vinyl cinnamate) Thin Layer

    The mechanism of photo-induced liquid crystal (LC) alignment on a poly(vinyl cinnamate) (PVCi) thin layer was studied. By spectral analysis for the polarized UV spectra of the PVCi thin layer exposed to a pola...

    Hee-Tak Kim, Jong-Woo Lee, Shi-Joon Sung, Jung-Ki Park in Polymer Journal (2001)

  15. Article

    Development of In-Plane Orientation in Pyromellitic Dianhydride-Oxydianiline Polyimide Film on Substrate during Thermal Imidization

    The development of in-plane orientation in pyromellitic dianhydride-oxydianiline (PMDA-ODA) polyimide film coated on silicon substrate during thermal imidization was investigated by means of FT-IR spectroscopy...

    Hee Tak Kim, Sang-Kyung Kim, Jung-Ki Park in Polymer Journal (1999)

  16. No Access

    Article

    Thermal and electrochemical characteristics of plasticized polymer electrolytes based on poly(acrylonitrile-co-methyl methacrylate)

    The thermal and electrochemical characteristics of plasticized polymer electrolytes composed of poly(acrylonitrile-co-methyl methacrylate) [P(AN-co-MMA)], a plasticizer [a mixture of ethylene carbonate and propy...

    Hee-** Ryoo, Hee-Tak Kim, Young-Gi Lee in Journal of Solid State Electrochemistry (1998)

  17. No Access

    Article

    Thermal degradation of poly(vinyl cinnamate)

    Hee-Tak Kim, Jung-Ki Park in Polymer Bulletin (1998)

  18. Article

    Effects of Thermal Curing on the Structure of Polyimide Film

    The effects of thermal curing method on degree of imidization, molecular orientation, and chain ordering of the 4,4-oxydiphenylene pyromellitimide (PMDA-ODA) were investigated. Three different thermal curing m...

    Sang-Kyung Kim, Hee-Tak Kim, Jung-Ki Park in Polymer Journal (1998)

  19. Article

    Effect of Imidization Temperature and Spinning Condition on Structure of Polyimide Film Derived from Cyclobutanedianhydride and 2,2-Bis(4-aminophenoxyphenyl)propane

    The polyimide derived from cyclobutanedianhydride and 2,2-bis(4-aminophenoxyphenyl)propane (CBDA-BAPP) is one of the typical materials for liquid crystal alignment layer in liquid crystal display (LCD). The ef...

    Hee-Tak Kim, Jung-Ki Park in Polymer Journal (1997)

  20. No Access

    Article

    Poly(oligo-oxyethylene methacrylate-co-alkali metal acrylamidocaproate) as a single ion conductor

    The new single ion conductors, poly(oligo-oxyethylene methacrylate-co-alkali metal acrylamidocaproic acid) ((CH2CCH3COO(CH2CH2O)9H)x−(CH2CHCONH(CH2)5 COO-M+)1-x), M+=Li+, Na+, K+, were synthesized and the effects...

    Hee-Tak Kim, Jung-Ki Park in Polymer Bulletin (1996)

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