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Article
Open AccessBranching mechanism of photoswitching in an Fe(II) polypyridyl complex explained by full singlet-triplet-quintet dynamics
It has long been known that irradiation with visible light converts Fe(II) polypyridines from their low-spin (singlet) to high-spin (quintet) state, yet mechanistic interpretation of the photorelaxation remain...
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Article
Open AccessVibrational wavepacket dynamics in Fe carbene photosensitizer determined with femtosecond X-ray emission and scattering
The non-equilibrium dynamics of electrons and nuclei govern the function of photoactive materials. Disentangling these dynamics remains a critical goal for understanding photoactive materials. Here we investig...
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Article
Open AccessTracking multiple components of a nuclear wavepacket in photoexcited Cu(I)-phenanthroline complex using ultrafast X-ray spectroscopy
Disentangling the strong interplay between electronic and nuclear degrees of freedom is essential to achieve a full understanding of excited state processes during ultrafast nonadiabatic chemical reactions. Ho...
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Article
Open AccessVisualizing the non-equilibrium dynamics of photoinduced intramolecular electron transfer with femtosecond X-ray pulses
Ultrafast photoinduced electron transfer preceding energy equilibration still poses many experimental and conceptual challenges to the optimization of photoconversion since an atomic-scale description has so f...
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Article
Tracking excited-state charge and spin dynamics in iron coordination complexes
Femtosecond resolution X-ray fluorescence spectroscopy is shown to track the charge and spin dynamics triggered when an iron coordination complex is excited by light, and establishes the critical role of inter...
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Article
Intermediate-spin ferrous iron in lowermost mantle post-perovskite and perovskite
The Earth’s lowermost mantle displays an important mineralogical transition from perovskite to post-perovskite but the spin state of iron in these phases remains poorly known. Experimental results suggest that...
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Article
Foreword
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Chapter and Conference Paper
Investigations on Structure and Transformation of Some Organometallic Compounds in Solution
Earlier NMR investigations revealed that the tetrameric [Me3SnL]4 compound [Me = methyl group, CH3; L = cupferronato anion, PhN2(O)O−] falls apart to monomeric units in chloroform solution. Comparison of Mössbaue...
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Article
Investigations on Structure and Transformation of Some Organometallic Compounds in Solution
Earlier NMR investigations revealed that the tetrameric [Me3SnL]4 compound [Me=methyl group, CH3; L=cupferronato anion, PhN2(O)O−] falls apart to monomeric units in chloroform solution. Comparison of Mössbauer sp...
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Article
Preface