![Loading...](https://link.springer.com/static/c4a417b97a76cc2980e3c25e2271af3129e08bbe/images/pdf-preview/spacer.gif)
-
Article
Hydrogenation of Dinitrobenzenes to Corresponding Diamines Over Cu–Al Oxide Catalyst in a Flow Reactor
The catalytic hydrogenation of dinitroaromatic compounds is an important reaction for the production of phenylenediamine derivatives, which are widely used in industry. In this work, the catalytic properties o...
-
Article
Effect of the Nature of Supports and the Degree of Palladium Dispersion on the Catalyst Activity and Selectivity in the Sunflower Oil Hydrogenation Reaction
Results of studying the Pd/C and Pd/O powder catalysts synthesized by the deposition of 0.5 and 1.0 wt % Pd on carbon materials (Sibunit 159k, thermal carbon black T-900, Vulcan XC-72R) and oxide supports (Ox: γ-...
-
Article
Development of a Method and Technique for Analysis of Acetone Hydrogenation Products by Gas Chromatography
The results of using capillary chromatographic columns with different stationary phases were compared to determine the purity of isopropanol obtained by hydrogenation of acetone. The study was performed with c...
-
Article
A Comparative Study of the Hydrogenation of 1,3,5-Trinitrobenzene and 2,4,6-Trinitrotoluene over a Copper–Alumina Catalyst in a Flow Reactor
The catalytic properties of a copper–alumina catalyst prepared from double layered hydroxide have been studied in the hydrogenation of 1,3,5-trinitrobenzene (TNB) and 2,4,6-trinitrotoluene (TNT) in a flow reac...
-
Article
Reductive Amination of Carbonyl Compounds over a Ni2P/SiO2 Catalyst in a Flow Mode
The catalytic properties of a nickel phosphide catalyst supported on silica gel in the reductive amination of carbonyl compounds were studied in a flow reactor using molecular hydrogen as a reducing agent. The...
-
Article
Effect of Diethylene Glycol on the Formation of the Oxide Precursor of the Nickel–Molybdenum Hydrotreating Catalyst
The effect of diethylene glycol addition on the formation of oxide precursors of nickel–molybdenum sulfide hydrotreating catalysts was studied by Raman spectroscopy and differential dissolution. The NiMoP/Al2O3 c...
-
Article
Co-Processing of Straight Run Gas Oil-Rapeseed Oil Mixture Using Sulfide NiMo Catalyst on Zeolite-Containing Support
Behavior of the sulfide NiMo catalyst on an alumina support containing SAPO—11 silicoaluminophosphate (NiMo/SAP-Al2O3) in the hydroprocessing of a mixture of a straight run gas oil (SRGO) and rapeseed oil (RO) wa...
-
Article
Effect of Mono-, Di-, and Triethylene Glycol on the Sulfidation Behavior of NiMo(P)/Al2O3 Hydrotreating Catalysts
The effect of ethylene glycol (EG), diethylene glycol (DEG), and triethylene glycol (TEG) on the sulfidation behavior of phosphate-doped NiMo/Al2O3 hydrotreating catalysts has been investigated. The catalyst prep...
-
Article
Study of the Influence Exerted by Addition of Coker Gas Oil to Straight-Run Gas Oil on the Process of Hydrotreating in the Presence of CoMo/Al2O3 Catalyst
Behavior of the CoMo/Al2O3 catalyst was experimentally studied in the course of hydrotreating of a straight-run gas oil with high content of sulfur (>2 wt %) and its mixture (up to 30 wt %) with light coker gas o...
-
Article
In Situ FMR Study of the Selective H2S-Oxidation Stability of ε-Fe2O3/SiO2 Catalysts
The stability of a catalyst for partial H2S oxidation has been studied by the ferromagnetic resonance (FMR) technique combined with transmission electron microscopy, X-ray diffraction, Mössbauer spectroscopy, and...
-
Article
Temperature of the Magnetic Ordering of the Trivalent Iron Oxide ε-Fe2O3
The trivalent iron oxide ε-Fe2O3 is a fairly rare polymorphic iron oxide modification, which only exists in the form of nanoparticles. This magnetically ordered material exhibits an intriguing magnetic behavior, ...
-
Article
Sulfide Catalysts for Production of Motor Fuels from Fatty Acid Triglycerides
Patents dealing with the production of motor fuel components by hydrodeoxygenation of renewable raw materials based on fatty acid triglycerides are analyzed. Various methods of using sulfide catalysts in hydro...
-
Article
One-Pot Synthesis of Secondary Amines from Nitroarenes and Aldehydes on Supported Copper Catalysts in a Flow Reactor: The Effect of the Support
The effect of the support on the properties of copper catalysts supported on γ-Al2O3, SiO2, and TiO2–SiO2 with a ~5 wt % Cu content was studied in the one-pot synthesis of N-heptyl-p-toluidine from p-nitrotoluene...
-
Article
Evolution of the Fe3+ Ion Local Environment During the Phase Transition ε-Fe2O3 → α-Fe2O3
Evolution of the local environment of Fe3+ ions in deposited Fe2O3/SiO2 nanoparticles formed in samples with different iron contents was investigated in order to establish the conditions for obtaining the stable
-
Article
Use of a Dual-Bed System for Producing Diesel Fuel from a Mixture of Straight-Run Diesel and Rapeseed Oil over Sulfide Catalysts
A dual-bed catalytic system including MoS2/Al2O3 and Co–MoS2/Al2O3 catalysts is proposed for the process of production of diesel fuel with the sulfur content of less than 10 ppm from a straight-run diesel fractio...
-
Article
Hydroprocessing of straight run diesel mixed with light cycle oil from fluid catalytic cracking, using sulfide NiMo catalyst on zeolite-containing supports
It is proposed that the sulfide NiMo system supported on alumina-SAPO-31 composite (NiMo/Al2O3-SAP catalyst) be used to obtain high-quality diesel fuel from a mixture of straight run diesel (SRGO) and light cycle...
-
Article
Study of Catalyst Deactivation in Liquid-Phase Hydrogenation of 3-Nitrostyrene Over Au/Al2O3 Catalyst in Flow Reactor
For the first time, we report the results of the study of dynamics of the Au/Al2O3 catalyst deactivation during the selective liquid-phase 3-nitrostyrene (3-NS) hydrogenation in a fixed bed flow reactor. It is sh...
-
Article
Study of the high-coercivity material based on ε-Fe2O3 nanoparticles in the silica gel matrix
We report the results of investigations of ε-Fe2O3 magnetic nanoparticles obtained by incipient wetness impregnation of silica gel. It was established that the obtained samples with an iron content of 12‒16% mass...
-
Article
Prospects for using Mo- and W-containing catalysts in hydroisomerization. a patent review. Part 1: Catalysts based on molybdenum and tungsten phosphides
Patent information on methods used for preparing catalytic systems containing molybdenum and tungsten phosphides and employing these systems in the hydroisomerization of paraffinic hydrocarbons are analyzed. A...
-
Article
Effect of the preparation conditions on the physicochemical and catalytic properties of Ni2P/SiO2 catalysts
The effect of the reduction conditions on the physicochemical and catalytic properties of Ni2P/SiO2 catalysts was studied. The catalysts were prepared by impregnating silica with a solution of nickel acetate and ...