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  1. No Access

    Article

    Photolysis of desoxybenzoins in micelles, chemical yield of benzaldehyde, and magnetic isotope effect

    1. The reaction of disproportionation of a geminal radical pair formed in photodissociation of desoxybenzoins is...

    V. F. Tarasov, E. N. Step, L. A. Margulis… in Bulletin of the Academy of Sciences of the… (1989)

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    Article

    Mechanism of photolysis of benzyl dimethylphenylsilyl ketone: Radical fragmentation versus isomerization

    1. Direct photolysis of benzyl dimethylphenylsilyl ketone occurs from its singlet excited state and intermediate...

    E. N. Step, V. F. Tarasov, A. L. Buchachenko in Bulletin of the Academy of Sciences of the… (1988)

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    Article

    Magnetic isotope effect of silicon

    E. N. Step, V. F. Tarasov, A. L. Buchachenko… in Bulletin of the Academy of Sciences of the… (1988)

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    Chapter and Conference Paper

    Magnetic Effects in the Photochemistry of Ketones

    Selection of Si isotopes (29Si against 28Si and 30Si) induced by the magnetic isotope effect has been discovered under photolysis of silyl-containing ketones. The direct photolysis of PhCH2COSi(CH3)2Ph induces de...

    A. L. Buchachenko, E. N. Step, V. F. Tarasov, I. A. Shkrob in Organic Free Radicals (1988)