Liquid Chromatography of Synthetic Polymers
Entropy/Enthalpy Compensation and Critical Conditions
Page
%P
-
Article
Comments on paper: Veronika Silliková, Jana Jakubčinová, Miroslav Horník, Igor Gomola, Silvia Dulanská, “Determination of caesium-137 in water samples using modified carbon microfibers”, J. Radioanal. Nuclear Chem. (2022) 331:1275–1284. https://doi.org/10.1007/s10967-022–08212
-
Chapter
Polymers and Their Complexity
Synthetic polymers are multicomponent complex systems having overlap** distributed properties. This chapter focuses on description of these overlap** distributions of molecular properties such as molar mas...
-
Chapter
Liquid Chromatography as a Tool for Determination of Distribution of Polymer Molecular Characteristics
In order to assess the distribution of their molecular properties, polymers must be separated. This book is devoted to the methods of polymer separations in solution. This chapter is intended to provide basic ...
-
Chapter
Entropy/Enthalpy Compensation in Polymer Liquid Chromatography
This chapter provides the basic concept of entropy/enthalpy compensation phenomenon operative in polymer LC. History of the development of the methods based on entropy/enthalpy compensation is followed by spec...
-
Chapter
Liquid Chromatography Under Limiting Conditions
LCLC is another approach to exploit the phenomenon of entropy/enthalpy compensation. The methods are broadly categorized as “barrier methods”. The working principle based on the nature of the eluent and barrie...
-
Chapter
Challenges and Opportunities
The final chapter of the book summarizes the strengths and limitations of different methods of LC of polymers. Still existing challenges and opportunities are highlighted.
-
Chapter
Conventional Entropy-Controlled Methods of Polymer Liquid Chromatography
This chapter is devoted to the polymer LC methods, in which the processes of permeation and exclusion of macromolecules into/from the porous column packing particles play a decisive role. For obvious reasons, ...
-
Book
-
Chapter
Liquid Chromatography at Critical Conditions
The most important method of polymer LC based on entropy/enthalpy compensation namely LCCC is comprehensively discussed in this chapter. The detailed discussion focuses on the establishment of the critical con...
-
Chapter
Temperature Gradient Interaction Chromatography
The chapter focuses on phenomenon of entropy/enthalpy compensation during the chromatographic run by continuous change in the temperature of the system. The working principle of the method is followed by a com...
-
Chapter
Hyphenation of Liquid Chromatography with Spectroscopy
The chapter provides a comprehensive overview of the current state-of-the-art of the hyphenation of polymer LC methods with spectroscopic techniques (FTIR, MS, NMR). Challenges in hyphenation of LC with spectr...
-
Chapter
Non-exclusion Methods of Polymer Liquid Chromatography
In this chapter, a brief discussion of most important polymer LC procedures, which employ the enthalpy-based separation mechanism, generally designated as enthalpic interactions, is provided. As mentioned prev...
-
Chapter
Eluent Gradient Interaction Chromatography
The chapter focuses on phenomenon of entropy/enthalpy compensation during the chromatographic run by continuous change in the mobile phase (eluent) composition. The working principle of the method is followed ...
-
Chapter
Two-Dimensional Liquid Chromatography
The chapter provides a comprehensive description of possibilities of coupling of different modes of polymer LC. Approaches of two-dimensional analysis are followed by description of the experimental setup for ...
-
Chapter
Polymers in Solution
This chapter is destined for the readers not involved in the research and applications of macromolecular substances. Its purpose is the brief, simplified elucidation of the selected principles and terms, major...
-
Chapter
Instrumentation for Polymer Liquid Chromatography
Due to dissimilar nature of separation for different modes of polymer LC, several additional challenges are posed compared to HPLC of small molecules. This chapter mainly focuses on peculiarities of instrument...
-
Article
Microporous carbon fibers prepared by carbonization of cellulose as carriers of particles of active substances
Microporous carbon fibers prepared by controlled carbonization of cellulose proved promising carrier of nano- and microparticles of solid active substances. The average pore size of the carbon fibers ranges fr...
-
Article
Carbon nanofiber based CuO nanorod counter electrode for enhanced solar cell performance and adsorptive photocatalytic activity
Dye-sensitized solar cells (DSSCs) are known as new generation solar cell of photovoltaic technologies (PV), and have become hotspot topic in the PV research. DSSCs include four main components such as photoan...
-
Article
Porous carbon fibers prepared from cellulose
A series of porous carbon microfibers has been prepared by controlled carbonization of cellulose precursors. Their surface area determined by the BET method from argon absorption ranges from about 1 to almost ...
-
Article
The 24th International Symposium on Separation Sciences (ISSS2018)
