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Article
Formation of Tebuconazole Complexes with Cadmium(II) Investigated by Electrospray Ionization Mass Spectrometry
The formation of complexes between tebuconazole (Teb) and cadmium in simplified model solutions as well as soil solutions was studied using electrospray ionization mass spectrometry. Teb and cadmium form two t...
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Article
Gaseous iron(II) and iron(III) complexes with BINOLate ligands
Electrospray ionization (ESI) of dilute solutions of 1,1′-bi-2-naphthol (BINOL) and iron(II) or iron(III) sulfate in methanol/water allows the generation of monocationic complexes of iron and deprotonated BINO...
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Chapter
Intrinsic Mechanisms of Oxidation Reactions as Revealed by Gas-Phase Experiments
Oxidation catalysis is of extreme importance in many areas of chemistry. The intrinsic mechanisms of oxidation reactions are, however, quite often understood only rather poorly, and catalyst research is ...
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Chapter
Sicherheitspartner in Brandenburg
“Keine Regierung und keine Bataillone vermögen Recht und Freiheit zu schützen, wo der Bürger nicht im Stande ist, selber vor die Haustüre zu treten und nachzusehen, was es gibt.”
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Chapter
Diastereoselective Effects in Gas-Phase Ion Chemistry
A method for the investigation of diastereoselective effects in reactions of gaseous ions bearing flexible backbones is described. It relies on the study of diastereoselectively labeled substrates that are stu...
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Article
Experimental and theoretical studies of diatomic gold halides
The diatomic gold halides AuX are studied by means of Fourier-transform ion cyclotron resonance mass spectroscopy and ab initio theory at a quasi-relativistic CCSD(T) level of theory. A thermokinetic approach ...
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Chapter
Characterization, Orbital Description, and Reactivity Patterns of Transition-Metal Oxo Species in the Gas Phase
Metal-oxo and -peroxo species play key roles in catalytic oxidations using transition metals This contribution addresses gas-phase studies of diatomic metal-oxo species and their properties which turn out to b...
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Article
Charge inversion as a structural probe for C6H 5 + and C6H 6 +· cations
Charge reversal (+CR−) of cations to anions can be used to structurally differentiate isomeric C6H 5 + and C6H 6 +· ...
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Chapter and Conference Paper
Einflüsse digitaler Bildsegmentierungstechniken auf die quantitative Analyse fluoreszierenden mikrobiellen Planktons
Um Reaktionen von Plankton auf Umwelteinflüsse zu verfolgen, werden auf Filtern angereicherte und gefärbte Zellen (zunächst Bakterien einer Breite von 0.2 ¼m — 1 ¼m) unter dem Epifluoreszenzmikroskop mittels V...