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Article
The design of new molecular "light switches" for DNA
Two novel ruthenium(II) complexes, [Ru(pztp)2(phen)](ClO4)2 and [Ru(pztp)2(bpy)](ClO4)2, have been synthesized and characterized by UV/Vis and 1H NMR spectroscopies and mass spectrometry. The MeCN solutions of b...
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Article
Synthesis, characterization and crystal structure of ruthenium(II) polypyridyl complexes
[Ru(bipy)2(5-R-phen)](ClO4)2 complexes have been prepared, where bipy=2,2′- bipyridine, phen=1,10-phenanthroline, and R=H, Me, NO2 or NH2. The influence of the different 5- substituted phen on the electron del...
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Article
The synthesis, characterization and crystal structure of trans(N)-(1,10-phenanthroline)-bis(L-prolinato)cobalt(III) perchlorate hydrate
The complex was prepared by reaction of cis-[Co(phen)2-Cl2] Cl·3H2O (phen = phenanthroline) with L-proline at pH 9, isolated by chromatography using an SP-Sephadex C-25 H+ form column, and characterized by elemen...