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Article
Reaction mechanism of organoselenium-catalyzed syn-dichlorination of alkenes: a DFT study
A new method for the syn-dichlorination of alkenes at room temperature has been proposed by Denmark et al. The method uses diselenide (PhSeSePh) as the precatalyst, benzyltriethylammonium chloride (BnEt3NCl) as t...
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Article
Quantum chemistry studies of the catalysis mechanism differences between the two isoforms of glutamic acid decarboxylase
The production of gamma-aminobutyric acid (GABA) is catalyzed by two isoforms of glutamic acid decarboxylase (GAD), using pyridoxal 5′-phosphate (PLP) as the cofactor. Between the two enzymes, GAD67 accounts f...