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Open AccessReply to: Diffusion anomaly in nanopores as a rich field for theorists and a challenge for experimentalists
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Article
Open AccessRhodium nanoparticles supported on silanol-rich zeolites beyond the homogeneous Wilkinson’s catalyst for hydroformylation of olefins
Hydroformylation is one of the largest industrially homogeneous processes that strongly relies on catalysts with phosphine ligands such as the Wilkinson’s catalyst (triphenylphosphine coordinated Rh). Heteroge...
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Article
Rational construction of multiple hollow silicalite-1 zeolite with enhanced quasi acidity for robust vapor-phase Beckmann rearrangement
Develo** efficient and stable zeolites for vapor-phase Beckmann rearrangement of cyclohexanone oxime is still a great challenge to realize ε-caprolactam (CPL) green production. In this work, the hierarchical...
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Article
Mechanical properties and microstructure of ground granulated blast furnace slag-based geopolymer reinforced with polyvinyl alcohol fibers
Ground granulated blast furnace slag (GGBFS) is a solid waste characterized by a high reactivity with alkali solutions, which is normally used geopolymer precursor. Fiber is often used to reinforce geopolymer....
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Article
Open AccessHyperloop-like diffusion of long-chain molecules under confinement
The ultrafast transport of adsorbates in confined spaces is a goal pursued by scientists. However, diffusion will be generally slower in nano-channels, as confined spaces inhibit motion. Here we show that the ...
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Article
Open AccessCharge-separation driven mechanism via acylium ion intermediate migration during catalytic carbonylation in mordenite zeolite
By employing ab initio molecular dynamic simulations, solid-state NMR spectroscopy, and two-dimensional correlation analysis of rapid scan Fourier transform infrared spectroscopy data, a new pathway is propose...
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Article
Open AccessMolecular identification and quantification of defect sites in metal-organic frameworks with NMR probe molecules
The defects in metal-organic frameworks (MOFs) can dramatically alter their pore structure and chemical properties. However, it has been a great challenge to characterize the molecular structure of defects, es...
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Article
Fischer–Tropsch synthesis to olefins boosted by MFI zeolite nanosheets
Catalytic reactions are severely restricted by the strong adsorption of product molecules on the catalyst surface, where promoting desorption of the product and hindering its re-adsorption benefit the formatio...
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Article
Stepwise or Concerted Mechanisms of Benzene Ethylation Catalyzed by Zeolites? Theoretical Analysis of Reaction Pathways
Benzene ethylation over zeolites has a long-standing controversy on two different possible reaction pathways, i.e., stepwise and concerted mechanisms. To solve this doubt and further find out the suitable zeolite...
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Article
Open AccessLayered double hydroxide membrane with high hydroxide conductivity and ion selectivity for energy storage device
Membranes with fast and selective ions transport are highly demanded for energy storage devices. Layered double hydroxides (LDHs), bearing uniform interlayer galleries and abundant hydroxyl groups covalently b...
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Article
Solid-state 31P NMR map** of active centers and relevant spatial correlations in solid acid catalysts
Solid acid catalysts are used extensively in various advanced chemical and petrochemical processes. Their catalytic performance (namely, activity, selectivity, and reaction pathway) mostly depends on their aci...
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Open AccessPublisher Correction: Thin-film composite membrane breaking the trade-off between conductivity and selectivity for a flow battery
An amendment to this paper has been published and can be accessed via a link at the top of the paper.
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Open AccessMolecular elucidating of an unusual growth mechanism for polycyclic aromatic hydrocarbons in confined space
Extension and clustering of polycyclic aromatic hydrocarbons (PAHs) are key mechanistic steps for coking and deactivation in catalysis reactions. However, no unambiguous mechanistic picture exists on molecule-...
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Article
Open AccessInsight into dynamic and steady-state active sites for nitrogen activation to ammonia by cobalt-based catalyst
The industrial synthesis of ammonia (NH3) using iron-based Haber-Bosch catalyst requires harsh reaction conditions. Develo** advanced catalysts that perform well at mild conditions (<400 °C, <2 MPa) for industr...
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Open AccessThin-film composite membrane breaking the trade-off between conductivity and selectivity for a flow battery
A membrane with both high ion conductivity and selectivity is critical to high power density and low-cost flow batteries, which are of great importance for the wide application of renewable energies. The trade...
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Article
Acid–base synergistic catalysis of biochar sulfonic acid bearing polyamide for microwave-assisted hydrolysis of cellulose in water
The development of a highly efficient heterogeneous catalysis process for the hydrolysis of cellulose to reducing sugars (RSs) and especially 5-hydroxymethylfurfural (HMF) in water is highly anticipated for la...
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Article
Surface half-metallicity in the Heusler alloy Cr2CoGa with low magnetic moment
Half-metallic fully compensated ferrimagnets (HM-FCFs) are important spintronic materials due to the high spin polarization and the low magnetic moment. Recently, motivated by the theoretical prediction of HM-...
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Reference Work Entry In depth
Solid-State NMR Characterization of Acidity of Solid Catalysts
Solid acid catalysts such as zeolites, metal oxides, and heteropolyacids are environmentally benign, and are widely applied in advanced chemical and petrochemical processes due to their inherent acid-base cata...
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Article
Open AccessMultiple thermal spin transport performances of graphene nanoribbon heterojuction co-doped with Nitrogen and Boron
Graphene nanoribbon is a popular material in spintronics owing to its unique electronic properties. Here, we propose a novel spin caloritronics device based on zigzag graphene nanoribbon (ZGNR), which is a het...
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Article
Effective transformation of cellulose to 5-hydroxymethylfurfural catalyzed by fluorine anion-containing ionic liquid modified biochar sulfonic acids in water
This article first discloses that the fluorine anion-containing ionic liquids-functionalized biochar sulfonic acids (BCSA-IL-F1–3s), which were simply synthesized by an ionic exchange of 1-trimethoxysilylpropyl-...