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Article
An Experimental Study of the Possible Use of Opoka as a Si Source in Glass Production of the Turkestan Region, Kazakhstan
Three series of experiments have been conducted to study the possible replacement of quartz sand with opoka in the composition of the initial charge for glass production. The experiments were carried out at at...
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Article
Composition, Structure, and Conditions of Formation of Fluorine-Bearing Sodalite: Experimental Evidence
Fluoro-sodalite was synthesized for the first time at temperatures of 400–800°C and H2O pressures of 1–2 kbar in the Si–Al–Na–H–O–F system. X-ray diffraction and infrared spectroscopic investigations showed that ...
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Article
Synthesis and study of the chemical stability and strength of zirconium phosphates with the structure of langbeinite with imitators of high-level radioactive waste (HLRW)
Crystalline zirconium phosphates with the langbeinite structure containing macroquantities of elements that imitate high-level radioactive waste (HLRW) (Cs 4.6 wt %, Sr 6.2 wt %, La 10.0 wt %, or U4+ 11.6 wt %) h...
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Article
Synthesis and study of structural analogs of kosnarite mineral under hydrothermal conditions
Distribution of cations (Na, K, Cs, Sr) between kosnarite solid solutions differing in the framework composition (Ti/Zr, P/Si) and aqueous solutions at 200°C was studied. The energies of mixing of kosnarite so...
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Article
Unusual phase transformations in synthetic NaF-bearing fluid inclusions in quartz
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Article
Na2CO3-bearing fluids: Experimental study at 700°C and under 1, 2, and 3 kbar pressure using synthetic fluid inclusions in quartz
Heterogeneous fluid equilibria in the second-type H2O-Na2CO3 system in the presence of SiO2 or SiO2 + NaAlSi3O8 were studied experimentally. Phase diagrams of the second-type systems are briefly described. Fluid ...
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Article
New representative in the sodalite structure type with extraframework anions [AlF6]3−
The crystal structure of new synthetic aluminosilicate |Na7.38(AlF6)0.70(H2O)4.88|[(Si6.74Al5.26)O24]-SOD, which was obtained by hydrothermal synthesis (T = 650° C, P = 2 Kbar) in the Si-Al-Na-F-H2O system, has b...
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Article
Immiscibility in sulfate-bearing fluid systems at high temperatures and pressures
Fluid equilibria in the H2O-Na2SO4-SiO2 system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in quartz. The obtained results indicated a heterogen...
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Article
Experimental study of heterogeneous fluid equilibria in silicate-salt-water systems
Fluid inclusions in quartz have been synthesized from Na2SO4 and NaF solutions at 700–800°C and 1 and 2 kbar using the fracture healing method. Some experiments have been carried out in the presence of albite gel...
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Article
Ussingite from the Lovozero Alkaline massif: Calorimetric, thermal, and IR spectroscopic study
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Article
Liquid separation in the presence of vapor in synthetic fluid inclusions obtained from Na2CO3 solutions
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Article
Synthesis of phosphate-bearing matrices by the method of metasomatic replacement reactions
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Article
An experimental study of Cl and S distribution between sodalite and fluid
S and Cl distribution between sodalite and fluid was experimentally studied at temperatures of 300–800°C and pressure of 0.5–3 kbar. It is demonstrated that S is preferably distributed into fluid in equilibriu...
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Article
Method of synthetic fluid inclusions in quartz in experimental study of the water-sodium sulfate system
The aim of this study is to estimate the capability of the method of synthetic fluid inclusions in experimental investigation of the properties of aqueous salt solutions, whose phase diagram is attributed to t...
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Article
Metastability at cryometry of sulfate-containing synthetic fluid inclusions
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Article
Experimental study of loparite formation in complex fluid-magmatic systems
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Article
Mineral thermometry and the composition of fluids of the sodalite syenites of the Lovozero alkaline massif
In order to determine the conditions of mineral formation, a suite of sodalite syenite samples was investigated from the differentiated complex and in part from the eudialyte lujavrite complex of the Lovozero ...
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Article
Isotopic thermometry of sodalite-bearing mineral associations
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Article
Hydrothermal synthesis and characterization of (Na,K)Ti2(PO4)3 solid solutions
Na1−x KxTi2(PO4)3 (0 ≤ x ≤ 1) solid solutions are synthesized through ion exchange under hydrothermal conditions and a sol-gel process. The unit cell parameters are calculated for (Na,K) t...
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Article
Temperature range for the formation of sodalite-bearing assemblages