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Article
Synthesis, size characterization and catalytic activities of transition metal oxide nanoparticles towards degradation of norfloxacin, oxytetracycline and lincomycin drugs based on H2O2 in aqueous medium
Metal oxide nanoparticles CuO, NiO and Fe2O3 are synthesized and size characterized using HRTEM, FESEM and XRD measurements. Ecofriendly biopolymers such as polyethylene glycol (PEG) and carboxymethyl cellulose (...
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Article
CuO nanoparticles with biostabilizers for the catalytic decolorization of bromocresol green, crystal violet, methyl red dyes based on H2O2 in aqueous medium
Ecofriendly biopolymers such as polyethylene glycol (PEG), carboxy methyl cellulose (CMC), starch (STA) were used as the stabilizers in the preparation of CuO nanoparticles. The sizes of CuOnps were characteri...
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Article
Open AccessImpact of CuO nanoleaves on MWCNTs/GCE nanocomposite film modified electrode for the electrochemical oxidation of folic acid
The salient features of the present work focus on the synthesis of CuO nanoleaves by alcoholic reduction of Cu(II) chloride in the presence of poly(diallyldimethylammonium chloride) (PDDA) for the application ...
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Article
The copper nanoparticles catalysed reduction of substituted nitrobenzenes: effect of nanoparticle stabilizers
Copper nanoparticles are prepared and size characterized using FESEM and HRTEM. Poly ethylene glycol (PEG), carboxy methyl cellulose (CMC) and poly N vinyl pyrrolidone (PVP) are used as the nanoparticle stabilize...
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Article
Reactive template method for the synthesis of Pd nanoparticles supported PoPd hollow spheres for electrochemical oxidation of ascorbic acid
Poly(o-phenylenediamine) (PoPD) hollow spheres have been successfully synthesized by facile monomer droplet template method. The structure, morphology and electrochemical properties of the resultant PoPD hollo...
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Article
Mono and bimetallic nanoparticles of gold, silver and palladium-catalyzed NADH oxidation-coupled reduction of Eosin-Y
Mono metallic (Au, Ag, Pd) and bimetallic (Au–Ag, Ag–Pd, Au–Pd) with 1:1 mol stoichiometry, nanoparticles are synthesized using one-pot, temperature controlled chemical method using cetyltrimethylammonium brom...
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Article
Antipyrilquinoneimine dye formation by coupling aniline derivatives with 4-aminoantipyrine in the presence of ruthenium nanoparticles
The coupling of 4-aminoantipyrine (4-AAP) with aniline derivatives catalyzed by ruthenium nanoparticles (Rnp) has been studied by UV-Vis spectroscopy in aqueous medium. The rate constant for antipyrilquinoneim...
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Article
Small-angle neutron scattering study of sodium cholate and sodium deoxycholate interacting micelles in aqueous medium
Small angle neutron scattering (SANS) measurements of D2O solutions (0.1 M) of sodium cholate (NaC) and sodium deoxycholate (NaDC) were carried out atT= 298 K. Under compositions very much above the critical mice...
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Article
Small-angle neutron scattering study of the effect ofn-alkanols on interacting micelles
Small-angle neutron scattering cross-section distributions of sodium dodecyl sulphate (SDS) and dodecyl trimethyl ammonium bromide (DTAB), each 0·3 M in D2O were obtained in the absence and presence of 0·1 M 1-pe...
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Article
Surfactant-induced stabilization of four-coordinated hemes in reconstituted hemoglobins
A transition from 5-coordination to 4-coordination metal centres of porphyrins in carbonmonoxy Fe(II), Cu(II) and Ni(II) hemoglobins is observed as a consequence of ionic surfactant interactions with metallopr...
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Article
Solvent effects on reverse micellisation of Tween 80 and Span 80 in pure and mixed organic solvents
Reverse micellisations of nonionic surfactants (Tween 80 and Span 80) in various pure nonaqueous solvents like carbontetrachloride, benzene, toluene, chloroform, cyclohexane and xylene, and in mixed solvent sy...
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Article
Formations of polyvinyltoluene microlatexes in quaternary oil in water cetyltrimethylammonium bromide microemulsions
Polymerization of vinyltoluene (VT) in quaternary microemulsions containing cetyltrimethylammonium bromide (CTAB) as the cationic surfactant is studied using laser Raman spectroscopy (LRS) and dilatometry. The...
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Article
Physico-chemical studies on synthetic disordered Ni-Fe layered double hydroxides
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Article
Adsorption studies of acetic acid dimers on activated charcoal from organic solvents
Acetic acid exists as dimers in organic solvents like benzene, toluene and xylene. Adsorption of dimeric acetic acid on activated charcoal (AC) at various temperatures from benzene, toluene and xylene solution...