Abstract
Metal oxide nanoparticles CuO, NiO and Fe2O3 are synthesized and size characterized using HRTEM, FESEM and XRD measurements. Ecofriendly biopolymers such as polyethylene glycol (PEG) and carboxymethyl cellulose (CMC) and synthetic polymer poly N-vinyl pyrrolidone (PVP) are used as stabilizing agents. The as synthesized metal oxide nanoparticles were used as catalysts in the degradation of drugs norfloxacin (NF), oxytetracycline (OTC) and lincomycin (LCM) using H2O2 as an oxidant. Using time dependent UV spectra, the progress of the reactions are monitored. Pseudo-first order conditions are maintained and the rate coefficient values are determined. The trend in the catalytic activity of metal oxide nanoparticles were found to be CuO > NiO > Fe2O3. Among the stabilizers used PEG > CMC > PVP trend for the catalytic activity of the nanoparticles was found. The rate coefficient values for the three drugs have been found to be NF > OTC > LCM. The metal oxide nanoparticles stabilized with biopolymers were found to be catalytically efficient compared to the synthetic polymer.
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References
Lanhua Hu, Stemig AM, Wammer KH, Strathmann TJ (2011) Environ Sci Technol 45:3635–3642
Lanhuahu, Martin H, Stramann TJ (2010) Environ Sci Technol 44:6416–6422
Di Paola A, Maurizio A, Augugliaro V, Garcıa-Lopez E, Loddo V, Marcı G, Palmisano L (2006) Int J Photoenergy Article ID 47418
Rivas FJ, Beltrán FJ, Encinas A (2012) J Environ Manag 100:10–15
Bautitz IR, Nogueira RFP (2007) J Photochem Photobiol A Chem 187:33–39
Lokea M-L, Jespersenb S, Vreekenc R, Halling-Sørensena B, Tjørnelund J (2003) J Chromatogr B 783:11–23
Chen M, Chu W (2012) Ind Eng Chem Res 51:4887–4893
Yang W, Zheng F, Lu Y, Xue X, Li N (2011) Ind Eng Chem Res 50:13892–13898
Wang Q, Yates SR (2008) J Agric Food Chem 56:1683–1688
Wang Y, Wang L, Li F, Liang J, Li Y, Dai J, Loh T-C, Ho Y-W (2009) J Agric Food Chem 57:5878–5883
Chiua M-H, Yangb H-H, Liuc C-H, Zena J-M (2009) J Chromatogr B 877:991–994
Kümmerer K (2001) Chemosphere 45:957–969
Kümmerer K (2009) Chemosphere 75:417–434
Hernando MD, Mezcua M, Fernández-Alba AR, Barceló D (2006) Talanta 69:334–342
Homem V, Santos L (2011) J Environ Manag 92:2304–2347
Koyuncu I, Arikan OA, Wiesner MR, Rice C (2008) J Membr Sci 309:94–101
Rivera-Utrilla J, Prados-Joya G, Sánchez-Polo M, Ferro-García MA, Bautista-Toledo I (2009) J Hazard Mater 170:298–305
Putra EK, Pranowo R, Sunarso J, Indraswati N, Ismadji S (2009) Water Res 43:2419–2430
Palominos R, Mondaca MA, Giraldo A, Peñeuela G, Pérez-Moya M, Mansilla HD (2009) Catal Today 144:100–105
Ötker HM, Akmehmet-Balcioglu I (2005) J Hazard Mater 122:251–258
Ikehata K, Naghashkar NJ, El-Din MG (2006) Ozone Sci Eng 28:353–414
Adams C, Asce M, Wang Y, Loftin K, Meyer M (2002) J Environ Eng 128:253–260
Kosuti K, Dolar D, Asperger D, Kunst B (2007) Sep Purif Technol 53:244–249
Fink Lea, Dror Ishai, Berkowitz Brian (2012) Chemosphere 86:144–149
Parimala L, Santhanalakshmi J (2013) Reac Kinet Mech Cat. doi 10.1007/s11144-013-0556-3
Hyeon T, Lee SS, Park J, Chung Y, Na HB (2001) J Am Chem Soc 123:12798–12801
Dharmaraja N, Prabu P, Nagarajan S, Kimb CH, Park JH, Kimb HY (2006) Mater Sci Eng B 128:111–114
Wang H, Shen Q, Li X, Liu F (2009) Langmuir 25:3152–3158
Shaojun J, Shourong Z, Daqiang Y, Lianhong W, Liangyan C (2008) J Environ Sci 20:806–813
Takács-Novák K, Noszál B, Hermecz I, Keresztúri G, odányi B, Szász G (1990) J Pharm Sci 79(11):1023–1028
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The authors thank NCNSNT, University of Madras for the FE-SEM and HR-TEM results. L. P. thanks for URF of the University of Madras.
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Parimala, L., Santhanalakshmi, J. Synthesis, size characterization and catalytic activities of transition metal oxide nanoparticles towards degradation of norfloxacin, oxytetracycline and lincomycin drugs based on H2O2 in aqueous medium. Reac Kinet Mech Cat 111, 621–632 (2014). https://doi.org/10.1007/s11144-013-0669-8
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DOI: https://doi.org/10.1007/s11144-013-0669-8