Abstract
Concentrations of Pt and Pd in roadside top-soil samples, collected in May 2003, at four types of sites (urban, suburban, rural and highway) in the greater Athens area as well as concentrations of Pb, Cu, Zn, Fe and Ca, were determined.
Our results show high concentrations of “classic” (Pb, Cu, Zn) and “new” (Pt, Pd) traffic related elements in top-soils on a highway and a representative urban street in Athens. In the highway samples, the average concentrations of Pt and Pd were 141.1 and 125.9 ng/g respectively, while in the urban street samples they were 35% lower. In the samples of the rural and suburban roads the Pt and Pd levels were very low 2.0 and 1.4 ng/g respectively. These data show an increased accumulation of Pt and Pd in top-soils during the last decade as a result of the gradual increase in the use of vehicles with catalytic converters. The Pt:Pd ratios (average: 1.2) were consistent with known catalytic converters composition (1–2.5), suggesting that the common source of these metals is catalytic converters. The levels of the traffic related elements in suburban and rural roads were very low, suggesting the negligible impact from emission sources. Principal component, biplot and cluster analysis discriminated the traffic related metals from Fe, Mn and Ca, which are abundant in soils, related mainly to the soil parent materials.
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Alt, F., Weber, G., Messerschidt, J., von Bohlen, A., Kastenholtz, B. and Guenther, K.: 2002, ‘Bonding states of palladium in phytosystems: First results for for endive’, Anal. Lett. 35, 1349–1359.
Angelone, M., Corraqdo, T. and Dowgiallo, G.: 1995, ‘Lead and cadmium distribution in urban soil and plants in the city of Rome: A preliminary study’, in Proceedings of the Third International Conference on the Biogeochemistry of Trace Elements, Paris: INRA Editions, pp. 23–24.
Barbante, C., Veysseyre, A., Ferrari, C., Van de Velde, K., Morel, C., Capodaglio, G., Cescon, P., Scarponi, G. and Boutron, C.: 2001, ‘Greenland snow evidence of large scale atmospheric contamination for platinum, palladium and rhodium’, Environ. Sci. Technol. 35, 835–839.
Barefoot, R. R.: 1999, ‘Distribution and speciation of platinum group elements in environmental matrices’, Trends Anal. Chem. 18(11), 702–707.
Cameron, K. C., Di, H. J. and McLaren, R. G.: 1997, ‘Is soil an appropriate dum** ground for our wastes?’, Austr. J. Soil. Res. 35, 995–1035.
Carlosena, A., Andrade, J. M. and Prada, D.: 1998, ‘Searching for heavy metals grou** roadsite soils as a function of motorized traffic infuelnce’, Talanta 47, 753–767.
Chronopoulos, J., Haidouti, C., Chronopoulou-Sereli, A. and Massas, I.: 1997, ‘Variations in plant and soil lead and cadmium content in urban parks in Athens, Greece’, Sci. Tot. Environ. 196, 91–98.
Cichella, D., De Vivo, B. and Lima, A.: 2003, ‘Palladium and platinum concentration in soils from the Napoli metropolitan area, Italy: Possible effects of catalytic exhausts’, Sci. Tot. Environ. 308, 121–131.
Cinti, D., Angelone, M., Masi, U. and Cremisini, C.: 2002, ‘Platinum levels in natural and urban soils from Rome and Latium (Italy): Significance for pollution by automobile catalytic converter’, Sci. Tot. Environ. 293, 47–57.
De Miguel, E., Llamas, J. F., Chacon, E. and Mazadiego, L. F.: 1999, ‘Sources and pathways of trace elements in urban environments: A multi-elemental qualitative approach’, Sci. Total Environ. 235, 355–357.
Ek, K. H., Morrison, G. M. and Rauch, S.: 2004, ‘Environmental routes for platinum group elements to biological materials - a review’, Sci. Tot. Environ. 334–335, 21–38.
Ely, J. C., Neal, C. R., Kulpa, C. F., Schneegurt, M. A., Seidler, J. A. and Jain, J. C.: 2001, ‘Implications of Platinum-Group Element accumulation along US roads from catalytic-converter attrition’, Environ. Sci. Technol. 35, 3816–3822.
Farago, M. E. and Parsons, P. J.: 1983, ‘The uptake and accumulation of platinum metals by the water hyacinth (Eichhornia crassipes)’, Inorg. Chim. Acta 79, 233–234.
Folinsby L. J.: 1993, ‘Human health effects of air pollution’, Environ. Health Perspect. 100, 45–46.
Fritsche, J. and Meisel, T.: 2004, ‘Determination of anthropogenic input of Ru, Rh, Pd, Re, Os, Ir and Pt in soils along Austrian motorways by isotope dilution ICP-MS’, Sci. Tot. Environ. 325, 145–154.
Gebel, H. T.: 2000, ‘Toxicology of platinum, palladium and rhodium and their compounds’, in F. Zereini and F. Alt F. (eds.), Anthropogenic Platinum Group Element Emissions and their Impact on Man and Environment, Springer-Verlag, pp. 245–256.
Gomez, B., Palacios, M. A., Gomez, M., Sanchez, J. L., Morrison, G., Rauch, S., McLeod, C., Ma, R., Caroli, S., Alimonti, A., Petrucci, F., Bocca, B., Schramel, P., Zischka, M., Petterson, C. and Wass, U.: 2002, ‘Levels and risk assessment for humans and ecosystems of platinum-group elements in the airborne particles and road dust of some European cities’, Sci. Tot. Environ. 299, 1–19.
Imperato, M., Adamo, P., Naimo, D., Arienzo, M., Stanzione, D. and Violante, P.: 2003, ‘Spacial distribution of heavy metals in urban soils of Naples city (Italy)’, Environ. Pollut. 124, 247–256.
Jarvis, K. E., Parry, S. J. and Piper, J. M.: 2001, ‘Temporal and spatial studies of autocatalyst-derived platinum, rhodium and palladium and selected vehicle-derived trace elements in the environment’, Environ. Sci. Technol. 35, 1031–1036.
Kabata-Pendias, A. and Pendias, H.: 2000, in Trace Elements in Soil and Plants, 3rd edn., CRC Press, Boca Raton, FL, pp. 1–432.
Kelly, J., Thornton, I. and Simpson, P. R.: 1996, ‘Urban Geochemistry: A study of the influence of anthropogenic activity on the heavy metal content of soils in traditionally industrial and non-industrial areas of Britain’, Applied Geochemistry 11, 363–370.
Kita, I., Sato, T., Kase, Y. and Mitropoulos, P.: 2004, ‘Neutral rains at Athens, Greece: A Natural safeguard against acidification of rains’, Sci. Tot. Environ. 327(1–3), 285–294.
Kousa, A., Oglesbym L., Koistinen, K., Kunzli, N. and Jantunen M.: 2002, ‘Exposure chain of urban air PM2.5-associations between ambient fixed site, residential outdoor, indoor, workplace and personal exposures in four European cities in the EXPOLIS – study’, Atmos. Environ. 36(18), 3031–3039.
Legret, M. and Pagotto, C.: 1999, ‘Evaluation of pollutant loadings in the runoff waters from a major rural highway’, Sci. Tot. Environ. 235, 143–150.
Li, X. D., Poon, C. S. and Liu, P. S.: 2001, ‘Heavy metal contamination of urban soils and street dusts in Hong Kong’, Appl. Geochem. 16, 1361–1368.
Lustig, S., Zang, S., Michalke, B., Schramel, P. and Beck, W.: 1997, ‘Platinum determination in nutrient plants by inductively coupled plasma mass spectrometry with special respect to the hafnium oxide interference’, Fresenius J. Anal. Chem. 357, 1157–1163.
Manta, D. S., Angelone, M., Bellanca, A., Neri, R. and Sprovieri, M.: 2002, ‘Heavy metals in urban soils: A case study from the city of Palermo (Sicily), Italy’, Sci. Tot. Environ. 300(1–3), 229–243.
Martin, M. H. and Coughethey, P. J.: 1982, Biological Moniroting of Heavy Metal Pollution, Applied Science Publishers LTD, London, NY., p. 475.
Merget, R. and Rosner, G.: 2001, ‘Evaluation of the health risk of platinum group metals emitted from automotive catalytic converters’, Sci. Tot. Environ. 270, 165–173.
Merget, R.: 2000, ‘Occupational platinum salt allergy. Diagnosis, prognosis prevention and therapy’, in: F. Zereini and F. Alt (eds.), Anthropogenic Platinum Group Element Emissions and their Impact on Man and Environment, Springer-Verlag, Berlin, Heidelberg, pp. 257–265.
Moldovan, M., Gomez, M. and Palacios, M. A.: 1999, ‘Determination of platinum, rhodium and palladium in car exhaust fumes’, J. Anal. At. Spectrom. 14, 1163–1169.
Moldovan, M., Rauch, S., Gomez, M., Palacios, M. A. and Morrison, G. M.: 2001, ‘Bioaccumulation of Palladium, Platinum and Rhodium from urban particulates and sediments by the freshwater isopod Asellus aquaticus’, Water Res. 35(17), 4175–4183.
Morcelli, C. P. R., Figueiredo, A. M. G., Sarkis, J. E. S., Enzweiler, J., Kakazu, M. and Sigolo, J. B.: 2005, ‘PGE and other traffic-related elements in roadside soils from Sao Paulo, Brazil’, Sci. Tot. Environ. (in press, pages 11).
Morton, O., Puchelt, H., Hernández, E. and Lounejeva, E.: 2001, ‘Traffic-related platinum group elements (PGE) in soils from Mexico City’, J. Geochem. Explor. 72, 223–227.
Morton-Bermea, O., Hernandez-Alvarez, E., Gaso, I. and Segovia, N.: 2002, ‘Heavy metal concentrations in surface soils from Mexico City’, Bull. Environ. Cont. Tox. 68, 383–388.
Niskavaara, H. and Kontas, E.: 1990, ‘Reductive coprecipitation as a separation method for the determination of gold, palladium, platinum, rhodium, silver, selenium and tellurium in geological samples by graphite furnace Atomic Absorption Spectrometry’, Anal. Chim. Acta 231, 273–282.
Ozaki, H., Watanabe, I. and Kuno, K.: 2004, ‘Investigation of the Heavy Metal Sources in Relation to Automobiles’, Water, Air and Soil Pollut. 157, 209–223.
Palacios, M. A., Gomez, M. M., Moldovan, M., Morrison, G. M., Rauch, S., Mcleod, C., Ma, R., Laserna, J., Lucena, P., Caroli, S., Alimonti, A., Petrucci, F., Bocca, B., Schramel, P., Lustig, S., Zischka, M., Wass, U., Stenbom, B., Luna, M., Saenz, J. C., Santamaria, J. and Torrens, J. M.: 2000, ‘Platinum-group elements: Quantification in collected exhaust fumes and studies of catalyst surfaces’, Sci. Tot. Environ. 257, 1–15.
Purves, D. and Mackenzie, E. J.: 1969, ‘Trace elements contamination of parklands in urban areas’, J. Soil Sci. 20, 288–290.
Rauch, S., Morrison, G. M., Motettica-Heino, M., Donard, O. F. X. and Muris, M.: 2002, ‘Elemental association and fingerprinting of traffic-related metals in road sediments’, Environ. Sci. Technol. 34, 3119–3123.
Ravindra, K., Bencs, L. and Van Grieken, R.: 2004, ‘Platinum group elements in the environment and their health risk’, Sci. Tot. Environ. 318, 1–43.
Riga-Karandinos, A. N. and Saitanis, C.: 2004, ‘Biomonitoring of concentrations of platinum group elements and their correlations to other metals’, Int. J. Environ. Pollut. 22(5), 563–579.
Schäfer, J., Echardt, J., Berner, Z. A. and Stóben, D.: 1999, ‘Time-dependent increase of traffic – emitted platinum group elements (PGE) in different environmental compartments’, Environ. Sci. Technol. 33, 3166–3170.
Schäfer, J. and Pulchelt, H.: 1998, ‘Platinum-group-metals (PGM) emitted from automobile catalytic converters and their distribution in roadside soils’, J. Geochem. Explor. 64, 307–314.
Schuster, M., Schwarzer, M. and Risse, G.: 2000, ‘Determination of palladium in environmental samples’, in F. Zereini and Alt F. (eds.), Anthropogenic Platinum Group Element Emissions and their Impact on Man and Environment, Springer-Verlag, Berlin, pp. 173–182.
Siskos, P. A., Bakeas, E. B., Lioli, I., Smirnioudi, V. N. and Koutrakis, P.: 2001, ‘Chemical characterization of PM2.5 aerosols in Athens – Greece’, Environ. Technol. 22, 687–695.
Sures, B., Zimmermann, S., Messerschmidt, J., Von Bohlen, A. and Alt, F.: 2001, ‘Fitst report on the uptake of automobile catalyst emitted palladium by European eels (Anguilla anguilla) following experimental exposure to road dust’, Environ. Pollut. 113, 341–435.
Thomaidis, N. S., Bakeas, E. B. and Siskos, P. A.: 2003, ‘Characterization of lead, cadmium, arsenic and nickel in PM2.5 particles in the Athens atmosphere, Greece’, Chemosphere 52, 959–966.
Thornton, I.: 1991, ‘Metal contamination of soils in urban areas’, in P. Bullock and P. G. Gregory (eds.), Soils in the Urban Environment, Blackwell, Chap. 4. pp. 47–75.
Van Loon, J. C.: 1980, Analytical Atomic Absorption Spectroscopy – Selected Methods, Academic Press, pp. 337.
Verstraete, D., Riondato, J., Vercauteren, J., Vanhaecke, F., Moens, L., Dams, R. and Verloo, M.: 1998, ‘Determination of the uptake of [Pt(NH3)4](NO3)2 by grass cultivated on sandy loam soil and by cucumber plants grown hydroponically’, Sci. Tot. Environ. 218, 153–160.
Wedepohl, K. H.: 1995, ‘The composition of the continental crust’, Geochim. Cosmochim. Acta 59, 1217–1232.
Wei, C. and Morrison, G. M.: 1994, ‘Platinum in road dusts and urban river sediments’, Sci. Tot. Environ. 146–147, 169–174.
Whiteley, J. D. and Murray, F.: 2003, ‘Anthropogenic platinum group elements (Pt, Pd and Rh) concentrations in road dusts and roadside soils from Perth, Western Australia’, Sci. Tot. Environ. 317, 121–135.
Wilcke, W., Muller, S., Kanchanakool, N. and Zech, W. 1998, ‘Urban soil contamination in Bangkok: Heavy metal and aluminium partitioning in top-soils’, Geoderma 86, 211–228.
Yassoglou, N., Kosmas, C., Asimakopoulos, I. and Kallianou, C. 1987, ‘Heavy metal contamination of roadside soils in the Greater Athens Area’, Environ. Pollut. 47, 293–304.
Zereini, F. and Alt, F.: 2000, Anthropogenic Platinum-group Elements Emission: Their Impact on Man and Environment, Springer Verlag; Berlin, Heidelberg, Germany, pp. 1–308.
Zereini, F., Wiseman, C., Beyer, J. M. and Artelt, S.: 2001, ‘Urban H. Platinum, lead and cerium concentrations of street particulate matter (Frankfurt am Main, Germany)’, J. Soils Sediments 1, 188–195.
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Riga-Karandinos, A.N., Saitanis, C.J. & Arapis, G. First Study of Anthropogenic Platinum Group Elements in Roadside Top-Soils in Athens, Greece. Water Air Soil Pollut 172, 3–20 (2006). https://doi.org/10.1007/s11270-005-9016-7
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DOI: https://doi.org/10.1007/s11270-005-9016-7