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Single-domain/multidomain bulk magnetic characteristics of Co-substituted Ni–Zn ferrites: tailoring the effect of Co substitution

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Abstract

The influence of cobalt ion substitution on the magnetic characteristics of CoxNi0.6−xZn0.4Fe2O4 (x = 0.0 to 0.6) and the associated structural changes incurred in the bulk were investigated. The compositions were prepared by precursor combustion method and final sintered at 1000 °C to obtain bulk ferrites. The X-ray diffraction and Raman spectroscopic studies depict the formation of the ferrite phase and also confirm the retention of phase throughout substitution. The lattice parameter increases from 8.3849 to 8.4028 Ǻ with the increase in cobalt concentration, and by the virtue of higher ionic radii of Co2+ ion than Ni2+ ion that follows Vegard’s law. The study suggests redistribution of metal ions at the lattice sites, and the change in domain states favors changes in magnetic characteristics. Here, the saturation magnetization increases along with the enhancement in the hysteresis loop as the Co2+ ion increases and was assigned to the higher magnetic moment of Co2+ ion than Ni2+ ion, as well as to the cationic redistribution. However, the permeability decreases with the Co ion substitution and was ascribed to microstructural changes and increased magnetocrystalline anisotropy. The permeability study also suggests the decrease in Curie temperature with the increase in cobalt content, and the AC susceptibility studies confirm the weakening of the A–B interaction.

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Data availability

The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

The authors are grateful to DST for providing support under DST-FIST and Nano-Mission Project No. SR/NM/NS-86/2009. The authors also acknowledge Dr V. Sathe, UGC-DAE Consortium for Scientific Research, Indore, India for providing Raman facilities.

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The authors declare that no funds, grants, or other support received during preparation of this manuscript.

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Authors and Affiliations

  1. School of Chemical Sciences, Goa University, Panaji, Goa, 403206, India

    Satu G. Gawas & V. M. S. Verenkar

  2. Dnyanprassarak Mandal’s College and Research Centre, Assagao, Mapusa, Goa, India

    Satu G. Gawas

  3. Department of Chemistry, PES’s RSN College of Arts and Science, Farmagudi, Ponda, Goa, 403401, India

    Satu G. Gawas

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  1. Satu G. Gawas
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by SGG. The first draft of the manuscript was written by SGG, and VMSV corrected and commented on previous version of manuscript. All authors read and approved the final manuscript. SGG and VMSV: Conceptualization; SGG and VMSV: Methodology; SGG: Formal analysis and investigation; SGG: Writing—original draft preparation; VMSV and SGG: Writing—review and editing; VMSV: Supervision.

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Correspondence to V. M. S. Verenkar.

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Gawas, S.G., Verenkar, V.M.S. Single-domain/multidomain bulk magnetic characteristics of Co-substituted Ni–Zn ferrites: tailoring the effect of Co substitution. J Mater Sci: Mater Electron 33, 6004–6017 (2022). https://doi.org/10.1007/s10854-022-07780-2

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