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Enhanced multiferroic properties of (Nd, Cr) co-doped BiFeO3 nanoparticles

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Abstract

Pure BiFeO3 (BFO) and doped Bi1−x Nd x Fe0.975Cr0.025O3 (x = 0.025, 0.05, and 0.075) nanoparticles were prepared by a sol–gel method. The do** effects were systematically investigated on the structural, morphological, magnetic, and ferroelectric properties. The dopant results in forming nanoparticles, and the (Nd, Cr) co-doped BFO nanoparticles show excellent ferromagnetic and ferroelectric properties. The proposed mechanism for the co-doped BFO provides an alternative strategy to form nanoparticles with enhanced multiferroic properties.

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References

  1. W. Eerenstein, N.D. Mathur, J.F. Scott, Multiferroic and magnetoelectric materials. Nature 442, 759–765 (2006)

    Article  ADS  Google Scholar 

  2. S.W. Cheong, M. Mostovoy, Multiferroics: a magnetic twist for ferroelectricity. Nature mater 6, 13–20 (2007)

    Article  ADS  Google Scholar 

  3. C.S. Watson, C. Hollar, K. Anderson, W.B. Knowlton, P. Müllner, Magnetomechanical Four-State Memory. Adv. Funct. Mater 23, 3995–4001 (2013)

    Article  Google Scholar 

  4. N.A. Hill, Why are there so few magnetic ferroelectrics? J. Phys. Chem. B 104, 6694–6709 (2000)

    Article  Google Scholar 

  5. S.R. Shannigrahi, A. Huang, N. Chandrasekhar, D. Tripathy, A.O. Adeyeye, Sc modified multiferroic BiFeO3 thin films prepared through a sol–gel process. Appl. Phys. Lett. 90, 022901–022903 (2007)

    Article  ADS  Google Scholar 

  6. M. Fiebig, Th. Lottermoser, D. Frohlich, A.V. Goltsev, R.V. Pisarev, Observation of coupled magnetic and electric domains. Nature (London) 419, 818–820 (2002)

    Article  ADS  Google Scholar 

  7. J. Wang, J.B. Neaton, H. Zheng, V. Nagarajan, S.B. Ogale, B. Liu, D. Viehland, V. Vaithyanathan, D.G. Schlom, U.V. Waghmare, N.A. Spaldin, K.M. Rabe, M. Wuttig, R. Ramesh, Epitaxial BiFeO3 Multiferroic Thin Film Heterostructures. Science 299, 1719–1722 (2003)

    Article  ADS  Google Scholar 

  8. K.Y. Yun, M. Noda, M. Okuyama, H. Saeki, H. Tabata, K. Saito, Structural and multiferroic properties of BiFeO3 thin films at room temperature. J. Appl. Phys 96, 3399–3403 (2004)

    Article  ADS  Google Scholar 

  9. J.B. Neaton, C. Ederer, U.V. Waghaaren et al., First-principles study of spontaneous polarization in multiferroic BiFeO3. Phys. Rev. B 71, 014113–014121 (2005)

    Article  ADS  Google Scholar 

  10. N.A. Spaldin, S.W. Cheong, R. Ramesh, Multiferroics: Past, present, and future. Phys. Today 63, 38–43 (2010)

    Article  Google Scholar 

  11. W.W. Mao, X.F. Wang, Y.M. Han, X.A. Li, Y.T. Li, Y.F. Wang, Y.W. Ma, X.M. Feng, T. Yang, J.P. Yang, W. Huang, Effect of Ln (Ln = La, Pr) and Co co-doped on the magnetic and ferroelectric properties of BiFeO3 nanoparticles. J. Alloys Compd. 584, 520–523 (2014)

    Article  Google Scholar 

  12. S.V. Vijayasundaram, G. Suresh, R.A. Mondal, R. Kanagadurai, Substitution-driven enhanced magnetic and ferroelectric properties of BiFeO3 nanoparticles. J. Alloys Compd. 658, 726–731 (2016)

    Article  Google Scholar 

  13. R. Seshadri, N.A. Hill, Visualizing the role of Bi 6 s “lone pairs” in the off-center distortion in ferromagnetic BiMnO3. Chem. Mater 13, 2892–2899 (2001)

    Article  Google Scholar 

  14. P. Ravindran, R. Vidya, A. Kjekshus, H. Fjellvag, O. Eriksson, Theoretical investigation of magnetoelectric behavior in BiFeO3. Rev. B 74, 224412 (2006)

  15. X. Qi, J. Dho, R. Tomov, M. Blamire, J. MacManus-Driscoll, Greatly reduced leakage current and conduction mechanism in aliovalent-ion-doped BiFeO3. Appl. Phys. Lett. 86, 062903 (2005)

    Article  ADS  Google Scholar 

  16. C. ederer, N.A. Spadin, Weak ferromagnetism and magnetoelectric coupling in bismuth ferrite. Phys. Rev. B 71, 060401–060404 (2005)

    Article  ADS  Google Scholar 

  17. J. Zeng, Z.H. Tang, M.H. Tang, D.L. Xu, Y.G. ** on the multiferroic properties of BiFeO3 thin films. Appl. Phys. A 122, 63 (2016)

    Article  Google Scholar 

  18. S.T. Zhang, Y. Zhang, M. Liu, C. Du, Y. Chen, Z. Liu, Y. Zhu, N.B. Ming, Substitution-induced phase transition and enhanced multiferroic properties of Bi1–x La x FeO3 ceramics. Appl. Phys. Lett. 88, 162901–162903 (2006)

    Article  ADS  Google Scholar 

  19. C. Yang, J.S. Jiang, F.Z. Qian, D.M. Jiang, C.M. Wang, W.G. Zhang, Effect of Ba do** on magnetic and dielectric properties of nanocrystalline BiFeO3 at room temperature. J. Alloys Compd. 507, 29–32 (2010)

    Article  Google Scholar 

  20. S.K. Pradhan, J. Das, P.P. Rout, V.R. Mohanta, S.K. Das, S. Samantray, D.R. Sahu, J.L. Huang, S. Verma, B.K. Roul, Effect of holmium substitution for the improvement of multiferroic properties of BiFeO3. J. Phys. Chem. Solids 71, 1557–1564 (2010)

    Article  ADS  Google Scholar 

  21. S.K. Pradhan, B.K. Roul, Effect of Gd do** on structural, electrical and magnetic properties of BiFeO3 electroceramic. J. Phys. Chem. Solids 72, 1180–1187 (2011)

    Article  ADS  Google Scholar 

  22. C. Meng, T. Guoqiang, X. Xu, X. Ao, R. Huijun, Preparation of Nd-doped BiFeO3 films and their electrical properties. Phys. B 407, 3360–3363 (2012)

    Article  ADS  Google Scholar 

  23. J. Ray, A.K. Biswal, S. Acharya, V. Ganesan, D.K. Pradhan, P.N. Vishwakarma, Effect of Co substitution on the magnetic properties of BiFeO3. J. Magn. Magn. Mater. 324, 4084–4089 (2012)

  24. A.T. Raghavender, N.H. Hong, Effects of Mn Do** on Structural and Magnetic Properties of Multiferroic BiFeO3 Nanograins Made by Sol-gel Method. J. Magn 16, 19–22 (2011)

    Article  Google Scholar 

  25. Y.A. Chaudhari, A. Singh, E.M. Abuassaj, R. Chatterjee, S.T. Bendre, Multiferroic properties in BiFe1–x Zn x O3 (x = 0.1–0.2) ceramics by solution combustion method (SCM). J. Alloys Compd. 518, 51–57 (2012)

    Article  Google Scholar 

  26. L. Yin, W. Liu, G. Tan, H. Ren, Two-phase coexistence and multiferroic properties of Cr-doped BiFeO3 thin films. J. Supercond. Novel Magn. 27, 2765–2772 (2014)

    Article  Google Scholar 

  27. G. L. Song, H. X. Zhang, T. X. Wang, H. G. Yang, F.G. Chang, Effect of Sm, Co codo** on the dielectric and magnetoelectric properties of BiFeO3 polycrystalline ceramics. J. Magn. Magn. Mater. 324, 2121–2126 (2012)

  28. A. Lahmar, S. Habouti, C.H. Solterbeck, M. Dietze, M. Es-Souni, Multiferroic properties of Bi0.9Gd0.1Fe0.9Mn0.1O3 thin film. J. Appl. Phys 107, 024104 (2010)

    Article  ADS  Google Scholar 

  29. Z. Wen, L. You, X. Shen, X.F. Li, D. Wu, J.L. Wang, A.D. Li, Multiferroic properties of (Bi1–x Pr x )(Fe0.95Mn0.05)O3 thin films. Mater. Sci. Eng., B 176, 990–995 (2011)

    Article  Google Scholar 

  30. W.W. Mao, X.F. Wang, L. Chu, Y.Y. Zhu, J. Wang, Q., Zhang, J.P. Yang, X.A. Li, W. Huang, Simultaneous enhancement of magnetic and ferroelectric properties in Dy and Cr co-doped BiFeO3 nanoparticles. Phys. Chem. Chem. Phys. 18, 6399–6405 (2016)

    Article  Google Scholar 

  31. Y.H. Ma, X.X. Tang, M.J. Lu, K. Zheng, W.W. Mao, J. Zhang, J.P. Yang, X.A. Li, Substitution-driven structural and magnetic transformation of Mn- and Co-doped BiFeO3. J. Supercond. Nov. Magn. 28, 3593–3598 (2015)

  32. P. Modak, D. Lahiri, S.M. Sharma, Correlation between Structure and Ferromagnetism in Nano-BiFeO3. J. Phys. Chem. C 120, 8411–8416 (2016)

    Article  Google Scholar 

  33. W.W. Mao, W. Chen, X.F. Wang, Y.Y. Zhu, Y.H. Ma, H.T. Xue, L. Chu, J.P. Yang, X.A. Li, W. Huang, Influence of Eu and Sr co-substitution on multiferroic properties of BiFeO3. Ceram. Int. 42, 12838–12842 (2016)

  34. X. Yan, G. Tan, W. Liu, H. Ren, A. ** Yang

Authors
  1. Huazhong Shu
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  2. Zhongcao Wang
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  3. Weiwei Mao
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  4. Yuhui Ma
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  5. Liang Chu
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  6. **ngfu Wang
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  7. Wei Chen
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  8. Jian Zhang
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  9. Jian** Yang
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  10. Rongfang Song
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  11. **ng’ao Li
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Corresponding authors

Correspondence to Rongfang Song or **ng’ao Li.

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Shu, H., Wang, Z., Mao, W. et al. Enhanced multiferroic properties of (Nd, Cr) co-doped BiFeO3 nanoparticles. Appl. Phys. A 123, 338 (2017). https://doi.org/10.1007/s00339-017-0849-x

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