Abstract
The leather industry generates $150 billion USD annually. The industry that processes animal hides or skins for finished leather goods generates a lot more solid waste than its main output, leather. The current ineffective disposal of these solid wastes (via open dum**, incineration, and landfilling) results in pollution, which obstructs the industry’s path to sustainable expansion. Interestingly, recycling waste into usable form seems like a potential option. Leather biomass contains collagen, keratin, and fat and can be used to produce sustainable bioproducts and replace petroleum-based materials. This chapter provides an extensive perspective on the effective reutilization of diverse forms of leather waste (keratin waste, untanned/fleshing waste, chrome-tanned waste, and tannery waste sludge) that are generated at various stages of processing the leather. However, there is still a sizable difference between the stated targets for sustainable leather technology and the levels that have been reached, despite ongoing research efforts. The chapter concludes that solid waste, which is generated from the tannery industry, is a gold mine that can be immediately used to make money while closing the loop.
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References
Amdouni, S., Trabelsi, A. B. H., Elasmi, A. M., Chagtmi, R., Haddad, K., Jamaaoui, F., Khedhira, H., & Chérif, C. (2021). Tannery fleshing wastes conversion into high-value-added biofuels and biochars using a pyrolysis process. Fuel, 294, 120423.
Appala, V. G., Pandhare, N. N., & Bajpai, S. (2022a). Biorefining of leather solid waste to harness energy and materials—A review. Biomass Conversion and Biorefinery, 1–18.
Appala, V. N. S. G., Pandhare, N. N., & Bajpai, S. (2022b). Mathematical models for optimization of anaerobic digestion and biogas production. Springer.
Arcibar-Orozco, J. A., Saldaña-Robles, A., Rangel-Méndez, R., Nielsen, L., Baltazar-Campos, H., Garduño-Cruces, E. A., Hernandez-López, B. V., & Caballero-Briones, F. (2023). Revalorization of chromium-tanned leather shavings into carbon materials and re-tanning solution. Biomass Conversion and Biorefinery, 1–13.
Ayele, M., Limeneh, D. Y., Tesfaye, T., Mengie, W., Abuhay, A., Haile, A., & Gebino, G. (2021). A review on utilization routes of the leather industry biomass. Advances in Materials Science and Engineering, 2021, 1–15.
Bhardwaj, M., Ram, N. R., & Nikhil, G. (2023). Systematic metabolic pathway analysis of selective hydrolytic strains for anaerobic fermentation of food waste and identification of molecular markers during stress response. Materials Today: Proceedings.
Bhavanam, A., Kumar, A., Neeraj, & Nikhil, G. (2021). Biological and thermochemical strategies for building biorefinery platform. In International conference on chemical, bio and environmental engineering (pp. 33–56). Springer.
Booramurthy, V. K., Kasimani, R., Subramanian, D., & Pandian, S. (2020). Production of biodiesel from tannery waste using a stable and recyclable nano-catalyst: Optimization and kinetic study. Fuel, 260, 116373.
Buljan, J., Reich, G. & Ludvik, J. (2000). Mass balance in leather processing. United Nations industrial development Organization. Regional programme for pollution control in the tanning industry in South-East Asia.
Cataldo, A., Grieco, A., Prete, A. D., Cannazza, G., & Benedetto, E. D. (2016). Innovative method for traceability of hides throughout the leather manufacturing process. The International Journal of Advanced Manufacturing Technology, 86, 3563–3570.
Catalina, M., Attenburrow, G. E., Cot, J., Covington, A. D., & Antunes, A. P. M. (2011). Influence of crosslinkers and crosslinking method on the properties of gelatin films extracted from leather solid waste. Journal of Applied Polymer Science, 119, 2105–2111.
Catalina, M., Cot, J., Balu, A. M., Serrano-Ruiz, J. C., & Luque, R. (2012). Tailor-made biopolymers from leather waste valorization. Green Chemistry, 14, 308–312.
Chen, N., Brown, E. M., & Liu, C.-K. (2021). Conversion of tannery waste into value-added products. ACS Publications.
Chen, L., Qiang, T., Chen, X., Ren, W., & Zhang, H. J. (2022a). Gelatin from leather waste to tough biodegradable packaging film: One valuable recycling solution for waste gelatin from leather industry. Waste Management, 145, 10–19.
Chen, X., Xu, L., Ren, Z., Jia, F., & Yu, Y. (2022b). Sustainable supply chain management in the leather industry: A systematic literature review. International Journal of Logistics Research and Applications, 1–41.
Chilakamarry, C. R., Mahmood, S., Saffe, S. N. B. M., Arifin, M. A. B., Gupta, A., Sikkandar, M. Y., Begum, S. S., & Narasaiah, B. (2021). Extraction and application of keratin from natural resources: a review. 3 Biotech, 11, 1–12.
China, C. R., Maguta, M. M., Nyandoro, S. S., Hilonga, A., Kanth, S. V., & Njau, K. N. (2020). Alternative tanning technologies and their suitability in curbing environmental pollution from the leather industry: A comprehensive review. Chemosphere, 254, 126804.
Chojnacka, K., Skrzypczak, D., Mikula, K., Witek-Krowiak, A., Izydorczyk, G., Kuligowski, K., Bandrów, P., & Kułażyński, M. (2021). Progress in sustainable technologies of leather wastes valorization as solutions for the circular economy. Journal of Cleaner Production, 313, 127902.
De Souza, F. D. R., Benvenuti, J., Meyer, M., Wulf, H., Klüver, E., & Gutterres, M. (2022). Extraction of keratin from unhairing of bovine hide. Chemical Engineering Communications, 209, 118–126.
Dumitra, C. M., Deselnicu, D. C., & Semenescu, A. (2023). Waste from the leather industry-a research in current context. Nonconventional Technologies Review/Revista de Tehnologii Neconventionale, 27.
Dwivedi, A., Agrawal, D., & Madaan, J. (2019). Sustainable manufacturing evaluation model focusing leather industries in India: A TISM approach. Journal of Science and Technology Policy Management, 10, 319–359.
Ferreira, M. J., & Almeida, M. F. (2011). Recycling of leather waste containing chromium—A review. Materials Science Research Journal, 5, 327.
Gomes, C. S., Repke, J. U., & Meyer, M. (2020). The effect of various pre-treatment methods of chromium leather shavings in continuous biogas production. Engineering in Life Sciences, 20, 79–89.
Hossain, A., Sultana, R., Moktadir, A., & Hossain, A. (2023). A novel bio-adsorbent development from tannery solid waste derived biodegradable keratin for the removal of hazardous chromium: A cleaner and circular economy approach. Journal of Cleaner Production, 137471.
Jiang, H., Liu, J., & Han, W. (2016). The status and developments of leather solid waste treatment: A mini-review. Waste Management & Research, 34, 399–408.
John Sundar, V., Gnanamani, A., Muralidharan, C., Chandrababu, N. K., & Mandal, A. B. (2011). Recovery and utilization of proteinous wastes of leather making: A review. Reviews in Environmental Science and Bio/technology, 10, 151–163.
Joseph, K., & Nithya, N. (2009). Material flows in the life cycle of leather. Journal of Cleaner Production, 17, 676–682.
Kanagaraj, J., Senthilvelan, T., Panda, R., & Kavitha, S. (2015). Eco-friendly waste management strategies for greener environment towards sustainable development in leather industry: A comprehensive review. Journal of Cleaner Production, 89, 1–17.
Karthikeyan, R., Balaji, S., & Sehgal, P. (2007). Industrial applications of keratins–A review.
Kolomaznik, K., Barinova, M., & Fürst, T. (2009). Possibility of using tannery waste for biodiesel production. Journal of the American Leather Chemists Association, 104, 177–182.
Koppiahraj, K., Bathrinath, S., & Saravanasankar, S. (2019). Leather waste management scenario in developed and develo** nations. International Journal of Engineering and Advanced Technology, 9, 852–857.
Kumar, V. K., Mahendiran, R., Subramanian, P., Karthikeyan, S., & Surendrakumar, A. (2022). Optimization of inoculum to substrate ratio for enhanced methane yield from leather fleshings in a batch study. Journal of the Indian Chemical Society, 99, 100384.
Li, A., Ge, W., Liu, L., & Qiu, G. (2022). Preparation, adsorption performance and mechanism of MgO-loaded biochar in wastewater treatment: A review. Environmental Research, 212, 113341.
Li, Y., Guo, R., Lu, W., & Zhu, D. (2019). Research progress on resource utilization of leather solid waste. Journal of Leather Science and Engineering, 1, 1–17.
Mella, B., Benvenuti, J., Oliveira, R. F., & Gutterres, M. (2019). Preparation and characterization of activated carbon produced from tannery solid waste applied for tannery wastewater treatment. Environmental Science and Pollution Research, 26, 6811–6817.
Mohan, S. V., Nikhil, G., Chiranjeevi, P., Reddy, C. N., Rohit, M., Kumar, A. N., & Sarkar, O. J. B. T. (2016). Waste biorefinery models towards sustainable circular bioeconomy: Critical review and future perspectives, 215, 2–12.
Moktadir, M. A., Ahmadi, H. B., Sultana, R., Liou, J. J., & Rezaei, J. (2020). Circular economy practices in the leather industry: A practical step towards sustainable development. Journal of Cleaner Production, 251, 119737.
Moktadir, M. A., & Rahman, M. M. (2022). Energy production from leather solid wastes by anaerobic digestion: A critical review. Renewable and Sustainable Energy Reviews, 161, 112378.
Moza, A., Ram, N. R., Srivastava, N., & Nikhil, G. (2022). Bioprocessing of low-value food waste to high-value volatile fatty acids for applications in energy and materials: A review on process-flow. Bioresource Technology Reports, 101123.
Mozhiarasi, V., Krishna, B. B., Nagabalaji, V., Srinivasan, S. V., Bhaskar, T., & Suthanthararajan, R. (2021). Leather industry waste based biorefinery. Elsevier.
Muralidharan, V., Palanivel, S., & Balaraman, M. (2022). Turning problem into possibility: A comprehensive review on leather solid waste intra-valorization attempts for leather processing. Journal of Cleaner Production, 133021.
Nazer, D. W., & Siebel, M. A. (2006). Reducing the environmental impact of the unhairing–liming process in the leather tanning industry. Journal of Cleaner Production, 14, 65–74.
Omoloso, O., Mortimer, K., Wise, W. R., & Jraisat, L. (2021). Sustainability research in the leather industry: A critical review of progress and opportunities for future research. Journal of Cleaner Production, 285, 125441.
Omoloso, O., Wise, W., Mortimer, K., Jraisat, L., & Omoloso, S. (2020). Corporate sustainability disclosure: A leather industry perspective. Emerging Science Journal, 4, 1–11.
Ossai, I. C., Hamid, F. S., & Hassan, A. (2022). Valorisation of keratinous wastes: A sustainable approach towards a circular economy. Waste Management, 151, 81–104.
Parisi, M., Nanni, A., & Colonna, M. (2021). Recycling of chrome-tanned leather and its utilization as polymeric materials and in polymer-based composites: A review. Polymers, 13, 429.
Patel, K., Munir, D., & Santos, R. M. (2022). Beneficial use of animal hides for abattoir and tannery waste management: A review of unconventional, innovative, and sustainable approaches. Environmental Science and Pollution Research, 1–17.
Pati, A., Chaudhary, R., & Subramani, S. (2014). A review on the management of chrome-tanned leather shavings: A holistic paradigm to combat the environmental issues. Environmental Science and Pollution Research, 21, 11266–11282.
Piccin, J. S., Gomes, C. S., Mella, B., & Gutterres, M. (2016). Color removal from real leather dyeing effluent using tannery waste as an adsorbent. Journal of Environmental Chemical Engineering, 4, 1061–1067.
Priebe, G., Kipper, E., Gusmão, A., Marcilio, N., & Gutterres, M. (2016). Anaerobic digestion of chrome-tanned leather waste for biogas production. Journal of Cleaner Production, 129, 410–416.
Ram, N. R., & Nikhil, G. (2022). A critical review on sustainable biogas production with focus on microbial-substrate interactions: Bottlenecks and breakthroughs. Bioresource Technology Reports, 101170.
Reddy, C. C., Khilji, I. A., Gupta, A., Bhuyar, P., Mahmood, S., Al-Japairai, K. A. S., & Chua, G. K. (2021). Valorization of keratin waste biomass and its potential applications. Journal of Water Process Engineering, 40, 101707.
Rigueto, C. V. T., Rosseto, M., Krein, D. D. C., Ostwald, B. E. P., Massuda, L. A., Zanella, B. B., & Dettmer, A. (2020). Alternative uses for tannery wastes: A review of environmental, sustainability, and science. Journal of Leather Science and Engineering, 2, 1–20.
Sai Bhavya, K., Selvarani, A., V Samrot, A., Javad, M., Thevarkattil, P., & Vvss, A. (2019). Leather processing, its effects on environment, and alternatives of chrome tanning. International Journal of Advanced Research in Engineering and Technology (IJARET), 10.
Saira, G., & Shanthakumar, S. (2023). Zero waste discharge in tannery industries–An achievable reality? A recent review. Journal of Environmental Management, 335, 117508.
Sathish, M., Madhan, B., & Rao, J. R. (2019). Leather solid waste: An eco-benign raw material for leather chemical preparation–A circular economy example. Waste Management, 87, 357–367.
Senthilkumar, N., Chowdhury, S., & Sanpui, P. (2023). Extraction of keratin from keratinous wastes: Current status and future directions. Journal of Material Cycles and Waste Management, 25, 1–16.
Shanmugam, P., & Horan, N. (2009). Optimising the biogas production from leather fleshing waste by co-digestion with MSW. Bioresource Technology, 100, 4117–4120.
Sharma, N., & Vuppu, S. (2023). Computational modelling and molecular docking of industrial leather enzymes. Molecular Biotechnology, 1–19.
Sharma, S., & Gupta, A. (2016). Sustainable management of keratin waste biomass: Applications and future perspectives. Brazilian Archives of Biology and Technology, 59.
Shaw, S., Chattopadhyay, P. K., Singha, N. R., & Mukherjee, G. (2022). Resource utilisation of solid leather waste: Part I. Journal of the Society of Leather Technologists and Chemists, 106, 137–144.
Simioni, T., Agustini, C. B., Dettmer, A., & Gutterres, M. (2022). Enhancement of biogas production by anaerobic co-digestion of leather waste with raw and pretreated wheat straw. Energy, 253, 124051.
Sivaram, N., & Barik, D. (2019). Toxic waste from leather industries. Elsevier.
Sultana, R., Dwivedi, A., & Moktadir, M. A. (2022). Investigating the role of consumers, producers, and policymakers: A case of leather supply chain towards sustainable chemistry. Current Opinion in Green and Sustainable Chemistry, 100724.
Suresh, V., Kanthimathi, M., Thanikaivelan, P., Rao, J. R., & Nair, B. U. (2001). An improved product-process for cleaner chrome tanning in leather processing. Journal of Cleaner Production, 9, 483–491.
Taghipour, M., & Jalali, M. (2016). Influence of organic acids on kinetic release of chromium in soil contaminated with leather factory waste in the presence of some adsorbents. Chemosphere, 155, 395–404.
Tang, Y., Zhao, J., Zhang, Y., Zhou, J., & Shi, B. (2021). Conversion of tannery solid waste to an adsorbent for high-efficiency dye removal from tannery wastewater: A road to circular utilization. Chemosphere, 263, 127987.
Velvizhi, G., Ranjitha, J., Vijayalakshmi, S., & Nikhil, G. (2020). Advancements in nanobiocatalysis for bioenergy and biofuel production. CRC Press.
Verma, S. K., & Sharma, P. C. (2022). Current trends in solid tannery waste management. Critical Reviews in Biotechnology, 1–18.
Wang, Y.-N., Zeng, Y., Zhou, J., Zhang, W., Liao, X., & Shi, B. (2016). An integrated cleaner beamhouse process for minimization of nitrogen pollution in leather manufacture. Journal of Cleaner Production, 112, 2–8.
Yang, M., Yan, L., Li, Y., Huang, P., Han, W., & Dang, X. (2022). An environment-friendly leather waste-based liquid film mulching and its application for facilitating the growth of maize crops. Process Safety and Environmental Protection, 159, 1236–1244.
Yuliana, M., Santoso, S. P., Soetaredjo, F. E., Ismadji, S., Ayucitra, A., Angkawijaya, A. E., Ju, Y.-H., & Tran-Nguyen, P. L. (2020). A one-pot synthesis of biodiesel from leather tanning waste using supercritical ethanol: Process optimization. Biomass and Bioenergy, 142, 105761.
Yuliana, M., Santoso, S. P., Soetaredjo, F. E., Ismadji, S., Ayucitra, A., Gunarto, C., Angkawijaya, A. E., Ju, Y.-H., & Truong, C.-T. (2021). Efficient conversion of leather tanning waste to biodiesel using crab shell-based catalyst: WASTE-TO-ENERGY approach. Biomass and Bioenergy, 151, 106155.
Zhang, C., **a, F., Long, J., & Peng, B. (2017). An integrated technology to minimize the pollution of chromium in wet-end process of leather manufacture. Journal of Cleaner Production, 154, 276–283.
Zhang, X., Chattha, S. A., Song, J., Zhang, C., & Peng, B. (2022). An integrated pickling-bating technology for reducing ammonia-nitrogen and chloride pollution in leather manufacturing. Journal of Cleaner Production, 375, 134070.
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Appala, V.N.S.G., Pandhare, N.N., Bajpai, S., Nikhil, G.N. (2024). Valorization of Leather Industry Solid Waste for Sustainability Through a Biorefinery Approach. In: Arya, R.K., Verros, G.D., Verma, O.P., Hussain, C.M. (eds) From Waste to Wealth. Springer, Singapore. https://doi.org/10.1007/978-981-99-7552-5_51
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