Abstract
This Chapter covers the basic knowledge and recent developments on quantitative detection of small ionic species. The broad diversity of approaches exists regarding selection and operation of recognition units. Meantime, three major principles in fluorescence reporting dominate in ion sensing. They are the ionization behavior of coupled to fluorophore charged groups, the modulation of photophysical processes in fluorophore (such as electron, proton, charge and energy transfers) and chemodosimetry (chemical transformations in fluorophore changing its fluorescence). The possibilities for obtaining the wavelength-ratiometric reporting signal in these cases are highlighted.
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Demchenko, A.P. (2023). Quantitative Fluorescent Detection of Ions. In: Introduction to Fluorescence Sensing. Springer, Cham. https://doi.org/10.1007/978-3-031-19089-6_9
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