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Applications of MOFs

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Physicochemical Aspects of Metal-Organic Frameworks

Part of the book series: Engineering Materials ((ENG.MAT.))

Abstract

Metal–organic frameworks (MOFs), a family of porous crystalline materials generated by coordinated-metal ions in organic linkers, have gained more attention in the last decades due to their distinct structures and diverse uses. However, there are still technical obstacles to their practical implementation owing to MOFs’ inherent fragility and their tiny powder form, such as pipe obstruction, recovery challenges, and possible environmental toxicity. To get over these constraints, research has concentrated on ways to transform nanocrystalline MOFs into macroscopic materials. Recently, methods for forming MOFs into macrostructure beads (0D), nanofibers (1D), membranes (2D), gels/sponges (3D), and membranes with in situ growth or deposition of MOFs with polymers, cotton, foams, or other porous substrates have been devised. This chapter discusses the different uses of MOFs, including biochemistry, cancer treatment, the adsorption of pollutants, and others.

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Notes

  1. 1.

    current density (mA.cm−2), CN: cycle number. (*aqueous redox flow batteries).

  2. 2.

    Vanadium redox flow battery.

  3. 3.

    lithium metal batteries.

  4. 4.

    sodium metal batteries.

  5. 5.

    Secondary lithium-bromine (Li–Br2) batteries.

  6. 6.

    lithium–sulfur batteries.

  7. 7.

    Lithium-Ion Batteries.

  8. 8.

    Ketjen Black (KB).

  9. 9.

    Cellulose nanofiber.

  10. 10.

    power conversion efficiency.

  11. 11.

    short-circuit current density.

  12. 12.

    open-circuit voltage.

  13. 13.

    fill factor.

  14. 14.

    Matrimid/NH2-PVDF (97/3) + 7 wt% NH2-MIL-101(Cr).

  15. 15.

    polystyrene-acrylate (PSA) modified hollow ZIF-8 (PHZ).

  16. 16.

    2D/2D FeNi-layered double hydroxide/bimetal-organic frameworks nanosheets.

  17. 17.

    Tetracycline hydrochloride.

  18. 18.

    Orange peel peroxidase.

  19. 19.

    Methylene blue.

  20. 20.

    Congo red.

  21. 21.

    Tetracycline.

  22. 22.

    Aerogels.

  23. 23.

    P-nitrophenol.

  24. 24.

    Sulfamethoxazole.

  25. 25.

    Carbamazepine.

  26. 26.

    Hydroxyapatite nanowires.

  27. 27.

    Direct red 23.

  28. 28.

    Diatom biosilica.

  29. 29.

    Malachite green.

  30. 30.

    Nanofibers.

  31. 31.

    Ionic liquid.

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  1. Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, 16846-13114, Tehran, Iran

    Mohammad Mehdi Salehi & Fereshte Hassanzadeh-Afruzi

  2. Institute for Nanoscience and Nanotechnology, Sharif University of Technology, Tehran, Iran

    Farhad Esmailzadeh

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  3. Fereshte Hassanzadeh-Afruzi
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    Ali Maleki

  2. Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran, Iran

    Reza Taheri-Ledari

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Salehi, M.M., Esmailzadeh, F., Hassanzadeh-Afruzi, F. (2023). Applications of MOFs. In: Maleki, A., Taheri-Ledari, R. (eds) Physicochemical Aspects of Metal-Organic Frameworks. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-031-18675-2_13

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