Abstract
The use of muonic X-rays for cultural heritage studies has steadily increased over the past few years. This includes investigations ranging from ancient coins to statues to meteorites to biomaterials. These studies use negative muons, which with a controllable momentum have a well-defined implantation depth (from microns to cm). This technique has many similarities to X-ray fluorescence, except that the negative muon has a mass ~200 times greater than that of an electron. This results in the emission of high energy X-rays in the range of 10s keV to 8 MeV. Therefore enabling elements from Li and upwards (in Z) being easily observed. Also, elements next to each other in the periodic table can be distinguished. Moreover, the final interaction with the negative muon and the nucleus can cause the emission of isotope specific gammas. Thus, enabling the possibility of isotope analysis. This chapter is a general introduction to the technique followed by a range of examples. This hopefully showcases the basics and the power of this unique and increasingly popular technique.
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References
Rosen L (1971) Relevance of particle accelerators to national goals. Science 173:490–497
Daniel H (1969) The muon as a tool for scanning the interior of the human body. Nucl Med 4:311–319
Köhler E, Bergmann R, Daniel H, Ehrhart P, Hartmann FJ (1981) Application of muonic X-ray techniques to the elemental analysis of archeological objects. Nucl Instrum Methods Phys Res 187:563–568
Daniel H, Hartmann FJ, Köhler E (1985) Analysis of glasses with muonic X-rays. Fresenius Z Anal Chem 321:65–67
Hillier AD, Paul DMcK, Ishida K (2015) Probing beneath the surface without a scratch — Bulk non-destructive elemental analysis using negative muons. Microchem J 125:203–207
Ninomiya K, Nagatomo T, Kubo KM, Strasser P, Kawamura N, Shimomura K, Miyake Y, Saito T, Higemoto W (2010) Development of elemental analysis by muonic X-ray measurement. J-PARC 225:012040
Engfer R, Schneuwly H, Vuilleumier JL, Walter HK, Zehnder A (1974) Charge-distribution parameters, isotope shifts, isomer shifts, and magnetic hyperfine constants from muonic atoms. Atomic Data Nucl Tables 14:509–597
Zinatulina D, Brianҫon C, Brudanin V, Egorov V, Perevoshchikov L, Shirchenko M, Yutlandov I, Petitjean C (2018) Electronic catalogue of muonic X-rays. Eur Phys J Conf 177(6):03006
Thomason JWG (2019) The ISIS Spallation Neutron and Muon Source – the first thirty three years. Nucl Instrum Methods Phys Res A 917:61–67
Matsuzaki T, Ishida K, Nagamine K, Watanabe I, Eaton GH, Williams WG (2001) The RIKEN-RAL pulsed muon facility. Nucl Instrum Methods Phys Res A 465:365–383
Hillier AD, Lord JS, Ishida K, Rogers C (2019) Muons at ISIS. Philos Trans R Soc A Math Phys Eng Sci 377:1–7
Eaton GH, Carne A, Cox SFJ, Davies JD, De Renzi R, Hartmann O, Kratzer A, Ristori C, Scott CA, Stirling GC, Sundqvist T (1988) Commissioning of the Rutherford Appleton pulsed muon facility. Nucl Instrum Methods Phys Res A A269:483–491
Hillier AD, Adams DJ, Baker PJ, Bekasovs A, Coomer FC, Cottrell SP, Higgins SD, Jago SJS, Jones KG, Lord JS, Markvardsen A, Parker PG, Peck JNT, Pratt FL, Telling MTF, Williamson RE (2014) Developments at the ISIS muon source and the concomitant benefit to the user community. J Phys Conf Ser 551:012067
Eaton GH, Clarke-Gayther MA, Scott CA, Uden CN, Williams WG (1993) Fast E-field switching of a pulsed surface muon beam: the commissioning of the European muon facility at ISIS. Nucl Instrum Methods Phys Res A 342:319–331
Miyake Y, Shimomura K, Kawamura N, Strasser P, Koda A, Makimura S, Fujimori H, Ikedo Y, Nakahara K, Takeshita S, Kato M, Kojima K, Kobayashi Y, Nishiyama K, Kadono R, Higemoto W, Itoc TU, Ninomiya K, Kubo K, Nagamine K (2012) J-PARC muon facility, MUSE. Phys Procedia 30:46–49
Marshall GM (1992) Muon beams and facilities at TRIUMF. In: Jungmann K, Hughes VW, zu Putlitz G (eds) The future of muon physics, vol 56(Suppl 1). Springer, Berlin/Heidelberg, pp S226–S231
CMMS. TRIUMF. [Online] [Cited: 9 30, 2019]. http://musr.ca/
SmuS Beamlines. PSI. [Online] [Cited: 9 30, 2019]. https://www.psi.ch/en/smus/beamlines
Ziegler J (2015) SRIM – the stop** and range of ions in matter
Ninomiya K, Kubo MK, Nagatomo T, Higemoto W, Ito TU, Kawamura N, Strasser P, Shimomura K, Miyake Y, Suzuki T, Kobayashi Y, Sakamoto S, Shinohara A, Sait T (2015) nondestructive elemental depth-profiling analysis by muonic X-ray measurement. Anal Chem 87:4597
Kubo MK, Moriyama H, Tsuruoka Y, Sakamoto S, Koseto E, Saito T, Nishiyama K (2008) Non-destructive elemental depth-profiling with muonic X-rays. J Radioanal Nucl Chem 278:777–781
Measday DF (2001) The nuclear physics of muon capture. Phys Rep 354:243–409
Borie E, Rinker GA (1982) The energy levels of muonic atoms. Rev Mod Phys 54:67–118
Evans HJ (1973) Gamma-rays following muon capture. Nucl Phys A A207:379–400
Anderson HL, Hargrove CK, Hincks EP, McAndrews JD, McKee RJ, Barton RD, Kessler D (1969) Precise measurement of the muonic X rays in the lead isotopes. Phys Rev 187:1565–1596
Kessler D, McKee RI, Hargrove CK, Hlncks EP, Anderson HL (1970) Muonic X rays and capture γ rays in 89Y. Can J Phys 48:3029
Backenstoss G, Charalambus S, Darnel H, Hamdton WD, Lynen U, von der Malsburg C, Poelz G, Pove HP (1971) Nuclear γ-rays following muon capture. Nucl Phys A162:541
Live Chart of Nuclides. [Online] IEAE. [Cited: September 14, 2019]. https://www-nds.iaea.org/relnsd/vcharthtml/VChartHTML.html
Fermi E, Teller E (1947) The capture of negative mesotrons in matter. Phys Rev 72:399
Vasilyev VA, Petrukhin VI, Risin VE, Suvorov VM, Horváth D (1976) Dubna Report, vol JINR R1, p 10222
Schneuwly H, Pokrovsky VI, Ponomarev LI (1978) On coulomb capture ratios of negative mesons in chemical compounds. Nucl Phys A 312:419
Daniel H (1979) Z Phys A 291:29
von Egidy T, Jakubassa-Amundsen DH, Hartmann FJ (1982) Phys Rev A 29:455
Ponting K, Butcher M (2015) The Metallurgy of Roman silver coinage: from the reform of Nero to the reform of Trajan. Cambridge University Press, Cambridge, UK, pp 100–129
Moreno-Suárez AI, Ager FJ, Scrivano S, Ortega-Feliu I, Gómez-Tubío B, Respaldiza MA (2015) First attempt to obtain the bulk composition of ancient silver–copper coins by using XRF and GRT. Nucl Instrum Methods Phys Res B 358:93–97
Hampshire BV, Butcher K, Ishida K, Green G, Paul DM, Hillier AD (2019) Using negative muons as a probe for depth profiling silver Roman Coinage. 2:400–407
Ueda M, Taguchi I, Saito Y (1996) Non-destructive analysis of the fineness of Kobans in the Yedo period. 1996-E-26. Institute for Monetary and Economic Studies
Terada K, Ninomiya K, Osawa T, Tachibana S, Miyake Y, Kubo MK, Kawamura N, Higemoto W, Tsuchiyama A, Ebihara M, Uesugi M (2014) A new X-ray fluorescence spectroscopyfor extraterrestrial materials using a muonbeam. Sci Rep 4:5072
Terada K, Sato A, Ninomiya K, Kawashima Y, Shimomura K, Yoshida G, Kawai Y, Osawa T, Tachibana S (2017) Non-destructive elemental analysis of a carbonaceous chondrite with direct current Muon beam at MuSIC. Sci Rep 7:15478
Reidy J, Hutson R, Daniel H, Springer K (1978) Use of muonic X rays for nondestructive analysis of bulk samples of low Z constituents. Anal Chem 50:40–44
Reidy J, Hutson R, Springer K (1975) Use of muonic X-rays for tissue analysis. IEEE Trans Nucl Sci NS-22:1780–1783
Goucher CL, Teilhet JH, Wilson KR, Chow T (1976) Lead isotope studies of metal source for ancient Nigerian ‘bronzes’. Nature 262:130–131
Brill RH, Yamakaki K, Barnes IL, Rosman KJR, Diaz M (1979) Lead isotopes in some Japanese and Chinese glasses. Airs Orient 11:87–109
Ninomiya K, Kudo T, Strasser P, Terada K, Kawai Y, Tampo M, Miyake Y, Shinohara A, Kubo KM (2019) Development of non-destructive isotopic analysis methods using muon beams and their application to the analysis of lead. J Radioanal Nucl Chem 320:801–805
Ninomiya K, Kubo MK, Strasser P, Shinohara A, Tampo M, Kawamura N, Miyake Y (2018) Isotope identification of lead by muon induced X-ray and gamma-ray measurements. JPS Conf Proc 21:011043
Hillier A, Ishida K, Seller P, Veale MC, Wilson MD (2018) Element specific imaging using muonic X-rays. JPS Conf Proc 21:011042
Yabu G, Katsuragawa M, Tampo M, Hamada K, Harayama A, Miyake Y, Oshita S, Saito S, Sato G, Takahashi T, Takeda S, Watanabe S (2018) Imaging of muonic X-ray of light elements with a CdTe double-sided strip detector. JPS Conf Ser 21:011044
JINR. Joint Institute for Nuclear Research (2019) Dzhelepov Laboratory of Nuclear Problems, Scientific Experimental Department of Nuclear Spectroscopy and Radiochemistry. Mu X-ray Catalogue. [Online]. [Cited: 9 29, 2019]. http://muxrays.**r.ru/
Groom DE, Mokhov NV, Striganov S (2001) Muon stop** power and range tables. At Data Nucl Data Tables 76:1
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Hillier, A.D., Hampshire, B., Ishida, K. (2022). Depth-Dependent Bulk Elemental Analysis Using Negative Muons. In: D'Amico, S., Venuti, V. (eds) Handbook of Cultural Heritage Analysis. Springer, Cham. https://doi.org/10.1007/978-3-030-60016-7_3
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DOI: https://doi.org/10.1007/978-3-030-60016-7_3
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