Abstract
Self-healing Metal Matrix Composites (SHMMCs) have emerged as an important field of research in materials engineering. This paper critically examines the current state of the art of SHMMCs, including matrix alloys, reinforcements, crack orientation, and stress states under which self-healing has been studied. The significance of characteristics of SMA reinforcement, including size, length, distribution, and interface strength, is presented. Challenges in synthesizing SHMMCs, including achieving wetting, bonding, and load transfer between the metal matrix and the reinforcement, overcoming the problem due to oxidation, and irregularities of cracked surfaces, are discussed. Needs of future research directions are outlined, including examining thermodynamics and kinetics of self-healing, design of microstructure based on mechanics for targeted self-healing, and develo** capabilities of autonomous and capacity for multicycle healing in metals, especially in high temperatures metals and alloys. The need for develo** self-healing and shape-changing capabilities in man-made materials similar to biological living materials is discussed.
Graphical abstract
Similar content being viewed by others
Data availability
Not applicable.
References
M. Nosonovsky, P.K. Rohatgi, Biomimetics in materials science: self-healing, self-lubricating, and self-cleaning materials (Springer, New York, 2012)
M. Bellah, M. Nosonovsky, P. Rohatgi, Recent advances in self-healing metal matrix composites, in Metal-matrix composites. ed. by T.S. Srivatsan, P.K. Rohatgi, S. Hunyadi Murph (Springer, Cham, 2022), pp.297–310
M. Bellah, M. Nosonovsky, P. Rohatgi, Shape memory alloy reinforced self-healing metal matrix composites. Appl. Sci. 13(12), 6884 (2023)
Y. Wang, D. Jiang, L. Zhang, B. Li, C. Sun, H. Yan, Z. Wu, H. Liu, J. Zhang, J. Fan, H. Hou, T. Ding, Z. Guo, Hydrogen bonding derived self-healing polymer composites reinforced with amidation carbon fibers. Nanotechnology 31(2), 025704 (2019)
B.J. Blaiszik, S.L.B. Kramer, S.C. Olugebefola, J.S. Moore, N.R. Sottos, S.R. White, Self-healing polymers and composites. Annu. Rev. Mater. Res. 40(1), 179–211 (2010)
S. Wang, M.W. Urban, Self-healing polymers. Nat. Rev. Mater. 5(8), 562–583 (2020)
C.-H. Li, J.-L. Zuo, Self-healing polymers based on coordination bonds. Adv. Mater. 32(27), 1903762 (2020)
L. Zhai, A. Narkar, K. Ahn, Self-healing polymers with nanomaterials and nanostructures. Nano Today 30, 100826 (2020)
M. Goyal, S.N. Agarwal, N. Bhatnagar, A review on self-healing polymers for applications in spacecraft and construction of roads. J. Appl. Polym. Sci. 139(37), e52816 (2022)
S.R. White, N.R. Sottos, P.H. Geubelle, J.S. Moore, M.R. Kessler, S.R. Sriram, E.N. Brown, S. Viswanathan, Autonomic healing of polymer composites. Nature 409(6822), 794–797 (2001)
V.K. Thakur, M.R. Kessler, Self-healing polymer nanocomposite materials: a review. Polymer 69, 369–383 (2015)
R.S. Trask, H.R. Williams, I.P. Bond, Self-healing polymer composites: mimicking nature to enhance performance. Bioinspir. Biomim. 2(1), P1 (2007)
I.L. Hia, V. Vahedi, P. Pasbakhsh, Self-healing polymer composites: prospects, challenges, and applications. Polym. Rev. 56(2), 225–261 (2016)
M. Amran, A.M. Onaizi, R. Fediuk, N.I. Vatin, R.S. Muhammad Rashid, H. Abdelgader, T. Ozbakkaloglu, Self-healing concrete as a prospective construction material: a review. Materials 15(9), 3214 (2022)
C. Xue, W. Li, J. Li, V.W.Y. Tam, G. Ye, A review study on encapsulation-based self-healing for cementitious materials. Struct. Concr. 20(1), 198–212 (2019)
G. Perrot, G. Couégnat, M. Ricchiuto, G.L. Vignoles, Image-based numerical modeling of self-healing in a ceramic-matrix minicomposite. Ceramics 2(2), 308–326 (2019)
P. Greil, Self-healing engineering ceramics with oxidation-induced crack repair. Adv. Eng. Mater. 22(9), 1901121 (2020)
B. Wang, R. Tu, Y. Wei, H. Cai, Self-healing of SiC–Al2O3–B4C ceramic composites at low temperatures. Materials 15(2), 652 (2022)
I. Justo-Reinoso, A. Heath, S. Gebhard, K. Paine, Aerobic non-ureolytic bacteria-based self-healing cementitious composites: a comprehensive review. J. Build. Eng. 42, 102834 (2021)
K.W. Shah, G.F. Huseien, Biomimetic self-healing cementitious construction materials for smart buildings. Biomimetics 5(4), 47 (2020)
C. Fernandez, M. Correa, M.-T. Nguyen, K. Rod, G. Dai, L. Cosimbescu, R. Rousseau, V.-A. Glezakou, Progress and challenges in self-healing cementitious materials. J. Mater. Sci. 56, 1–30 (2021)
V.C. Li, Y.M. Lim, Y.-W. Chan, Feasibility study of a passive smart self-healing cementitious composite. Compos. Part B Eng. 29(6), 819–827 (1998)
X.F. Wang, Z.H. Yang, C. Fang, N.X. Han, G.M. Zhu, J.N. Tang, F. **ng, Evaluation of the mechanical performance recovery of self-healing cementitious materials—its methods and future development: a review. Constr. Build. Mater. 212, 400–421 (2019)
J.B. Ferguson, B.F. Schultz, P.K. Rohatgi, Self-healing metals and metal matrix composites. JOM 66(6), 866–871 (2014)
V. Kilicli, X. Yan, N. Salowitz, P.K. Rohatgi, Recent advancements in self-healing metallic materials and self-healing metal matrix composites. JOM 70(6), 846–854 (2018)
M. Arseenko, J. Gheysen, F. Hannard, N. Nothomb, A. Simar, Self-healing in metal-based systems, in Self-healing construction materials: fundamentals, monitoring and large scale applications. ed. by A. Kanellopoulos, J. Norambuena-Contreras (Springer, Cham, 2022), pp.43–78
B. Grabowski, C.C. Tasan, Self-healing metals, in Self-healing materials. ed. by M.D. Hager, S. van der Zwaag, U.S. Schubert (Springer, Cham, 2016), pp.387–407
N. van Dijk, S. van der Zwaag, Self-healing phenomena in metals. Adv. Mater. Interfaces 5(17), 1800226 (2018)
J. Martinez-Lucci, R.S. Amano, P. Rohatgi, Review in self healing in metal matrix composites. J. Aeronaut. Astronaut. Aviat. 53(4), 441–472 (2021)
E.N. Brown, N.R. Sottos, S.R. White, Fracture testing of a self-healing polymer composite. Exp. Mech. 42(4), 372–379 (2002)
A.C. Balazs, Modeling self-healing materials. Mater. Today 10(9), 18–23 (2007)
A.C. de Oliveira Gonzalez, T.F. Costa, Z. de Araújo Andrade, A.R.A.P. Medrado, Wound healing—a literature review. An. Bras. Dermatol. 91(5), 614–620 (2016)
K.S. Toohey, N.R. Sottos, J.A. Lewis, J.S. Moore, S.R. White, Self-healing materials with microvascular networks. Nat. Mater. 6(8), 581–585 (2007)
Hastrich, C., “Self healing materials|bouncing ideas” [Online]. Available: https://bouncingideas.wordpress.com/2012/02/01/self-healing-materials/. [Accessed: 13-Nov-2023].
W.A. Muller, Getting leukocytes to the site of inflammation. Vet. Pathol. 50(1), 7–22 (2013)
M. Leick, V. Azcutia, G. Newton, F.W. Luscinskas, Leukocyte recruitment in inflammation: basic concepts and new mechanistic insights based on new models and microscopic imaging technologies. Cell Tissue Res. 355(3), 647–656 (2014)
I. Gebeshuber, B. Majlis, H. Stachelberger, Tribology in biology: biomimetic studies across dimensions and across fields. Int. J. Mech. Mater. Eng. IJMME 4, 321–327 (2009)
R. Verberg, A.T. Dale, P. Kumar, A. Alexeev, A.C. Balazs, Healing substrates with mobile, particle-filled microcapsules: designing a ‘repair and go’ system. J. R. Soc. Interface 4(13), 349–357 (2007)
J.Y. Lee, G.A. Buxton, A.C. Balazs, Using nanoparticles to create self-healing composites. J. Chem. Phys. 121(11), 5531–5540 (2004)
S. Tyagi, J.Y. Lee, G.A. Buxton, A.C. Balazs, Using nanocomposite coatings to heal surface defects. Macromolecules 37(24), 9160–9168 (2004)
K.A. Smith, S. Tyagi, A.C. Balazs, Healing surface defects with nanoparticle-filled polymer coatings: effect of particle geometry. Macromolecules 38(24), 10138–10147 (2005)
Y. Yang, L. Gao, J. **e, Y. Zhou, J. Hu, Q. Li, J. He, Defect-targeted self-healing of multiscale damage in polymers. Nanoscale 12(6), 3605–3613 (2020)
M.A. Ganjei, E. Aflaki, Application of nano-silica and styrene-butadiene-styrene to improve asphalt mixture self healing. Int. J. Pavement Eng. 20(1), 89–99 (2019)
P.G. Kumar, Application of nano silica to improve self-healing of bitumen mixtures. Comput. Res. Prog. Appl. Sci. Eng. 6(4), 276–280 (2020)
P.E. Leser, J.A. Newman, S.W. Smith, W.P. Leser, R.A. Wincheski, T.A. Wallace, E.H. Glaessgen, R.S. Piascik, Mitigation of crack damage in metallic materials (Langley Research Center, Hampton, 2014)
X.G. Zheng, Y.-N. Shi, K. Lu, Electro-healing cracks in nickel. Mater. Sci. Eng. A 561, 52–59 (2013)
A. Ruzek, Synthesis and characterization of metallic systems with potential for self-healing (Univerity of Wisconsin, Milwaukee, 2009)
S. van der Zwaag, An introduction to material design principles: damage prevention versus damage management, in Self healing materials: an alternative approach to 20 centuries of materials science. ed. by S. van der Zwaag (Springer, Dordrecht, 2007), pp.1–18
S. van der Zwaag, Routes and mechanisms towards self healing behaviour in engineering materials. Bull. Pol. Acad. Sci. Tech. Sci. 58(2), 227 (2010)
S. van der Zwaag, N.H. van Dijk, H.M. Jonkers, S.D. Mookhoek, W.G. Sloof, Self-healing behaviour in man-made engineering materials: bioinspired but taking into account their intrinsic character. Philos. Trans. R. Soc. Math. Phys. Eng. Sci. 367(1894), 1689–1704 (2009)
N. Shinya, J. Kyono, Effect of boron nitride precipitation at cavity surface on rupture properties. Mater. Trans. 47(9), 2302–2307 (2006)
N. Shinya, J. Kyono, K. Laha, C. Masuda, Self-healing of creep damage through autonomous boron segregation and boron nitride precipitation during high temperature use of austenitic stainless steels, in Proceedings of the first international conference on self-healing materials. ed. by J. Smith (Trans Tech Publications Ltd, Stafa, 2007)
M.V. Manuel, Design of a biomimetic self-healing alloy composite (Northwestern University, Evanston, 2007)
N. Salowitz, S. Misra, M.I. Haider, M. Povolo, P. Rohatgi, Investigation into the performance of NiTi shape memory alloy wire reinforced Sn–Bi self-healing metal matrix composite. Materials 15(9), 2970 (2022)
J. Martinez Lucci, R.S. Amano, P. Rohatgi, B. Schultz, Experiment and computational analysis of self-healing in an aluminum alloy. ASME Int. Mech. Eng. Congress Expos. (2008). https://doi.org/10.1115/IMECE2008-68304
J. Martinez Lucci, R.S. Amano, P. Rohatgi, B. Schultz, Self-healing in an aluminum alloy reinforces with microtubes. Energy Nanotechnol. Int. Conf. (2008). https://doi.org/10.1115/ENIC2008-53011
O.P. Oladijo, M.O. Bodunrin, K. Sobiyi, N.B. Maledi, K.K. Alaneme, Investigating the self-healing behaviour of under-aged and 60Sn–40Pb alloy reinforced aluminium hybrid composites. Thin Solid Films 620, 201–205 (2016)
M.V. Manuel, G.B. Olson, Biomimetic self-healing metals. Proc. Int. Conf. Self-Heal. Mater. 1, 18–20 (2007)
S.K. Misra, Shape memory alloy reinforced self-healing metal matrix composites (The University of Wisconsin, Milwaukee, 2013)
M.C. Wright, M. Manuel, T. Wallace, Fatigue resistance of liquid-assisted selfrepairing aluminum alloys reinforced with shape memory alloys, 2013
C.R. Fisher, H.B. Henderson, M.S. Kesler, P. Zhu, G.E. Bean, M.C. Wright, J.A. Newman, L.C. Brinson, O. Figueroa, M.V. Manuel, Repairing large cracks and reversing fatigue damage in structural metals. Appl. Mater. Today 13, 64–68 (2018)
J.B. Ferguson, B.F. Schultz, P.K. Rohatgi, Zinc alloy ZA-8/shape memory alloy self-healing metal matrix composite. Mater. Sci. Eng. A 620, 85–88 (2015)
M.A. Poormir, S.M.R. Khalili, R. Eslami-Farsani, Investigation of the self-healing behavior of Sn–Bi metal matrix composite reinforced with NiTi shape memory alloy strips under flexural loading. JOM 70(6), 806–810 (2018)
M.A. Poormir, S.M.R. Khalili, R. Eslami-Farsani, Optimal design of a bio-inspired self-healing metal matrix composite reinforced with NiTi shape memory alloy strips. J. Intell. Mater. Syst. Struct. 29(20), 3972–3982 (2018)
V. Srivastava, M. Gupta, Experimental assessment of self-healing characteristics in AA2014matrix with nitinol wire and solder alloy as healing agents. Mater. Res. Express 6(8), 085704 (2019)
V. Srivastava, M. Gupta, Experimental assessment of self-healing nature in aluminum-based smart composites with NiTi wires and solder alloy as healing agents through taguchi approach. J. Intell. Mater. Syst. Struct. 31(18), 2101–2116 (2020)
V. Srivastava, M. Gupta, Impact of post hardening mechanism on self-healing assessment of AA2014 nitinol-based smart composites. Met. Mater. Int. 27(8), 2666–2681 (2021)
V. Srivastava, M. Gupta, Parametric assessments of self-healing characteristics in AA2014–NiTi-based metallic composites through destructive and nondestructive evaluation. Russ. J. Nondestruct. Test. 56, 1064–1082 (2020)
V. Srivastava, M. Gupta, Design and prediction of healing assessment for AA2014-nitinol strip-solder alloy based hybrid self-healing composite structure via taguchi analysis and fuzzy logic approach. Mech. Adv. Mater. Struct. 30, 1–20 (2022)
V. Srivastava, M. Gupta, Evaluation and prediction of self-healing assessments for AA2014 based hybrid smart composite structures: a novel fuzzy logic approach. Int. J. Eng. 35(10), 1841–1857 (2022)
S. Sharma, G. Nandan, R. Tyagi, P. Rohtagi, Fabrication, testing, and microstructural analysis of nitinol-based self-healing metal matrix composite of A356 alloy cast by semi-solid metal processing. Adv. Mater. Process Technol. (2023). https://doi.org/10.1080/2374068X.2023.2210932
P. Zhu, Z. Cui, M.S. Kesler, J.A. Newman, M.V. Manuel, M.C. Wright, L.C. Brinson, Characterization and modeling of three-dimensional self-healing shape memory alloy-reinforced metal-matrix composites. Mech. Mater. 103, 1–10 (2016)
P. Zhu, Shape memory alloy modeling and applications to porous and composite structures (Northwestern University, Evanston, 2015)
M.V. Manuel, C.R., Fisher, M.C., Wright, 2020, Self-repairing metal alloy matrix composites, methods of manufacture and use thereof and articles comprising the same
J.A. Monroe, J.S. McAllister, D.S. Content, J. Zgarba, X. Huerta, I. Karaman, Negative thermal expansion ALLVAR alloys for telescopes. Adv. Opt. Mech. Technol. Telesc. Instrument. 10706, 107060 (2018)
T. Hisashige, T. Yamaguchi, T. Tsuji, Y. Yamamura, Phase transition of Zr1−xHfxV2O7 solid solutions having negative thermal expansion. J. Ceram. Soc. Jpn. 114(1331), 607 (2006)
B.K. Greve, K.L. Martin, P.L. Lee, P.J. Chupas, K.W. Chapman, A.P. Wilkinson, Pronounced negative thermal expansion from a simple structure: cubic ScF3. J. Am. Chem. Soc. 132(44), 15496–15498 (2010)
M.P. Attfield, Strong negative thermal expansion in siliceous faujasite. Chem. Commun. 5, 601–602 (1998)
P. Lightfoot, D.A. Woodcock, M.J. Maple, L.A. Villaescusa, P.A. Wright, The widespread occurrence of negative thermal expansion in zeolites basis of a presentation given at materials discussion. J. Mater. Chem. 11(1), 212–216 (2001)
P. Rohatgi, Self healing metals and alloys—including structural alloys and self-healing solders. 2013, U.S. Patent 8,518,531
P. Rohatgi, Self-healing aluminum alloys incorporating shape metal alloys and reactive particles. 2013, U.S. Patent 9,435,014
P. Rohatgi, Self healing lead, tin, and their alloys, and solders, incorporating shape memory alloys, reactive particles and hollow vascular networks. 2018, U.S. Patent 10,161,026
G.Q. Xu, M.J. Demkowicz, Healing of nanocracks by disclinations. Phys. Rev. Lett. 111(14), 145501 (2013)
C.M. Barr, T. Duong, D.C. Bufford, Z. Milne, A. Molkeri, N.M. Heckman, D.P. Adams, A. Srivastava, K. Hattar, M.J. Demkowicz, B.L. Boyce, Autonomous healing of fatigue cracks via cold welding. Nature 620(7974), 552–556 (2023)
Amano, R., Rohatgi, P., Martínez Lucci, J., Schultz, B., and Ruzek, A., 2009, “Design and Demonstration of Self-Healing Behavior in a Lead-Free Solder Alloy,” 7th International Energy Conversion Engineering Conference, p. 4514.
J. Martínez Lucci, R.S. Amano, P.K. Rohatgi, Heat transfer and fluid flow analysis of self-healing in metallic materials. Heat Mass Transf. 53, 825–848 (2017)
J. Martinez-Lucci, A. Ruzek, S.K. Misra, P.K. Rohatgi, R.S. Amano, Self-healing in metal castings (11-051). AFS Trans.-Am. Foundry Soc. 119, 187 (2011)
J. Martinez-Lucci, A. Ruzek, S. Misra, P. Rohatgi, R. Amano, Can castings heal themselves? Mod. Cast. 101(7), 24–27 (2011)
J. Martínez Lucci, R.S. Amano, P.K. Rohatgi, Heat transfer and fluid flow analysis of self-healing in metallic materials. Heat Mass Transf. 53(3), 825–848 (2017)
K.K. Alaneme, O.I. Omosule, Experimental studies of self healing behaviour of under-aged Al–Mg–Si alloys and 60Sn–40Pb alloy reinforced aluminium metal-metal composites. J. Miner. Mater. Charact. Eng. 3(1), 1–8 (2014)
J. Kim, H.J. Kim, S.H. Hong, H.J. Park, Y.S. Kim, Y.J. Hwang, Y.B. Jeong, J.-Y. Park, J.M. Park, B. Sarac, W.-M. Wang, J. Eckert, K.B. Kim, Thermally-triggered dual in-situ self-healing metallic materials. Sci. Rep. 8(1), 2120 (2018)
K. Mysore, D., Chan, D., Bhate, G., Subbarayan, I., Dutta, V., Gupta, J., Zhao, D., Edwards Aging-informed behavior of Sn3.8Ag0.7Cu solder alloys: 2008 11th IEEE intersociety conference on thermal and thermomechanical phenomena in electronic systems, I-THERM. 2008 11th IEEE Intersoc. Conf. Therm. Thermomechanical Phenom. Electron. Syst. -THERM, 2008, pp. 870–875
I. Dutta, D. Pan, S. Ma, B.S. Majumdar, S. Harris, Role of shape-memory alloy reinforcements on strain evolution in lead-free solder joints. J. Electron. Mater. 35(10), 1902–1913 (2006)
J.P. Coughlin, J.J. Williams, G.A. Crawford, N. Chawla, Interfacial reactions in model NiTi shape memory alloy fiber-reinforced sn matrix ‘smart’ composites. Metall. Mater. Trans. A 40(1), 176–184 (2009)
J.P. Coughlin, J.J. Williams, N. Chawla, Mechanical behavior of niti shape memory alloy fiber reinforced sn matrix ‘smart’ composites. J. Mater. Sci. 44(3), 700–707 (2009)
C.R. Fisher Jr., H.B. Henderson, M.S. Kesler, M.V. Manuel, A reactive element approach to improve fracture healing in metallic systems. Front. Mater. 6, 210 (2019)
C.R. Fisher, Design of liquid-assisted self-healing metal-matrix composites (University of Florida, Gainesville, 2013)
L. Ren, X. Xu, Y. Du, K. Kalantar-Zadeh, S.X. Dou, Liquid metals and their hybrids as stimulus-responsive smart materials. Mater. Today 34, 92–114 (2020)
T. Yu, D. Deng, G. Wang, H. Zhang, Crack healing in SUS304 stainless steel by electropulsing treatment. J. Clean. Prod. 113, 989–994 (2016)
Q. Shengru, L. Yanli, L. Yun, Z. Chengyu, Damage healing of aluminum alloys by D. C. electropulsing and evaluation by resistance. Rare Met. Mater. Eng. 38(4), 570–573 (2009)
H. Song, Z. Wang, X. He, J. Duan, Self-healing of damage inside metals triggered by electropulsing stimuli. Sci. Rep. 7(1), 7097 (2017)
T. Jiang, M.J. Chollier Brym, G. Dubé, A. Lasia, G.M. Brisard, Electrodeposition of aluminium from ionic liquids: part I—electrodeposition and surface morphology of aluminium from aluminium chloride (AlCl3)–1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) ionic liquids. Surf. Coat. Technol. 201(1), 1–9 (2006)
Z. Hsain, J.H. Pikul, Low-energy room-temperature healing of cellular metals. Adv. Funct. Mater. 29(43), 1905631 (2019)
D. Svetlizky, B. Zheng, X. Wang, S. Jiang, L. Valdevit, J.M. Schoenung, E.J. Lavernia, N. Eliaz, Towards a self-healing aluminum metal matrix composite: design, fabrication, and demonstration. Appl. Mater. Today 37, 102148 (2024)
J.-N. Zhu, Z. Ding, E. Borisov, X. Yao, J.C. Brouwer, A. Popovich, M. Hermans, V. Popovich, Healing cracks in additively manufactured NiTi shape memory alloys. Virtual Phys. Prototyp. 18(1), e2246437 (2023)
Funding
This research received no external funding.
Author information
Authors and Affiliations
Contributions
Framework and conceptualization, P.R., and M.B.; outline, P.R., and M.B.; summary of self-healing using SMA wires and a column of low melting point alloy as healing agents in the matrix, V.S.; writing and manuscript preparation, P.R., M.B., and V.S.; table of self-healing systems, P.R., and M.B. All authors have read and agreed to the published version of the manuscript.
Corresponding author
Ethics declarations
Conflict of interest
On behalf of all authors, the corresponding author states that there is no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Rohatgi, P., Bellah, M. & Srivastava, V. Current status and future research imperatives of self-healing metal matrix composites. Journal of Materials Research 39, 1597–1621 (2024). https://doi.org/10.1557/s43578-024-01355-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/s43578-024-01355-z