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Formation of Silver-Containing Nanocomposites during Thermolysis of Polyacrylonitrile Salt: EPR Study

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Abstract

New insoluble polymer silver-containing nanocomposites are synthesized by the thermal treatment of a polymer complex based on polyacrylonitrile without the use of an additional reducing agent. The resulting composites are paramagnetic and have a spin concentration of about 1017−1018 spin/g and an average size of silver nanoparticles of 5−8 nm. The electron paramagnetic resonance is used to monitor the synthesis of nanosystems in time. It is found that the nanocomposite is formed via two main stages through the reduction of silver ions and the further development of nanoparticles, while the polymer matrix can undergo some changes and contribute to the overall magnetism of the resulting composite.

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REFERENCES

  1. R. Lehner, X. Wang, S. Marsch, and P. Hunziker, Nanomedicine (N. Y., NY. U. S.) 9, 742 (2013).

    CAS  Google Scholar 

  2. S. S. Khutsishvili, M. V. Lesnichaya, T. I. Vakul’skaya, G. Dolmaa, G. P. Aleksandrova, A. L. Rakevich, and B. G. Sukhov, Spectrosc. Lett. 51, 169 (2018).

    Article  CAS  Google Scholar 

  3. S. Suresh, Nanosci. Nanotechnol. 3, 62 (2013).

    Google Scholar 

  4. Y. Zhu, L. P. Stubbs, F. Ho, R. Liu, C. P. Ship, J. A. Maguire, and N. S. Hosmane, ChemCatChem 2, 365 (2010).

    Article  CAS  Google Scholar 

  5. S. Chaturvedia, P. N. Davea, and N. K. Shah, J. Saudi Chem. Soc. 16, 307 (2012).

    Article  Google Scholar 

  6. U. Landau and K. Anselm, Bactericidal and Oligodynamic Action of Silver and Copper in Hygien, Medicine and Water Treatment (Finishing Publ. Ltd., Stevenage, 2007).

    Google Scholar 

  7. B. A. Rozenberg and R. Tenne, Prog. Polym. Sci. 33, 40 (2008).

    Article  CAS  Google Scholar 

  8. A. Kausar, J. Plast. Film Sheeting 35, 295 (2019).

    Article  CAS  Google Scholar 

  9. K. Yusupov, V. Khovaylo, D. Muratov, L. Kozhitov, D. Arkhipov, V. Pryadun, and A. Vasiliev, J. Electron. Mater. 45, 3440 (2016).

    Article  CAS  Google Scholar 

  10. S. K. Kumar, N. Jouault, B. Benicewicz, and T. Neely, Macromolecules 46, 3199 (2013).

    Article  CAS  Google Scholar 

  11. O. M. Folarin, E. R. Sadiku, and A. Maity, Int. J. Phys. Sci. 6, 4869 (2011).

    Google Scholar 

  12. G. Liao, J. Fang, Q. Li, S. Li, Z. Xu, and B. Fang, Nanoscale 11, 7062 (2019).

    Article  CAS  Google Scholar 

  13. A. K. Selvam and G. Nallathambi, Fibers Polym. 16, 1327 (2015).

    Article  CAS  Google Scholar 

  14. S. P. Gubin, Y. A. Koksharov, G. B. Khomutov, and G. Y. Yurkov, Russ. Chem. Rev. 74, 489 (2005).

    Article  CAS  Google Scholar 

  15. Y. Liu, G. Jiang, L. Li, H. Chen, Q. Huang, T. Jiang, and X. Du, MRS Commun. 6, 31 (2015).

    Article  CAS  Google Scholar 

  16. I. Karbownik, T. Rybicki, A. A. Karpinska, and H. Teterycz, Mater. Sci. Polym. 34, 564 (2016).

    Article  CAS  Google Scholar 

  17. P.-O. Rujitanaroj, N. Pimpha, and P. Supaphol, J. Appl. Polym. Sci. 116, 1967 (2010).

    CAS  Google Scholar 

  18. Organikum, Ed. by H. G. O. Becker, W. Berger, G. Domschke, E. Fanghänel, J. Faust, M. Fischer, F. Gentz, K. Gewald, R. Gluch, R. Mayer, K. Müller, D. Pavel, H. Schmidt, K. Scholberg, K. Schwetlick, E. Seiler, and G. Zeppenfield (VEB Deutscher Verlag der Wissenschaften, Berlin, 1986).

    Google Scholar 

  19. C. P. Poole, Electron Spin Resonance: A Comprehensive Treatise on Experimental Techniques (Dover Publ., Dover, 1997).

    Google Scholar 

  20. C. A. Barret and T. B. Massalsky, Structure of Metals (McGraw-Hill, New York, 1966).

    Google Scholar 

  21. S. S. Khutsishvili, T. I. Vakul’skaya, N. P. Kuznetsova, T. G. Ermakova, A. S. Pozdnyakov, and G. F. Prozorova, J. Phys. Chem. C 118, 19338 (2014).

    Article  CAS  Google Scholar 

  22. M. Ali, A. I. Shames, S. Gangopadhyay, B. Saha, and D. Meyerstein, Transition Met. Chem. 29, 463 (2004).

    CAS  Google Scholar 

  23. J. A. McMilan and B. Smaler, J. Chem. Phys. 35, 1698 (1961).

    Article  Google Scholar 

  24. N. I. Tikhonov, S. S. Khutsishvili, L. I. Larina, A. S. Pozdnyakov, A. I. Emel’yanov, G. F. Prozorova, A. V. Vashchenko, and T. I. Vakul’skaya, J. Mol. Struct. 1180, 272 (2019).

    Article  CAS  Google Scholar 

  25. H. N. Po, Coord. Chem. Rev. 20, 171 (1976).

    Article  CAS  Google Scholar 

  26. O. P. Murtha and R. A. Walton, Inorg. Chem. 12, 1278 (1973).

    Article  CAS  Google Scholar 

  27. W. Liu, M. Wang, Z. **ng, and G. Wu, Radiat. Phys. Chem. 81, 835 (2012).

    Article  CAS  Google Scholar 

  28. H. Xue, P. Bhowmik, and S. Schlick, Macromolecules 26, 3340 (1993).

    Article  CAS  Google Scholar 

  29. H. R. Moon, J. H. Kim, and M. P. Suh, Angew. Chem., Int. Ed. Engl. 44, 1261 (2005).

    Article  CAS  Google Scholar 

  30. S. S. Khutsishvili, T. I. Vakul’skaya, G. P. Aleksandrova, and B. G. Sukhov, J. Cluster Sci. 28, 3067 (2017).

    Article  CAS  Google Scholar 

  31. V. A. Timoshenko, T. I. Shabatina, Yu. N. Morozov, and G. B. Sergeev, J. Struct. Chem. 47, 145 (2006).

    Article  CAS  Google Scholar 

  32. J. Michalik, H. Yamada, D. R. Brown, and L. Kevan, J. Phys. Chem. 100, 4213 (1996).

    Article  CAS  Google Scholar 

  33. M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stoser, G. Pacchioni, Nanotecnology 19, 135701 (2008).

    Article  Google Scholar 

  34. V. Ya. Varshavskii, Fibre Chem. 25, 442 (1993).

    Article  Google Scholar 

  35. F. Blatter and K. W. Blazey, ZPhys-e. D: At., Mol. Clusters 18, 427 (1991).

    Article  CAS  Google Scholar 

  36. T. V. Ganenko, A. P. Tantsyrev, A. N. Sapozhnikov, S. S. Khutsishvili, T. I. Vakul’skaya, T. V. Fadeeva, B. G. Sukhov, and B. A. Trofimov, Russ. J. Gen. Chem. 85, 477 (2015).

    Article  CAS  Google Scholar 

  37. Z. Qu and E. Roduner, Asia-Pac. J. Chem. Eng. 4, 602 (2009).

    Article  CAS  Google Scholar 

  38. M. V. Lesnichaya, B. G. Sukhov, G. P. Aleksandrova, E. R. Gasilova, T. I. Vakul’skaya, S. S. Khutsishvili, A. N. Sapozhnikov, I. V. Klimenkov, and B. A. Trofimov, Carbohydr. Polym. 175, 18 (2017).

    Article  CAS  Google Scholar 

  39. A. Kawabata, J. Phys. Soc. Jpn. 29, 902 (1970).

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

This work was carried out using equipment of the Baikal Analytical Shared Research Center at the Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences.

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Authors and Affiliations

  1. Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 664033, Irkutsk, Russia

    N. I. Tikhonov, S. S. Khutsishvili, T. I. Vakul’skaya, N. P. Kuznetsova, A. I. Emel’yanov & A. S. Pozdnyakov

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  1. N. I. Tikhonov
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  2. S. S. Khutsishvili
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  3. T. I. Vakul’skaya
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  4. N. P. Kuznetsova
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  6. A. S. Pozdnyakov
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Correspondence to S. S. Khutsishvili.

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Tikhonov, N.I., Khutsishvili, S.S., Vakul’skaya, T.I. et al. Formation of Silver-Containing Nanocomposites during Thermolysis of Polyacrylonitrile Salt: EPR Study. Polym. Sci. Ser. B 63, 175–181 (2021). https://doi.org/10.1134/S1560090421010073

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  • DOI: https://doi.org/10.1134/S1560090421010073

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