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Modified Vortex-assisted Surfactant-enhanced Emulsification Microextraction using Methyl Benzoate for the Preconcentration of Fungicides in Fruit Juice Samples and Determination by High-performance Liquid Chromatography

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Abstract

Methyl benzoate-based vortex-assisted surfactant-enhanced emulsification microextraction (VASEME) has been developed and applied for the preconcentration of fungicides (i.e., carbendazim, thiabendazole and fluberidazole) and their subsequent determination by high performance liquid chromatography. Methyl benzoate (as extraction solvent) and sodium dodecyl sulfate (as emulsifier) were used in VASEME. Parameters affecting the extraction performance were investigated and optimized. Under the optimum conditions, linearity was obtained in the range of 0.1–200 μg/L with the coefficient of determination exceeding 0.998. Limits of detection and quantitation were 0.01–0.5 and 0.1–3 μg/L, respectively. Recoveries of the spiked analytes (10–100 μg/L) from fruit juice samples were between 72 and 116% with the relative standard deviation below 10%. The proposed method is simple, rapid, consuming less solvent, sensitive and reliable for the determination of fungicide residues in fruit juice samples.

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Funding

This research was supported by the grant for new scholars from the Thailand Research Fund (TRF) and Rajamangala University of Technology Isan, under grant no. TRG5780038.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Engineering, Rajamangala University of Technology Isan, Khon Kaen Campus, 40000, Khon Kaen, Thailand

    Yanawath Santaladchaiyakit, Jittaya Sadchaiyaphum, Nusara Phannorit, Chutikarn Lekyoung & Nipaporn Chumwangwapee

  2. Materials Chemistry Research Center, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Khon Kaen University, 40002, Khon Kaen, Thailand

    Supalax Srijaranai

Authors
  1. Yanawath Santaladchaiyakit
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  2. Jittaya Sadchaiyaphum
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  3. Nusara Phannorit
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  4. Chutikarn Lekyoung
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  5. Nipaporn Chumwangwapee
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  6. Supalax Srijaranai
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Correspondence to Yanawath Santaladchaiyakit.

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Yanawath Santaladchaiyakit, Sadchaiyaphum, J., Phannorit, N. et al. Modified Vortex-assisted Surfactant-enhanced Emulsification Microextraction using Methyl Benzoate for the Preconcentration of Fungicides in Fruit Juice Samples and Determination by High-performance Liquid Chromatography. J Anal Chem 74, 1027–1034 (2019). https://doi.org/10.1134/S1061934819100095

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