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Electrochemical Properties of N-Methyl-2,2'-bipyridinium Iodide and N,N'-Dimethyl-2,2'-bipyridinium Iodide

  • ELECTROCHEMISTRY. GENERATION AND STORAGE OF ENERGY FROM RENEWABLE SOURCES
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Abstract

The electrochemical properties of N-substituted salts of 2,2'-bipyridine: N-methyl-2,2'-bipyridinium iodide and N,N '-dimethyl-2,2'-bipyridinium iodide were studied by cyclic voltammetry (CV). The electrochemical properties are greatly affected by the methyl substituents at the nitrogen atom in the ortho-bipyridine molecule. The conproportionation constants were calculated for N,N '-dimethyl-2,2'-bipyridinium iodide and made it possible to judge about the degree of electron localization in the systems.

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Funding

This study was financially supported by the Ministry of Science and Higher Education of the Russian Federation (topic no. 121111000064-5). It was performed under the government contract at Mordovia National Research University (creation of new laboratories for young researchers).

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Authors and Affiliations

  1. Mordovia State University, 430005, Saransk, Russia

    A. V. Dolganov, L. A. Klimaeva, E. E. Muryumin, S. G. Kostryukov, A. Sh. Kozlov & O. V. Tarasova

  2. Lobachevsky State University of Nizhny Novgorod, 603022, Nizhny Novgorod, Russia

    A. V. Knyazev

Authors
  1. A. V. Dolganov
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  2. L. A. Klimaeva
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  3. E. E. Muryumin
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  6. O. V. Tarasova
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Correspondence to A. V. Dolganov.

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Translated by L. Smolina

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Dolganov, A.V., Klimaeva, L.A., Muryumin, E.E. et al. Electrochemical Properties of N-Methyl-2,2'-bipyridinium Iodide and N,N'-Dimethyl-2,2'-bipyridinium Iodide. Russ. J. Phys. Chem. 97, 2307–2313 (2023). https://doi.org/10.1134/S0036024423100060

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