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Effect of the morphology of structured carbon nanomaterials on their oxidizability

  • Physical Chemistry of Nanoclusters and Nanomaterials
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Abstract

The oxidation of multi-walled carbon nanotubes (MCNTs), nanofibers (CNFs), and few-layer graphite fragments (FLGFs) with a nitric acid solution was studied. The oxygen content in the functionalized derivatives was determined by X-ray photoelectron spectroscopy and thermal analysis. The results were correlated with the structural features of the nanomaterials revealed by high-resolution transmission electron microscopy and X-ray diffraction. The highest content of carboxyl groups was achieved by functionalization of carbon nanotubes with the conical position of graphene layers.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, Russia

    S. V. Savilov, A. S. Ivanov, A. V. Egorov, M. N. Kirikova, E. A. Arkhipova & V. V. Lunin

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    S. V. Savilov, E. A. Arkhipova & V. V. Lunin

Authors
  1. S. V. Savilov
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  2. A. S. Ivanov
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  3. A. V. Egorov
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  4. M. N. Kirikova
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  5. E. A. Arkhipova
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  6. V. V. Lunin
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Corresponding author

Correspondence to S. V. Savilov.

Additional information

Original Russian Text © S.V. Savilov, A.S. Ivanov, A.V. Egorov, M.N. Kirikova, E.A. Arkhipova, V.V. Lunin, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 2, pp. 249–255.

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Savilov, S.V., Ivanov, A.S., Egorov, A.V. et al. Effect of the morphology of structured carbon nanomaterials on their oxidizability. Russ. J. Phys. Chem. 90, 429–435 (2016). https://doi.org/10.1134/S0036024416020278

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  • DOI: https://doi.org/10.1134/S0036024416020278

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