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Nickel release rate of several nickel-containing stainless steels for jewelries

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Abstract

Nickel-containing stainless steels have been widely applied in watch and jewelry production, and their responses to the Nickel Directive become a universal concern in the industry. The nickel release rates and corrosion behaviors of types 316L, 304, 303 and 201 stainless steels under the conditions of solid solution and mirror polishing were studied by artificial sweat soaking and electrochemical methods. The results show that the weekly nickel release rates in artificial sweat do not strictly correspond to the nickel contents, which present a descending order as 303 stainless steel of 2.06 µg/cm2, 201 stainless steel of 1.51 µg/cm2, 304 stainless steel of 0.08 µg/cm2 and 316L stainless steel of 0.02 µg/cm2. Both the nickel release rates of type 303 and 201 stainless steels significantly exceed the threshold values regulated in EN1811 : 2011; therefore, they should be avoided to be used as watch and jewelry materials owing to the risk of nickel sensitization. The nickel release rates of 316L and 304 stainless steels meet the requirements of the standard. Sulfide inclusions in stainless steel become the sources of pitting and exacerbate the damage of the passivation membrane, which is the significant cause to enhance the nickel release rates.

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References

  1. J. P. Yuan, W. Li, C. Wang, Mater. Sci. Eng. C 33 (2013) 446–452.

    Article  Google Scholar 

  2. C. Lidén, Brit. J. Dermatol 169 (2013) 733.

  3. J. P. Thyssen, T. Menne, Chem. Res. Toxicol 23 (2010) 309–318.

    Article  Google Scholar 

  4. European Communities, Off. J. Europ. Commun. 37 (1994) 1–2.

    Google Scholar 

  5. EN1811 : 1998, Reference Test Method for Release of Nickel from Products Intended to Come into Direct Prolonged Contact with the Skin, European Committee for Standardization, Brussel, 1998.

  6. The Commission of European Communities, Off. J. Europ. Union 301 (2004) 51–52.

    Google Scholar 

  7. EN 1811 : 1998 + A1: 2008, Reference Test Method for Release of Nickel from Products Intended to Come into Direct and Prolonged Contact with the Skin, European Committee for Standardization, Brussel, 2008.

  8. EN 1811: 2011, Reference Test Method for Release of Nickel from All Post Assemblies which are Inserted into Pierced Parts of the Human Body and Articles Intended to Come into Direct and Prolonged Contact with the Skin, European Committee for Standardization, Brussel, 2011.

  9. J. P. Yuan, W. Li, W. X. Guo, Adv. Mater. Res. 241 (2011) 3284–3289.

    Article  Google Scholar 

  10. H. S. Khatak, B. Raj, Corrosion of Austenitic Stainless Steels: Mechanism, Mitigation and Monitoring, Woodhead Publishing Ltd., UK, 2002.

  11. N. J. Laycock, R. C. Newman, Corros. Sci. 39 (1997) 1771–1790.

    Article  Google Scholar 

  12. G. S. Frankel, J. Electrochem. Soc. 145 (1998) 2186–2198.

    Article  Google Scholar 

  13. Z.J Jia, C. W. Du, C. T. Li, Z. Yi, X. G. Li, Int. J. Miner. Metall. Mater. 18 (2011) 48–52.

    Article  Google Scholar 

  14. J. H. Cleland, Eng. Fail. Anal. 3 (1996) 65–69.

    Article  Google Scholar 

  15. J. Wu, Duplex Stainless Steels, 2nd ed., Metallurgical Industry Press, Bei**g, 1999.

  16. A. Chiba, I. Muto, Y. Sugawara, N. Hara, J. Electrochem. Soc. 160 (2013) 511–520.

    Article  Google Scholar 

  17. J. P. Yuan, W. Li, C. Wang, Rare Metal Mater. Eng. 41 (2012) 947–951.

    Article  Google Scholar 

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Authors and Affiliations

  1. Jewelry Institute of Guangzhou Panyu Polytechnic, 511483, Guangzhou, Guangdong, China

    Jun-** Yuan (Doctor, Professor), Chang Wang, Chun-yu Ma, Ling-xia Chen & De-dong Chen

  2. Department of Materials Science and Engineering, **an University, 510632, Guangzhou, Guangdong, China

    Wei Li

Authors
  1. Jun-** Yuan
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  2. Wei Li
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  3. Chang Wang
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  4. Chun-yu Ma
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  5. Ling-xia Chen
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  6. De-dong Chen
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Yuan, Jp., Li, W., Wang, C. et al. Nickel release rate of several nickel-containing stainless steels for jewelries. J. Iron Steel Res. Int. 22, 72–77 (2015). https://doi.org/10.1016/S1006-706X(15)60012-7

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  • DOI: https://doi.org/10.1016/S1006-706X(15)60012-7

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