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An eco-friendly and sensitive deep eutectic solvent-based liquid-phase microextraction procedure for extraction preconcentration of Pb (II) ions

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Abstract

In recent years, interest in green solvents, which are environmentally friendly, easy to prepare and biodegradable, and in their applications in chemistry has considerably increased. In the current study, a new and easy deep eutectic solvent-based liquid-phase microextraction method compatible with green chemistry principles was developed for preconcentration of Pb (II) ions. The amount of Pb (II) ions was determined with graphite furnace atomic absorption spectrometry (GFAAS). Various analytical parameters such as deep eutectic solvent (DES) ratio and amount, ligand amount, pH, sample volume were optimized and the effects of potential matrix ions on the method were investigated. The preconcentration factor of the method was found to be 160, while the limit of detection (LOD) and limit of quantification (LOQ) were found to be 0.071 µg L−1 and 0.236 µg L−1, respectively. The developed procedure was performed to determine Pb (II) ions in lake and river waters, and the accuracy of the procedure was determined with certified reference wastewater (SPS-WW1) analysis.

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References

  1. G.P. Rao, C. Lu, F. Su, Sep. Purif. Technol. 58, 224–231 (2007)

    Article  CAS  Google Scholar 

  2. A.M. Al-Othman, Z.A. Al-Othman, G.E. El-Desoky, M.A.M. Aboul-Soud, M.A. Habila, J.P. Giesy, Arab. J. Geosci. 6, 3103–3109 (2013)

    Article  CAS  Google Scholar 

  3. O. Aydın-Urucu, Ş Dönmez, E. Kök-Yetimoğlu, J. Anal. Methods Chem. 2017, 1–17 (2017). https://doi.org/10.1155/2017/6268975

    Article  CAS  Google Scholar 

  4. M.A. Habila, Z.A. Alothman, E. Yilmaz, E.A. Alabdullkarem, M. Soylak, Microchem. J. 148, 214–219 (2019)

    Article  CAS  Google Scholar 

  5. E. Kendüzler, M. Duman-Dinç, D. Trak, B. Kabak, Y. Arslan, J. Anal. Chem. 75, 1264–1269 (2020)

    Article  Google Scholar 

  6. M.A. Baldo, A.M. Stortini, P. Oliveri, R. Leardi, L.M. Moretto, P. Ugo, Talanta 210, 120667 (2020)

    Article  CAS  PubMed  Google Scholar 

  7. R. Rahnama, A. Shokuhi Rad, P. Farrokhmanesh, Int. J. Environ. Anal. Chem. 98, 98247–257 (2018). https://doi.org/10.1080/03067319.2018.1445728

    Article  CAS  Google Scholar 

  8. O. Aydın-Urucu, Z. Yurtman-Gündüz, S. Deniz, E. Kök-Yetimoğlu, A. Aydın, Environ. Chem. Lett. 12, 449–453 (2014)

    Article  Google Scholar 

  9. A. Beyler-Çiğil, O. Aydın-Urucu, M.V. Kahraman, J. Appl. Polym. Sci. 136, 48241–48249 (2019)

    Article  Google Scholar 

  10. O. Aydın-Urucu, E. Kök-Yetimoğlu, H. Filik, Maced J. Chem. Eng. 32, 69–78 (2013)

    Article  Google Scholar 

  11. O. Aydın-Urucu, E.D. Aracier, J. AOAC Int. 104, 645–649 (2021)

    Article  PubMed  Google Scholar 

  12. S. Zhang, B. Chen, M. He, B. Hu, Microchem. J. 139, 380–385 (2018)

    Article  CAS  Google Scholar 

  13. N. Altunay, D. Bingöl, A. Elik, R. Gürkan, Spectrochim. Acta A Mol. Biomol. Spectrosc. 221, 117166 (2019)

    Article  CAS  PubMed  Google Scholar 

  14. T. Borahan, T. Unutkan, N.B. Turan, F. Turak, S. Bakırdere, Food Chem. 299, 125065 (2019)

    Article  CAS  PubMed  Google Scholar 

  15. J. Huang, X. Guo, T. Xu, L. Fan, X. Zhou, S. Wu, J. Chromatogr. A 1598, 1–19 (2019)

    Article  CAS  PubMed  Google Scholar 

  16. A. Shishov, A. Bulatov, M. Locatelli, S. Carradori, V. Andruch, Microchem J. 135, 33–38 (2017)

    Article  CAS  Google Scholar 

  17. O.E. Plastiras, E. Andreasidou, V. Samanidou, Molecules 25, 6026 (2020). https://doi.org/10.3390/molecules25246026

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  18. S. Fouladlou, H. Faraji, H. Shahbaazi, A. Moghimi, F. Azizinezhad, Microchem. J. 162, 105834 (2021)

    Article  CAS  Google Scholar 

  19. E. Carasek, G. Bernardi, D. Morelli, J. Merib, J. Chromatogr A. 1640, 461944 (2021)

    Article  CAS  PubMed  Google Scholar 

  20. M. Soylak, S. Deryol, F. Uzcan, Int J. Environ. Anal. Chem. 101, 1437–1447 (2021). https://doi.org/10.1080/03067319.2019.1685092

    Article  CAS  Google Scholar 

  21. Y. Marcus, Deep Eutectic Solvents, Springer International Publishing, Cham, https://doi.org/10.1007/978-3-030-00608-2

  22. Z. Ali, A. Zuhri, Spectrosc. Lett 19(4), 333–341 (1986)

    Article  Google Scholar 

  23. L. Gao, S. Jie Chen, F. Chen, W. Hong Zhou, J. Long Yao, Adv. Mater. Res. 830, 345–348 (2013)

    Article  Google Scholar 

  24. O. Aydın-Urucu, E. Kök-Yetimoğlu, S. Dönmez, S. Deniz, J. Serb. Chem. 84(4), 435–443 (2019)

    Article  Google Scholar 

  25. J. Chen, S. **ao, X. Wu, K. Fang, W. Liu, Talanta 67, 992–996 (2005)

    Article  CAS  PubMed  Google Scholar 

  26. R.G. Wuilloud, H.A. Acevedo, F.A. Vazquez, L.D. Martinez, Anal. Lett. 35, 1649–1665 (2002)

    Article  CAS  Google Scholar 

  27. M.A. Taher, Bull. Chem. Soc. Ethiop. 17(2), 129–138 (2003)

    CAS  Google Scholar 

  28. W. Guo, W. Liu, S. **, S. Hu, H. Zhang, Y. Peng, 2nd International Conference on Bioinformatics and Biomedical Engineering, (2008).

  29. M.B. Arain, E. Yilmaz, M. Soylak. J. Mol. Liq. 224, 538–543 (2016)

    Article  CAS  Google Scholar 

  30. A. Karatepe, M. Yemen, F. Kayapa, E. Yılmaz, F. Karipcin, M. Soylak, Talanta 248, 123651 (2022)

    Article  CAS  PubMed  Google Scholar 

  31. M. Soylak, M. Koksal, Microchem. J. 147, 832–837 (2019)

    Article  CAS  Google Scholar 

  32. Z.A. Alothman, E. Yilmaz, M. Habila, A. Shabaka, M. Soylak, Microchim. Acta 180, 669–674 (2013)

    Article  CAS  Google Scholar 

  33. Z.A. Alothman, N.H. Al-Shaalan, M.A. Habila, Y.E. Unsal, M. Tuzen, M. Soylak, Environ. Monit. Assess. 187(2), 9 (2015). https://doi.org/10.1007/s10661-014-4160-4

    Article  CAS  PubMed  Google Scholar 

  34. M.A. Habila, E. Yilmaz, Z.A. Alothman, M. Soylak, J., Ind. Eng. Chem. 37, 306–311 (2016)

    Article  CAS  Google Scholar 

  35. S. Samaneh, B. Abdulrahman, G. Farhad, S.F. Ghorbani, Chem. Pap. 72(8), 1945–1952 (2018)

    Article  Google Scholar 

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Authors and Affiliations

  1. Faculty of Sciences, Chemistry Department, Marmara University, İstanbul, Turkey

    Esra Duygu Aracier, Ece Kök Yetimoğlu & Oya Aydın Urucu

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  1. Esra Duygu Aracier
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  2. Ece Kök Yetimoğlu
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  3. Oya Aydın Urucu
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Correspondence to Ece Kök Yetimoğlu or Oya Aydın Urucu.

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Aracier, E.D., Kök Yetimoğlu, E. & Aydın Urucu, O. An eco-friendly and sensitive deep eutectic solvent-based liquid-phase microextraction procedure for extraction preconcentration of Pb (II) ions. ANAL. SCI. 39, 1065–1071 (2023). https://doi.org/10.1007/s44211-023-00315-7

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