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Deciphering the role of alkyl chain length on interaction study of antidepressant drug-cationic surfactants in imidazolium based ionic liquid

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Abstract

To study the role of alkyl chain length on the thermodynamics and mixed micellization behavior of amitriptyline hydrochloride (AMT) with dodecyltrimethylammonium bromide (DTAB)/cetyltrimethylammonium bromide (CTAB) in imidazolium based ionic liquid 1-methyl-3-octylimidazolium chloride (Omim.Cl) at various mole fractions and several temperatures (varied: 298–313 K) was carried out by the electrical conductivity measurements. Mixed micellization behavior of CTAB with AMT demonstrates the synergistic interaction while DTAB with AMT favors antagonistic interaction, in the presence of Omim.Cl. The shift in nature of binding interaction from antagonistic to synergistic with increase in the alkyl chain length of cationic surfactant from DTAB to CTAB is elucidated in terms of the divergence in ideal and calculated values of critical micelle concentration (cmc) and micellar mole fraction (Xm) and discussed in an appropriate manner. In addition, the values of various thermodynamic parameters were determined by using the results obtained from conductivity plots. They also support the results obtained from the interaction parameters.

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Acknowledgements

Dr. Abbul Bashar Khan thankful to University Grant Commission for UGC-BRS Research Start-Up-Grant (No.F.30-531/2020(BSR)).

This article is dedicated to Prof. Kabir-ud-Din (my PhD supervisor) on his 75th birthday.

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Authors and Affiliations

  1. Division of Computational Physics, Institute for Computational Science, Ton Duc Thang University, Ho Chi Minh City, Vietnam

    Dileep Kumar

  2. Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City, Vietnam

    Dileep Kumar

  3. Department of Biochemistry, Daulat Ram College, University of Delhi, New Delhi, India

    Mehraj ud din Parray

  4. Department of Chemistry, Jamia Millia Islamia, (A Central University), New Delhi, India

    Farooq Ahmed Wani & Abbul Bashar Khan

  5. Centre for Interdisciplinary Research in Basic Sciences, Jamia Millia Islamia (A Central University), New Delhi, India

    Neeraj Dohare & Rajan Patel

  6. Department of Chemistry, Aligarh Muslim University, Aligarh, India

    Maroof Ali

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  1. Dileep Kumar
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Correspondence to Abbul Bashar Khan.

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Kumar, D., Parray, M.u.d., Wani, F.A. et al. Deciphering the role of alkyl chain length on interaction study of antidepressant drug-cationic surfactants in imidazolium based ionic liquid. J IRAN CHEM SOC 19, 2449–2457 (2022). https://doi.org/10.1007/s13738-021-02459-7

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  • DOI: https://doi.org/10.1007/s13738-021-02459-7

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