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Provenance discrimination of commercial grape juices from Argentina and Brazil based on elemental composition and chemometric methods

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Abstract

The knowledge of a product’s origin is an important aspect for consumers who demand quality and authenticity. Grape juice is a beverage that has currently gained more attention due to the tendency of people towards a more natural and healthy lifestyle. The aim of this study was to discriminate the origin of grape juice samples. For this purpose, chemometric techniques were applied to commercial samples of grape juice from Argentina and Brazil, and the feasibility of classification models of predicting the origin of samples based on elemental composition, was investigated. Inductively coupled plasma mass spectrometry (ICP-MS) was used to determine 10 elements (V, Cr, Mn, Fe, Ni, Cu, As, Rb, Y and Mo). Unsupervised methods, such as principal component analysis (PCA) and cluster analysis (CA) and the supervised technique, linear discriminant analysis (LDA) with bootstrap** and k-fold cross-validation were assessed. The best result was achieved for LDA with 4 fold cross validation with a prediction accuracy of 81%.

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Acknowledgements

This work was supported by Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Agencia Nacional de Promoción Científica y Tecnológica (FONCYT) (Project PICT-2019-03859-BID) and Universidad Nacional de Cuyo (Project 06/M035-T1 (Argentina).

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Authors and Affiliations

  1. Laboratorio de Química Analítica para Investigación y Desarrollo (QUIANID), Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Cuyo, Instituto Interdisciplinario de Ciencias Básicas (ICB), CONICET UNCUYO, Padre J. Contreras 1300, (5500), Mendoza, Argentina

    Brenda V. Canizo & Rodolfo G. Wuilloud

  2. Laboratorio DHARMa, Departamento Sistemas de Información, Facultad Regional Mendoza, Universidad Tecnólogica Nacional (FRM-UTN), Mendoza, Argentina

    Ana Laura Diedrichs

  3. Grupo GridTICs, Departamento Electrónica, Facultad Regional Mendoza, Universidad Tecnológica Nacional (FRM-UTN), Mendoza, Argentina

    Ana Laura Diedrichs

  4. Comisión Nacional de Energía Atómica, Gerencia Química, Buenos Aires, Argentina

    Agustín Londonio & Patricia Smichowski

  5. Instituto de Investigación e Ingeniería Ambiental (3iA), Universidad de San Martín, Martín de Irigoyen, San Martín, Buenos Aires, 3100, 1650, Argentina

    Agustín Londonio

  6. Consejo Nacional de Investigaciones Científicas y Técnicas, Buenos Aires, Argentina

    Patricia Smichowski

  7. Instituto de Química Básica y Aplicada del Nordeste Argentino (IQUIBA-NEA), Facultad de Ciencias Exactas y Naturales y Agrimensura, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Universidad Nacional del Nordeste (UNNE), Av. Libertad 5470, (3400), Corrientes, Argentina

    Roberto G. Pellerano

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  1. Brenda V. Canizo
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  2. Ana Laura Diedrichs
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  3. Agustín Londonio
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  4. Patricia Smichowski
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  5. Roberto G. Pellerano
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  6. Rodolfo G. Wuilloud
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Correspondence to Rodolfo G. Wuilloud.

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Canizo, B.V., Diedrichs, A.L., Londonio, A. et al. Provenance discrimination of commercial grape juices from Argentina and Brazil based on elemental composition and chemometric methods. Food Measure 18, 2409–2419 (2024). https://doi.org/10.1007/s11694-024-02376-2

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  • DOI: https://doi.org/10.1007/s11694-024-02376-2

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