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Experimental Investigation of Phase Equilibria in Zr-Ni-Pt System

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Abstract

Phase equilibria in Zr-Ni-Pt ternary system have been experimentally determined through diffusion triple and alloy sampling approaches. Based on the results of Electron Probe Microanalysis (EPMA) and x-ray diffraction (XRD), isothermal sections of this system were constructed at 1073 and 1173 K. A new ternary phase denoted as Zr4(Pt,Ni)3 was detected with composition ranging from 2.5 to 29.7 at.% Ni and 40.7 to 12.7 at.% Pt at 1073 K while 2.2 to 25.1 at.% Ni and 40.9 to 17.5 at.% Pt at 1173 K, respectively. Three continuous solutions are formed between binary compounds ZrNi and ZrPt, Zr7Ni10 and Zr7Pt10, ZrNi3 and ZrPt3, and large ternary solubility of Ni in ZrPt4, and of Pt in Zr2Ni and ZrNi5, were observed.

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Acknowledgments

This work was financially supported by the National Key Research and Development Program of China (Grant No. 2016YFB0701404) and the Major State Basic Research Development Program of China (Grant No. 2014CB6644002).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Central South University, Changsha City, 410083, Hunan Province, People’s Republic of China

    J. Lu, X. M. Huang, K. Hu, H. S. Liu, G. M. Cai & Z. P. **

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  1. J. Lu
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  2. X. M. Huang
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  3. K. Hu
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  4. H. S. Liu
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  5. G. M. Cai
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Correspondence to H. S. Liu.

Appendix

Appendix

See Tables 4 and 5.

Table 4 Tie-lines determined through the Zr-Ni-Pt diffusion triple treated at 1073 K
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Table 5 Tie-lines determined through the Zr-Ni-Pt diffusion triple treated at 1173 K
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Lu, J., Huang, X.M., Hu, K. et al. Experimental Investigation of Phase Equilibria in Zr-Ni-Pt System. J. Phase Equilib. Diffus. 39, 301–314 (2018). https://doi.org/10.1007/s11669-018-0631-6

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  • DOI: https://doi.org/10.1007/s11669-018-0631-6

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